铝合金2007的激光焊接

研究了采用高功率Nd:YAG连续激光器焊接铝合金2007的方法和工艺参数。通过观察焊缝截面,发现存在气孔和热裂纹。工艺实验表明,采用填充焊丝AlSi12激光焊接可有效抑制热裂纹的产生。     

热空穴应力下LDD nMOSFET中GIDL电流退化特性研究*

本文通过GIDL电流参数IDIFF对空穴应力下LDD nMOSFET中的GIDL电流退化进行了深入研究。IDIFF是在相同VDG下漏电压VD=1.4V和栅电压VG=-1.4V两种情形下的GIDL电流之差。空穴陷落在栅漏交叠区的氧化层中导致GIDL电流退化。这些陷落的空穴减小了上述两种对称的测试情形下的横向电场差ΔEX从而使得IDIFF表小。从GIDL电流中提取的IDIFF随着应力时间t的增加而减小。IDIFF的退化量ΔIDIFF,MAX与应力时间成幂指数关系：ΔIDIFF,MAX∝tm, m=0.3. 并用热电子应力实验验证了HHS实验中的相关物理机理。     

Ultrasonication‐Induced Self‐Assembled Fixed Nanogap Arrays of Monomeric Plasmonic Nanoparticles inside Nanopores

Monomeric gold (Au) and silver (Ag) nanoparticle (NP) arrays are self‐assembled uniformly into anodized aluminium oxide (AAO) nanopores with a high homogeneity of greater than 95%, using ultrasonication. The monomeric metal NP array exhibits asymmetric plasmonic absorption due to Fano‐like resonance as interpreted by finite‐difference time‐domain (FDTD) simulation for the numbers up to 127 AuNPs. To examine gap distance‐dependent collective‐plasmonic resonance, the different dimensions of S, M, and L arrays of the AuNP diameters/the gap distances of ≈36 nm/≈66 nm, ≈45 nm/≈56 nm, and ≈77 nm/≈12 nm, respectively, are prepared. Metal NP arrays with an invariable nanogap of ≈50 nm can provide consistent surface‐enhanced Raman scattering (SERS) intensities for Rhodamine 6G (Rh6G) with a relative standard deviation (RSD) of 3.8–5.4%. Monomeric arrays can provide an effective platform for 2D hot‐electron excitation, as evidenced by the SERS peak‐changes of 4‐nitrobenzenethiol (4‐NBT) adsorbed on AgNP arrays with a power density of ≈0.25 mW µm^‐2 at 514 and 633 nm. For practical purposes, the bacteria captured by 4‐mercaptophenylboronic acid are found to be easily destroyed under visible laser excitation at 514 nm with a power density of ≈14 mW µm^‐2 for 60 min using Ag due to efficient plasmonic‐electron transfer.     

填充热丝激光窄间隙焊接的实验研究

将填充热丝应用到高光束质量、长焦距的光纤激光窄间隙焊接中,不锈钢母材通过激光加热,镍基焊丝通过电流加热,有效利用复合热源的优势,提高了焊丝过渡稳定性和熔覆效率。通过高速摄像机对送丝过程进行在线观察,分析工艺参数对焊丝过渡的影响。研究不锈钢和镍基合金异种金属窄间隙焊接接头的凝固组织,并对焊缝金属进行元素分布扫描。研究发现,由焊丝电流和送丝速度等工艺参数决定的送丝稳定性是影响填充热丝激光焊接质量的最主要因素。对于窄间隙焊接,采用与间隙宽度相当的离焦光斑激光热导焊,可形成较好的侧壁熔合,由熔融金属曲面和侧壁构成的激光反射是侧壁熔合的主要原因。焊缝冷却速度较快,焊缝金属的凝固组织呈明显的对生生长,在坡口侧壁附近其生长方向与侧壁近似垂直,焊缝不存在宏观偏析。在间隙底部直角处容易出现未熔合现象,采用底部圆弧过渡的U型坡口后,可较好地解决底部未熔合问题,获得了无宏观缺陷的焊接接头。     

