High temperature corrosion mechanisms and effect of alloying elements for materials used in waste incineration environment

Corrosion products on two typical materials, SA213-T12 steel and alloy 625 exposed to the actual combustion gas, were analyzed in addition to laboratory tests for penetration of corrosive matter. It has been clarified that corrosion products of oxides containing a little chlorides and sulphides show lamellar structures and that at the alloy-scale interface, chlorination, sulphidation, and oxidation occur under a low P_O2-high P_Cl2 condition. The formation of scale structures and the effect of corrosion-resistant alloying elements can be explained according to the stability tendencies of metals, chlorides, and oxides in the M-Cl-O equilibrium diagrams. The severity of corrosion environments at the interface is influenced by the penetration extent of corrosive matters through deposits and scales, and the protective effects of oxide films derived from alloying elements play an important role in preventing the corrosion. On the other hand, it has been shown that thermal fluctuation characterized in this kind of environment makes the lamellar scale structures and sometimes breaks and peels off the scale, and thus accelerates the corrosion. On the basis of the above mentioned knowledge, a new corrosion model is presented.     

中厚板在线30通道超声波探伤方法及应用

介绍了柳钢公司在生产锅炉板、压力容器板过程中，曾试用了６种探伤方法；而研制的３０通道在线超声波探伤法不仅可满足国家标准要求，而且能适应生产节奏，并具有快速、准确、简便的特点。     

φ114mm直缘成型焊管机组的研制

简介了研制的φ１１４ｍｍ直缘成型焊管机组的技术性能和工艺特点。与普通辊式成型机组相比，该机组工艺先进，焊管精度高。     

Corrosion resistance of austenitic stainless steel separator for molten carbonate fuel cell

STS310S and SC-STS310S (simultaneously co-deposited chromium and aluminum onto 310S austenitic stainless steel substrate by pack-cementation process) were used as separator materials on the cathode side of a molten carbonate fuel cell. With the STS310S, corrosion proceeded via three steps; a formation step of unstable corrosion product, a protection step against corrosion until breakaway, and an advance step of corrosion after breakaway. The final corrosion product was LiFeO₂ and the loss of mass was 6.5 mg/cm² after a corrosion test of 480 hr at 650°C. The SC-STS310S showed more effective corrosion resistance, however, than did common STS310S. There was especially no corrosion loss on the SC-STS310S after the 480 hr corrosion test. It is anticipated that it will be very useful as an alternative separator on the cathode side off the MCFC in the future.     

高钒高速钢碳化钒形态的数值化分析

针对碳化钒的不同形态,设计出定量分析软件,并利用形状因子K,实现了高钒高速钢不同碳化物形态数值化处理,当K介于0.785～1.000之间碳化钒形态为团球状;K≤0.223,碳化钒呈开花状.高钒高速钢当碳含量达到4.2%时,K为0.86和当量直径D为0.78μm,碳化物呈团球状均匀分布.     

混凝土尿素池的腐蚀及防腐蚀措施

本文对混凝土尿素池的腐蚀原因、规律及影响因素进行了阐述，提出了混凝土尿素池的腐蚀及防腐蚀措施，延长了设备的寿命，保证了尿素生产的正常运转。     

ZL114铝合金激光--龟弧的复合焊接

设计了一种激光-电弧复合热源焊接ZL114合金的新工艺，并对焊后的试件进行了X光检测、抗拉强度和全相组织等实验。结果表明，该种新工艺对铝合全有良好的适应性和可行性，是焊接领域的一个趋势。     

12Cr2MoWVTiB钢焊后热处理工艺改进的研究

研究了焊后热处理保温时间对12Cr2MoWVTiB钢的显微组织及力学性能的影响。结果表明,在其它条件不变的情况下,焊后热处理保温时间由原来1.5h缩短为1h,既可以满足其组织性能的要求,又缩短了生产周期,降低了生产成本。     

新型冷轧(拔)无缝钢管高分子润滑工艺研究

提出了冷轧(拔)无缝钢管高分子润滑工艺。研究了该工艺的PL膜各种特性。介绍了工业实验情况。实验证明,高分子润滑工艺完全满足冷轧(拔)钢管工艺要求,并具有操作简便、环境污染小等优点,完全可以代替传统的磷化-皂化润滑工艺。     

工程机械用800MPa低合金高强度钢焊接接头断裂韧性评价

对调质状态800MPa低合金高强度钢及其焊接接头进行了系列温度的断裂韧性测试,讨论不同焊接方法对焊接接头断裂韧性的影响。发现板材的轧制方向对断裂韧性影响显著,LT方向试件的断裂韧性远超过TL方向试件的断裂韧性。在-60℃以上,母材处于上平台延性断裂范畴。在-80℃,裂纹扩展过程中有延脆断裂模式的转变。焊条电弧焊焊缝的断裂韧性与气体保护焊焊缝的断裂韧性相当。尽管常温下焊缝金属的断裂韧性甚至优于母材,但随着试验温度的降低,焊缝金属的断裂韧性迅速下降。在-20℃已发生断裂模式转变,这在结构服役时要引起重视。本研究为大型工程机械的断裂安全评定奠定了基础。