基于Host Link FINS协议的PLC远程通信

以欧姆龙公司CP1H型号的PLC为应用背景,设计了基于Host Link FINS协议的PLC设备远程监控系统.该文提出了基于串口的远程通信方案,并且详细分析了Host Link FINS协议的结构和指令格式,用MFC实现了监控软件的设计,完成监控软件与欧姆龙PLC的数据通信功能,实现监控软件对PLC的远程监控.经过现场的测试和运行,该监控系统稳定可靠,性能较高.     

La2-xSrxNiO4薄膜的制备及氧敏特性的研究

本实验采用无机盐为原料的溶胶－凝胶法制备了复合氧化物La2-xSrxNiO4薄膜，研究了它的阻温特性和氧敏特性，并采用XRD，SEM，AFM（原子力显微镜）等对该薄膜的结构进行了表征。     

二乙酸亚碘酰苯及羟基对甲苯磺酰氧碘基苯的合成研究

通过碘化苯直接与 2 6 %～ 30 %的过氧化氢溶液和醋酸酐反应 ,合成了二乙酸亚碘酰苯 ,该反应避免直接使用较高浓度的过乙酸 ,且操作简单方便 ,产物收率较好 ,纯度高。同时也可不必分离出二乙酸亚碘酰苯直接加入对甲苯磺酸反应 ,得到羟基对甲苯磺酰氧碘基苯。     

重钙装置改产磷铵反应与尾气洗涤系统设备出现的问题

介绍瓮福磷肥厂重钙(TSP)装置改产DAP后,反应与尾气洗涤系统料浆泵、搅拌器、反应器、洗涤泵、重要阀门在运行中出现的问题及处理措施.     

Synthesis of copolymers of tert‐butyl vinyl ether with maleic and citraconic anhydrides

In the present study, the effects of charge‐transfer complex formation and intramolecular fragmentation (side‐chain lactonization) in radical copolymerization of tert‐butyl vinyl ether (t‐BVE) with anhydrides of maleic (MA) and citraconic (CA) acids and the structure–thermal behavior relationships of the resulting copolymers were examined using the ¹H‐NMR, FTIR, DSC, and TGA analysis methods. It was shown that copolymerization under the chosen conditions proceeded through intramolecular fragmentation with the formation of γ‐lactone units. Side‐chain fragmentation of t‐BVE–MA and t‐BVE–CA copolymers also was confirmed by TGA and DSC analysis. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2455–2463, 2006 2006     

在二辛基磷酸钠的微乳液中金属盐的最大含量

测算了二(2-乙基己基)磷酸钠(NaDEHP)或二(正辛基)磷酸钠(NaDOP)、正辛醇，正辛烷、水和金属盐(CoSO4、NiSO4、FeCl2、CuCl2和CaCl2等)组成的均匀单相微乳液中金属盐水溶液的极限增溶量(Vlim)和金属盐的最大含量(Smax)。相同条件下，NaDOP体系中的Vlim和Smax都比NaDEHP体系巾的高得多，这是因为NaDOP中的正辛基的空间位阻小。     

Specially elaborated thermally induced phase separation to fabricate poly(L‐lactic acid) scaffolds with ultra large pores and good interconnectivity

Poly(L ‐lactic acid) (PLLA) scaffolds with pore diameters from several micrometers to ～300 μm were fabricated by a specially elaborated thermally induced phase separation technique. Two different coarsening protocols, i.e., normal coarsening and multi‐step coarsening were compared in consideration of phase separation and domain growth. A normal coarsening route produced scaffolds with pore size from several micrometers to 150 μm depending on the coarsening time after phase separation, accompanying with the emergence of isolated pores at long time coarsening. Scaffolds with large pores with size up to ～300 μm were fabricated by the two‐step coarsening technique, e.g., the PLLA‐solvent (dioxane/water) system was coarsened at a temperature after phase separation for a period, followed by coarsening at a lower temperature for another period. In parallel with formation of the large pores, the interconnectivity between pores was also improved, which was evidenced by scanning electron microscopy, gelatin solution pervasion, and collagen entrapment. The present technique provides the ability to produce scaffolds with high purity, controllable microstructures, and ease of modification, and hence can be widely used in tissue engineering field. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3336–3342, 2006     

反应过程中升华型催化剂的物性变化(Ⅱ) X—射线衍射结果

对衰化程度不同的升华型催化剂进行了 X—射线衍射测定。发现在使用过程中催化剂比表面迅速减小,但氯化汞-活性炭催化剂的新旧样品中,氯化汞均保持单层分散。但即将废弃的醋酸锌-活性炭催化剂上,醋酸锌的单层分散情况受到破坏,出现了醋酸锌晶相峰。晶相峰的出现可能与后期使用温度偏高引起烧结有关。晶相峰的出现会降低催化活性,使之不得不被废弃。     

治理铬渣的两个关键

铬渣中存在的酸溶性六价铬是解毒效果能否持久的关键，而铬渣中游离氧化镁消化是利用铬渣作建筑材料时必须高度重视的问题，论述了湿法解毒、高温解毒和非熔融的综合利用法等方法，对铬盐行业的铬渣治理有指导作用。     

Raman spectroscopic study of conformational changes in the amorphous phase of poly(lactic acid) during deformation

The conformational distribution change of amorphous poly(lactic acid) (PLA) induced by deformation has been studied using Raman spectroscopy. Spectroscopic features associated with the rotational isomeric states (ttt, ttg′, tg′t, tg′g′) have been established experimentally and supported by normal coordinate analysis. Deformation induced a significant increase in the most favorable tg′t conformation. Based on the relative intensities of Raman-active skeletal modes, a quantitative method has been developed that can be used to elucidate structural changes in a variety of deformed polymer samples. For biaxially oriented PLA films, the overall tg′t conformation increased from the 76% in undeformed sample to a value as high as 92%. The change in conformational distribution in the amorphous phase follows a different trend (76-88%) as compared to the increase in sample crystallinity (0-43%). A large change in amorphous chain conformation occurred at relatively low draw ratios. In contrast, the large change in the degree of crystallinity occurred at higher draw ratios.