基于无线传感器网络的小粒种咖啡园滴灌自动控制系统

为实现小粒种咖啡种植园的精量灌溉,达到节水增收的目的,基于无线传感器网络（WSNs）设计了一种滴灌自动控制系统,主要由传感器节点、簇头、控制节点和汇聚节点组成.测试了节点间的有效通信距离为50m,并在此基础上,采用静态簇和节点定位布置的方法进行了灌区划分和节点部署,每个灌区为边长50m的正方形,内设1个簇头、1个控制节点和4个传感器节点.采用定时通信与时间同步技术、休眠技术相结合的方法实现节点数据的无线传输,融合土壤含水率、光强和空气温湿度等信息,采用分区轮灌策略实现滴灌的自动控制.实验结果表明：系统实现了预期设计目标,能应用于小粒咖啡园的精量灌溉管理.     

Amphiphilic segmented polymer networks based on poly(2-alkyl-2-oxazoline) and poly(methyl methacrylate)

Amphiphilic segmented polymer networks (SPNs) have been prepared by free radical copolymerization of methyl methacrylate with α,ω-bisacrylate terminated poly(2-methyl-2-oxazoline) and poly(2-ethyl-2-oxazoline). DSC and DMTA analysis demonstrated the influence of the copolymer composition, the molecular weight and nature of the poly(2-alkyl-2-oxazoline)s and the polymerization conditions on the final phase morphology of the networks. A comparative phase morphology study of the polymer blends and SPNs revealed the more compatible phase morphology of the networks. The compatibility could be further increased by UV-induced network formation. The investigation of the solvent uptake in different solvents clearly demonstrated the amphiphilic nature of the SPNs.     

Natural rubber–ethylene‐propylene‐diene rubber covulcanization: Effect of reinforcing fillers

Filled covulcanizates of elastomer blend comprising natural rubber (NR) and ethylene‐propylene‐diene rubber (EPDM) of commercial importance were successfully prepared by using a multifunctional rubber additive; namely, bis(diisopropyl)thiophosphoryl disulfide (DIPDIS). A Two‐stage vulcanization technique further improved the physicochemical properties of the blend vulcanizates by restricting, through the formation of polar rubber bound intermediates, the migration of curative and filler from lower to highly unsaturated rubber. Scanning electron microscopy studies indicate homogeneity and coherency in the morphology of the two‐stage vulcanizates. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1001–1010, 2002; DOI 10.1002/app.10361     

Synthesis and biological activity of phthalimide‐based polymers containing 5‐fluorouracil

The attachment of anticancer agents to polymers is a promising approach towards reducing the toxic side‐effects and retaining the potent antitumour activity of these agents. A new tetrahydrophthalimido monomer containing 5‐fluorouracil (ETPFU) and its homopolymer and copolymers with acrylic acid (AA) and with vinyl acetate (VAc) have been synthesized and spectroscopically characterized. The ETPFU contents in poly(ETPFU‐co‐AA) and poly(ETPFU‐co‐VAc) obtained by elemental analysis were 21 mol% and 20 mol%, respectively. The average molecular weights of the polymers determined by gel permeation chromatography were as follows: M_n = 8900 g mol^?1, M_w = 13 300 g mol^?1, M_w/M_n = 1.5 for poly(ETPFU); M_n = 13 500 g mol^?1, M_w = 16 600 g mol^?1, M_w/M_n = 1.2 for poly(ETPFU‐co‐AA); M_n = 8300 g mol^?1, M_w = 11 600 g mol^?1, M_w/M_n = 1.4 poly(ETPFU‐co‐VAc). The in vitro cytotoxicity of the compounds against FM3A and U937 cancer cell lines increased in the following order: ETPFU > 5‐FU > poly(ETPFU) > poly(ETPFU‐co‐AA) > poly(ETPFU‐co‐VAc). The in vivo antitumour activities of all the polymers in Balb/C mice bearing the sarcoma 180 tumour cell line were greater than those of 5‐FU and monomer at the highest dose (800 mg kg^?1). © 2002 Society of Chemical Industry     

