Adhesion and Hydrolytic Stability of the Interface Between High-Modulus Polyethylene Fibers and Acrylic Resins

The effects of oxyen plasma treatment on the surface chemistry of Spectra 1000® high modulus polyethylene fibers and on the mechanical properties of fiber-reinforced composites of the fibers in a Bis-GMA based acrylic resin have been studied. X-ray photoelectron spectroscopy and diffuse reflectance FTIR spectroscopy have been used to show that the majority of oxygen on the fiber surface exists mostly in the form of ether and/or epoxy linkages, with carbonyl-, carboxylic- and ester-containing compounds accounting for less than 10 percent of the total. While the untreated and plasma-treated fibers have similar chemical compositions, the surfaces of the plasma-treated fibers are more polar and the oxygen is chemically bonded instead of being merely physisorbed. The interfacial shear strength between the fibers and the acrylic resin is increased by a factor of 2.3 by the plasma treatment indicating the presence of a weak boundary layer on the surface of the untreated fibers. The hydrolytic stability of the composite interfaces was investigated for fibers sized with several Bis-GMA-based adhesives. Maximum stability was attained by sizing with Bis-GMA containing a peroxide catalyst or an amine accelerator. The flexural properties of composites utilizing plasma-treated and untreated fibers were compared in three-point bending. The ultimate bending loads for composites using treated fibers were much higher than those for composites with untreated fibers, but only a fraction of that for glass or Kevlar®-reinforced materials.     

易水解聚酯的热性能

用PTA法合成了一系列易水解聚酯(EHDPET)。采用DSC和TGA技术系统分析了SIPE、IPA、脂肪族化合物(A)等各组分含量对其热性能的影响。结果表明:tg、tcc(冷结晶温度)随SIPE含量的增加而升高,tm、tmc(热结晶温度)则下降;IPA的加入使tg、tm、tmc均下降,而tcc升高;随脂肪族化合物(A)含量的增加,tcc、tg下降。随SIPE、脂肪族化合物(A)含量的增加,EHDPET的热稳定性变差。     

环氧乙烯基酯树脂 (Ⅱ)环氧乙烯基酯树脂在酸、碱、盐溶液中的稳定性

较为详细论述了影响环氧乙烯基酯树脂在酸、碱、盐溶液中稳定性的各种结构因素。     

Treatment of methanol wastewater with two-stage and two-phase anaerobic process

The two-stage and two-phase anaerobic process (TSTP) composed of hydrolytic acidification reactor,first-order and second-order external circulation anaerobic reactors (EC) was taken to treat methanol wastewater. Test results show that TSTP process is quick start-up in 51 d, and the maximum VFA of hydrolytic acidification reactor effluent reaches 876 mg/L. Under the condition of volume loading of 6.56 kgCOD/m3·d, COD removal rate of the first-order EC reactor is about 85%, and under the condition of volume loading of 1.02 kgCOD/m3·d, COD removal rate of the second-order EC reactor is about 50%. When the inflow COD of TSTP process is between 7000-11000 mg/L, its effluent COD is lower than 600 mg/L. In the biological conversion process of methanol into methane,the production of acetic acids as an intermediate product can be ignored and the direct production of methane from methanol is predominant.     

HABR反应器处理高质量浓度有机废水

目的 研究采用复合式折流板反应器(HABR)处理可生化的高质量浓度有机废水,为处理高质量浓度有机废水提供费用低、效果好的反应器.方法 对各个隔室及整个反应器的污水处理效果,反应器内的污泥特性,反应器内碱度和酸化关系进行试验.结果 HABR反应器污泥产率低,并且能形成一定量的颗粒污泥,污泥不易流失,能在HABR反应器内保持高的污泥量,HABR反应器在HRT(水力停留时间)为36 h,COD容积负荷(VLR)为10 kg/(m3·d),进水pH=7.0时,对CODcr依然有很高处理效果,其CODcr去除率稳定在95%左右.结论 带有填料的HABR反应器无论在启动过程和稳定运行阶段都表现出比ABR更好的效果,具有更高的稳定性.     

分区进水对ABR水解酸化效果影响的研究

试验采用四格室厌氧折流板反应器（ABR）,以单侧进水ABR对比研究了四点进水方式对ABR反应器的水解酸化功能的影响.结果表明,分区进水方式增强了ABR反应器的水解酸化功能,出水中VFA主要以甲酸、乙酸为主,COD的去除率高于单侧进水ABR。     

海洋酸化研究进展

介绍了海洋酸化的原因及目前研究的一些进展。随着人类向大气中大量排放二氧化碳,引发了温室效应和海洋酸化等环境问题,海洋酸化将会导致海水碱度升高从而溶解更多的二氧化碳,还会导致海洋生物链发生变化,加快海洋生物数量的退化速度,并且海洋酸化会加剧一些全球气候问题。     

Monolithically integrated CoP nanowire array: An on/off switch for effective on-demand hydrogen generation via hydrolysis of NaBH<Subscript>4</Subscript> and NH<Subscript>3</Subscript>BH<Subscript>3</Subscript>

The issues of hydrogen generation and storage have hindered the widespread use and commercialization of hydrogen fuel cell vehicles.It is thus highly attractive,but the design and development of highly active non-noble-metal catalysts for on-demand hydrogen release from alkaline NaBH4 solution under mild conditions remains a key challenge.Herein,we describe the use of CoP nanowire array integrated on a Ti mesh (CoP NA/Ti) as a three-dimensional (3D) monolithic catalyst for efficient hydrolytic dehydrogenation of NaBH4 in basic solutions.The CoP NA/Ti works as an on/off switch for on-demand hydrogen generation at a rate of 6,500 mL/(min.g) and a low activation energy of 41 kJ/mol.It is highly robust for repeated usage after recycling,without sacrificing catalytic performance.Remarkably,this catalyst also performs efficiently for the hydrolysis of NH3BH3.     

HA-BAF一体式工艺处理炼油废水

采用水解酸化-好氧一体式生物滤池处理炼油废水。研究结果表明，该反应器对COD、Ar-OH、NH3-N和油类具有良好的去除效果，出水的COD、At-OH、NH4-N和油含量都低于《污水综合排放标准》（GB8978-1996）中的一级排放标准。     

水解酸化-SBR法处理米粉厂废水工程实践

介绍了水解酸化—SBR法处理米粉厂生产废水的工程实例．经过两年多的连续运行，处理效果稳定．多次监测结果表明：出水CODcr达到77．1mg／L，BOD5达到24．3mg／L，SS达到20．6mg／L，其去除率达到90％以上，完全达到国家规定的《污水综合排放标准》(GB8978—96)的新改扩一级标准．