环流式碳化塔研究与操作实践

遵循过程不冷却,结晶为控制过程等工艺原则、操作理论和技术路线,在 164×3620环流式碳化塔中分别进行了联合制碱法和氨碱法母液的碳酸化重碱结晶过程模拟试验,介绍了主要条件试验和连续运转120h的试验数据,讨论了晶浆浓度、操作过饱和度、液体环流速度、结晶温度和溶液碳化度等结晶过程工艺参数,考察了二氧化碳吸收传质总系数并比较了塔的二氧化碳吸收容积能力和重碱结晶容积能力,测定了碳酸氢钠平均结疤速度。     

Toughening of vinylester–urethane hybrid resins through functionalized polymers

Liquid nitrile rubber, hyperbranched polyester, and core/shell rubber particles of various functionality, namely, vinyl, carboxyl, and epoxy, were added up to 20 wt % to a bisphenol‐A‐based vinylester–urethane hybrid (VEUH) resin to improve its toughness. The toughness was characterized by the fracture toughness (K_c) and energy (G_c) determined on compact tensile (CT) specimens at ambient temperature. Toughness improvement in VEUH was mostly achieved when the modifiers reacted with the secondary hydroxyl groups of the bismethacryloxy vinyl ester resin and with the isocyanate of the polyisocyanate compound, instead of participating in the free‐radical crosslinking via styrene copolymerization. Thus, incorporation of carboxyl‐terminated liquid nitrile rubber (CTBN) yielded the highest toughness upgrade with at least a 20 wt % modifier content. It was, however, accompanied by a reduction in both the stiffness and glass transition temperature (T_g) of the VEUH resin. Albeit functionalized (epoxy and vinyl, respectively) hyperbranched polymers were less efficient toughness modifiers than was CTBN, they showed no adverse effect on the stiffness and T_g. Use of core/shell modifiers did not result in toughness improvement. The above changes in the toughness response were traced to the morphology assessed by dynamic mechanical thermal analysis (DMTA) and fractographic inspection of the fracture surface of broken CT specimens. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 672–680, 2002; DOI 10.1002/app.10392     

优化甲醇工艺操作 提高产品质量

本文介绍了甲醇三塔精馏的产品质量控制及其影响因素 ,并提出了常压塔负压的处理方法。     

多周期多原料的供应链网络成本优化及其混合遗传算法

建立并求解一个基于成本最小的供应链网络模型.与以往研究不同,在该模型中生产一种产品需要至少两种原料,每种原料都可以由备选供应商提供.根据模型的特点,用0、1代表对原材料供应商、工厂和分销中心的选择情况,以MATLAB 7.6为平台,运用Sheffield大学的遗传算法工具箱,将遗传算法与线性规划算法相结合,实现了模型的求解.算例结果表明,给出的染色体编码方案正确,混合遗传算法有效,能解决多周期、多原料的供应链网络成本优化问题.还探讨了需求和距离变化,以及需求随机时对最优成本和最优个体的影响.研究表明,需求变化的影响大于距离变化的影响,需求随机对最优成本和最优个体的影响不大.     

A multiobjective hybrid ant colony optimization approach applied to the assignment and scheduling problem

The assignment and scheduling problem is inherently multiobjective. It generally involves multiple conflicting objectives and large and highly complex search spaces. The problem allows the determination of an efficient allocation of a set of limited and shared resources to perform tasks, and an efficient arrangement scheme of a set of tasks over time, while fulfilling spatiotemporal constraints. The main objective is to minimize the project makespan as well as the total cost. Finding a good approximation set is the result of trade‐offs between diversity of solutions and convergence toward the Pareto‐optimal front. It is difficult to achieve such a balance with NP‐hard problems. In this respect, and in order to efficiently explore the search space, a hybrid bidirectional ant‐based approach is proposed in this paper, which is an improvement of a bi‐colony ant‐based approach. Its main characteristic is that it combines a solution construction developed for a more complicated problem with a Pareto‐guided local search engine.     

移动混合开发框架

针对现有混合开发框架在开发便利性和应用性能方面的不足,研究了以HTML5开发为基础的移动混合开发框架的问题.结合HTML5跨平台特性、打包机制、多窗口管理机制、原生插件开发技术等,实现了一套自有的混合开发框架.本混合开发框架为开发带来了便利,提升了开发效率,同时,混合引擎中独特实现的Widget应用管理以及窗口管理模式也改善了混合应用的性能,提升了用户体验.我公司实现的企业级移动解决方案表明该框架性能较好,易于使用,具有较好的商业价值.     

New anion exchanger organic–inorganic hybrid materials and membranes from a copolymerof glycidylmethacrylate and γ‐methacryloxypropyl trimethoxy silane

Organic–inorganic hybrid materials and mem branes were prepared through coating on Teflon plate or dip‐coating on microporous alumina substrates with the solution of glycidylmethacrylate (GMA) and γ‐methacryloxypropyl trimethoxy silane (γ‐MPS) copolymer, followed by ring‐opening of the GMA moiety with trimethylamine hydrochloric and sol–gel reaction of the γ‐MPS moiety. Composition of the GMA and γ‐MPS copolymer was varied by changing the feed ratio of GMA to γ‐MPS during the copolymerization. So the thermal stability, hydrophilicity, electrical properties, etc. of the hybrid materials and membranes were varied. Results showed that as the γ‐MPS amount increased in the copolymer, T_d (the temperature on thermogram at 5% weight loss) value of the hybrid materials and water contact angle of the hybrid membrane generally increased, while the anion exchange capacity, water uptake (W_R) and pure water flux decreased. The charge transition point of the hybrid membranes deduced from their streaming potential behavior decreased from pH > 12 to pH = 7–8 as the γ‐MPS amount increased. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3580–3589, 2006     

基于同构多核处理器的任务调度

随着现代应用对计算机性能要求的提高,计算机主频不断提升。由于功耗和半导体工艺的限制,仅靠提高单核主频难以继续维持“摩尔定律”,同构多核处理器（Homogeneous Multi-core）应运而生。在同构多核处理器的支持下,一个芯片汇集多个地位对等、结构相同的通用处理器核,以最小的代价满足了提高系统性能、负载均衡、处理器容错的需要。并行体系结构需要结合与之适应的软件实现性能效益的倍增。本文从操作系统层面,针对处理器结构的变化,研究并实现多核任务调度。系统采用混合调度策略,簇间独立调度,簇内统一调度。从调度模式、调度算法、分配算法、调度时机等方面详细分析了多核调度的原理和实现机制。最后通过模拟实验证明功能正确性及算法可调度性。     

冷却塔修复与改造的技术经济分析

评述辽河化肥厂配套公用工程设施－美国玛利６００型７格塔冷却修复与改造项目的技术经济分析，叙述了该冷却塔现状，并据此拟定出的经济面实效的分期改造方案。     

水性核（PMMA）／壳（PU）聚氨酯丙烯酸酯杂化乳液的合成研究

合成高Tg低成膜温度的水性聚氨酯丙烯酸酯杂化乳液,研究了合成工艺、—N CO和—O H的比例、丙烯酸酯含量等因素对乳液稳定性和其他性能的影响。