用于光刻系统仿真的多边形处理算法

为提高光刻仿真效率,通过对光刻原理进行研究,提出了2种多边形处理算法,将掩模上的多边形图案进行切分优化,将其划分成若干矩形或三角形。在Linux环境下应用C语言设计出一个完整的光刻仿真系统,设计的具体光学参数为:光源波长为193nm,数值孔径为0.3~0.8,部分相干系数可调范围为0.2~0.8,可一次性仿真1μm×1μm到10μm×10μm范围内的45 nm~0.18μm工艺的复杂版图,并通过多次实验进行验证。实验结果表明:原版图图像的边缘细节得到保留,且该算法有效地减少了光刻模拟的计算复杂度与计算时间,整体效率提升20%以上,为当前智能传感器系统芯片的制造节省了宝贵时间。     

Fluoroelastomers-dependence of relaxation phenomena on composition

The dynamic-mechanical properties of some fluoroelastomers were determined as a function of composition at low frequency (≈ 1 Hz), by means of a free oscillation torsion pendulum, between −180°C and the softening point. Vinylidenefluoride (VDF)-hexafluoropropene (HFP) copolymers of molar composition 0–39% HFP and terpolymers of VDF and HFP with up to 30mol% tetrafluoroethylene (TFE) and a constant VDF to HFP molar ratio of 3.4 were considered. Two relaxation processes typical of the amorphous phase were found. The first, located at about −87°C, is related to local motions and the transition temperature was found to be independent of composition for copolymers, while it depends on TFE molar content for terpolymers. The second is related to the glass transition and the transition temperature depends on the composition. However, for semicrystalline copolymers the double glass transition phenomenon was observed. When crystallinity goes to zero at about 20 mol% HFP, only one transition is observed. It was also found that ordered structures can take place for terpolymers when TFE molar concentration exceeds 20%. The crystal disorder transition of pure PVDF (75°C) is observed also for low HFP concentrations but the transition temperature is strongly reduced. Analogies between the VDF-HFP and E-P systems are also discussed.     

一种基于过零点的时延测量方法

信号传输时间（时延）的测量,是雷达、声纳系统的关键技术之一。本文研究了一种基于过零点的时延测量方法,在建立过零点搜索模型的基础上推导得出时延测量的测量结果表达式;定量分析了高斯白噪声条件下过零点时延测量的测量精度,得到测量误差的理论表达式。仿真与实验表明,过零点时延测量精度与信号频率、过零点数目、信噪比密切相关,当信噪比较高时,其测量精度与经典FFT法相当,而优势在于过零点时延测量的算法简单、计算量小,适用于对实时性要求较高的测量场合。     

Competitive removal of Pb2+, Cd2+, and Zn2+ by poly(acrylamide‐co‐maleic acid) hydrogels/differential pulse polarographic determination

Poly(acrylamide‐co‐maleic acid) [P(AAm/MA)] hydrogels, with various compositions, were prepared from ternary mixtures of acrylamide (AAm)/maleic acid (MA)/water by using ⁶⁰Co γ‐rays. The effect of composition of these hydrogels, on the competitive removal of Pb²⁺, Cd²⁺, and Zn²⁺ ions from aqueous solution, was investigated. The hydrogel compositions and their adsorption behaviors were determined by use of differential pulse polarography, a very sensitive electroanalytical technique. It was observed that the external stimuli of pH, temperature, and ionic strength have an important role on the adsorption. The increments of MA content in P(AAm/MA) hydrogels caused a significant increase in the adsorption these ions. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2401–2406, 2004     

Polyamide‐reinforced ethylene–propylene–diene rubber compatibilized with chlorinated polyethylene

Vulcanizates of blends of ethylene–propylene–diene rubber and polyamide copolymers were prepared by reactive compatibilization. A reactive route was employed for compatibilizing these blends with the addition of chlorinated polyethylene (CPE). The influence of the compatibilizers, crosslinking agents, blend compositions, and addition modes of the compatibilizers on the mechanical properties of the blends was investigated. The morphologies of the blends were determined with scanning electron microscopy. The addition of CPE was found to reduce the particle size of the dispersed phase remarkably. The stability of the blends with compatibilizers was measured by high‐temperature thermal aging. The mechanical properties were examined by stress–strain measurements and dynamic mechanical thermal measurements; the addition of polyamide copolymers caused significant improvements in the tensile properties of these blends.© 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1727–1736, 2003