离子迁移率测量装置研制及其在不同温、湿度下的变化规律

离子迁移率是直流输电线路离子流场计算的关键参数。为研究不同温、湿度条件下离子流场中的离子迁移率变化规律,在分析推导Gerdien离子迁移率测量原理的基础上,提出了一种在常规Gerdien管传感器两端设置屏蔽电极来抑制外部合成电场对测量区电场畸变效应的方法,研制出一套直流输电线路合成电场离子迁移率测量传感器及测控装置。在人工气候室中,搭建了直流输电线路离子流场模拟试验平台,对测量装置的适用性进行了验证。试验表明:常温常湿条件下正、负离子迁移率分别为1.25 cm2/(V·s)和1.59 cm2/(V·s);温度变化范围为10~40℃、湿度变化范围为3~25 g/m3时,正、负离子平均迁移率呈现出随温度增大而减小,随绝对湿度增大而减小并趋于饱和的变化规律,满足指数变化的拟合公式。分析指出:轻、重离子浓度比例变化与离子的水合反应程度为其变化原因。该研究工作可为直流输电线路离子流场的准确预测提供参考。     

Co-processing as a tool to improve aqueous dispersibility of cellulose ethers

Cellulose ethers are important materials with numerous applications in pharmaceutical industry. They are widely employed as stabilizers and viscosity enhancers for dispersed systems, binders in granulation process and as film formers for tablets. These polymers, however, exhibit challenge during preparation of their aqueous dispersions. Rapid hydration of their surfaces causes formation of a gel that prevents water from reaching the inner core of the particle. Moreover, the surfaces of these particles become sticky, thus leading to agglomeration, eventually reducing their dispersion kinetics. Numerous procedures have been tested to improve dispersibility of cellulose ethers. These include the use of cross-linking agents, alteration in the synthesis process, adjustment of water content of cellulose ether, modification by attaching hydrophobic substituents and co-processing using various excipients. Among these, co-processing has provided the most encouraging results. This review focuses on the molecular mechanisms responsible for the poor dispersibility of cellulose ethers and the role of co-processing technologies in overcoming the challenge. An attempt has been made to highlight various co-processing techniques and specific role of excipients used for co-processing.     

养护温度对高掺量粉煤灰水泥浆体水化的影响

从胶凝材料的水化程度、浆体孔结构以及水化产物的角度出发,研究温度发展历程对高掺量粉煤灰水泥浆体的作用机理.结果显示:采用温度匹配养护后,前期粉煤灰反应程度和浆体的碱含量消耗加快,而后期影响较小;水化产物较标准养护方式无论从形貌上还是成分上都有一定区别,但随着龄期发展,这种区别逐渐变小;温度匹配养护方式对高掺量粉煤灰水泥浆体孔结构的优化有利.     

活化方式对CFBC脱硫灰自硬化性能的影响

通过物理粉磨、化学激发和物理-化学联合激发3种方式系统研究了循环流化床锅炉燃烧脱硫灰(CFBC脱硫灰)物理力学性能的变化规律,并采用水化热,FTIR,XRD和SEM测试方法分析了活化方式对CFBC脱硫灰自硬化水化历程及性能的影响机理.结果表明:物理粉磨、化学激发和联合活化均提高了脱硫灰的自硬强度及水化反应程度,且降低了需水量比.与原状CFBC脱硫灰相比,粉磨后试样需水量比降低了13％(质量分数),7,28d抗压强度分别提高了210.0％,25.4％;改性剂A,B加入后混磨试样需水量比降低了19％,7,28 d抗压强度各自提高了337.0％,96.5％.在相同的A掺量下,CFBC脱硫灰与A混合后混磨试样的强度效果优于粉磨后A的外加.CFBC脱硫灰的主要水化产物为AFt,Ca(OH)2,CaSO4·2H2O,C-S-H凝胶.     