Plasmon‐Induced Hot Carrier Separation across Dual Interface in Gold–Nickel Phosphide Heterojunction for Photocatalytic Water Splitting

Precise control of the topology of metal nanocrystals and appropriate modulation of the metal–semiconductor heterostructure is an important way to understand the relationship between structure and material properties for plasmon‐induced solar‐to‐chemical energy conversion. Here, a bottom‐up wet chemical approach to synthesize Au/Ni₂P heterostructures via Pt‐catalyzed quasi‐epitaxial overgrowth of Ni on Au nanorods (NR) is presented. The structural motif of the Ni₂P is controlled using the aspect ratio of the Au NR and the effective micelle concentration of the C₁₆TAB capping agent. Highly ordered Au/Pt/Ni₂P nanostructures are employed as the photoelectrocatalytic anode system for water splitting. Electrochemical and ultrafast absorption spectroscopy characterization indicates that the structural motif of the Ni₂P (controlled by the outer‐shell deposition of Ni) helps to manipulate hot electron transfer during surface plasmon decay. With optimized Ni₂P thickness, Pt‐tipped Au NR with an aspect ratio of 5.2 exhibits a geometric current density of 10 mA cm^?2 with an overpotential of 140 mV. The photoanode displays unprecedented long‐term stability with continuous chronoamperometric performance of 50 h at an input potential of 1.5 V with over 30 days. This work provides definitive guidance for designing plasmonic–catalytic nanomaterials for enhanced solar‐to‐chemical energy conversion.     

DF/HF化学激光器高振动态基频谱线机理分析

在采用冷泵浦反应体系的DF/HF化学激光器中多次观察到了DF分子4-3振动能级跃迁的谱线以及HF分子3-2振动能级跃迁的谱线.给出了几幅典型的光谱图,并理论计算了高振动态基频谱线的增益曲线.实验和理论分析显示,上述高振动态基频谱线并非直接产生于冷泵浦反应,F原子复合和热泵浦反应起到了重要作用.最后讨论了热泵浦反应和链泵浦反应对采用冷泵浦反应DF/HF激光器输出光谱、增益及增益区长度的影响.     

加压热煤气脱硫技术研究初步结果

新建成了一套热煤气脱硫剂试验台架系统,加压流化床操作,已成功地投入运行。进行了钛酸锌脱硫剂的初步试验,并取得了4个循环试验的结果。     

移动多媒体广播复用器自动热备份系统设计

论述了移动多媒体广播前端系统中设计自动热备份系统的重要意义,提出了复用器热自动备份系统的技术要求、系统结构,最后详细介绍了自动热备份的实施原理,包括切换条件以及切换过程中的信息交互和动作过程.     

圆铜线热镀锡生产工艺的探讨

镀锡圆铜线具有多种优良特性,且其生产工艺属于物理加工,具有设备投入低、效率高、操作简单等优点,在电线电缆行业中得到了广泛的应用和发展。圆铜线热镀锡工艺虽然简单,但工序流程较多,如放线、酸洗、水洗、干燥、预热烘干、助焊剂、镀锡、冷却、收线,其中的每个环节控制不当,都可影响到产品的最终质量。随着圆铜线直径的逐渐增大,热镀锡工艺的控制难度也不断加大,直径为0．80～2．54mm圆铜线热镀锡工艺的生产实践表明,只有严格控制每个工序流程,不断分析总结及采取改进措施,才可获得优良的产品质量。     

The characteristics of hot mixed asphalt modified by nanosilica

The objective of this research is to investigate the characteristics of the hot mixed asphalt modified by 2%, 4%, 6%, and 8% nanosilica by weight of binder. Marshall stability, dynamic creep, and indirect tensile tests were used to study effects of nanosilica on performance characteristics of the mixtures. Results showed that nanosilica can improve Marshall stability, resilient modulus, indirect tensile strength, and fatigue life compared to unmodified mixtures. However, the tensile strength ratio parameter in the moisture sensitivity tests indicated a decrease in the resistance of the modified mixtures against moisture damage.