基于点阵式测量的混凝土箱梁水化热温度场原位试验

在混凝土箱梁模型上布设479个温度测点,对箱梁在水化热期间的温度变化规律进行精密测量。通过德洛内三角网格算法,建立用于混凝土箱梁温度测量的温度传感器点阵,绘制箱梁全截面在水化热期间的温度场云图,进而分析混凝土箱梁的水化热温度发展规律。研究结果表明：箱梁的水化热温度场基本呈对称分布,其中腹板水化热温度变化最大,最高温度为64.8℃,顶板、底板与腹板的最大平均温升比值约为1∶1.1∶1.4;底板水化热温度最先达到峰值,为混凝土浇筑后11h;腹板的平均温度峰值出现在浇筑后12h;顶板温度峰值相对滞后,为混凝土浇筑后13h;箱梁各板沿厚度方向的水化热温度服从高斯分布形式;顶板、底板沿宽度方向水化热温度呈双峰对称分布,服从二项组合式的高斯分布模型,而腹板的水化热温度沿板高可认为常量。此外,文中给出了箱梁模型关键位置在水化热期间的温度数据,可用于指导混凝土箱梁水化热温度试验的测点布置,并且为箱梁的水化热温度控制和设计提供参考。     

Indentation deformation and cracking behavior of hydrated aluminoborate glasses

Aluminoborate glasses have recently been found to feature high resistance to crack initiation during indentation due to a highly flexible network structure. In cesium aluminoborate glasses, it has been found that the use of a simple post-treatment, namely aging in a humid atmosphere, can further improve this resistance. To better understand the mechanical properties of this glass family upon humid aging, we here study the effect of aging conditions on the structure and mechanical properties of Li,K,Cs-aluminoborate glasses. As expected, we find that higher humidity and longer aging time cause more pronounced permeation of atmospheric water into the glasses. Due to their denser structure and stronger modifier-oxygen bonds, the humid aging has a relatively smaller effect on the mechanical properties of Li- and K-containing glasses relative to Cs-containing glasses, with the latter achieving an ultrahigh crack resistance. We find that the humid aging leads to the formation of a hydration layer in the Cs-aluminoborate glass surface, with a thickness of around 26 μm upon aging at 23 °C with 40% relative humidity for 7 days. Moreover, a remarkable indentation behavior, that is, the observation of μm-sized shear bands inside the imprint of the Cs-glass upon aging at 60% relative humidity is reported. Taken as a whole, the work provides guidelines for how to control the humid aging rate as a function of relative humidity and temperature to form a hydration layer and thus achieve improved crack resistance in such glasses.     

Glass with hydration-induced compressive stress profiles

A novel potassium phospho-aluminosilicate composition is described that can be strengthened by water vapor to achieve deep compressive stress (CS) profiles. Water vapor treatment at (A) 85°C and 85% relative humidity for 40 days results in a CS of 389 ± 20 MPa and a compressive depth of layer (DOL) of 18 ± 2 μm. When treated at (B) 160°C and 0.1 MPa for 7 days, a CS of 245 ± 20 MPa and a DOL of 40 ± 2 μm is achieved. Glasses with hydration-induced stress profiles can provide high retained strength following flaw introduction compared with ion-exchanged soda-lime silicate glass. Sample treatment B also has an exemplary Vickers indentation cracking threshold value greater than 20 kgf. The hydration profile determined by secondary ion mass spectrometry (SIMS) is shown to closely match the stress profile for these samples. SIMS analysis also shows that the depth of water enrichment correlates well with the depletion depth of phosphorus. The high tendency towards water-induced strengthening for this new type of glass even enables self-strengthening by the generation of a near-surface CS profile following exposure to ambient conditions.     

Biomolecular Structure and Dynamics with Neutrons: The View from Simulation

The characterization of the structure and internal dynamics of biomolecules is essential to understanding their biological function. Neutron scattering probes similar time- and length-scales to molecular dynamics simulation. Hence, simulation models of biomolecules have become invaluable in the interpretation of experimental neutron data. Here, we report on advances in the application of simulation in developing neutron scattering to investigate internal protein motions and, as an example of industrial relevance, in the derivation of physical models of use in biofuel renewable energy research.     

激光共聚焦原位观察水泥早期水化(英文)

采用激光共聚焦显微镜对水泥早期水化过程进行原位观察,样品尺寸为35mm×25mm×5mm的水泥压实体,通过滴加水使压实体中的水泥水化。结果表明:压实体的水化对于正常水泥浆体的水化有着很好的参考作用;压实体样品与水接触8h,表面生成大量的水化产物,水化16h,大部分孔洞被水化产物填充,水化1d,水泥水化到达稳定期,微结构逐渐变密实。