全文获取类型
收费全文 | 11467篇 |
免费 | 1253篇 |
国内免费 | 105篇 |
专业分类
电工技术 | 15篇 |
综合类 | 292篇 |
化学工业 | 4911篇 |
金属工艺 | 71篇 |
机械仪表 | 113篇 |
建筑科学 | 209篇 |
矿业工程 | 32篇 |
能源动力 | 154篇 |
轻工业 | 6288篇 |
水利工程 | 35篇 |
石油天然气 | 177篇 |
武器工业 | 1篇 |
无线电 | 50篇 |
一般工业技术 | 307篇 |
冶金工业 | 62篇 |
原子能技术 | 30篇 |
自动化技术 | 78篇 |
出版年
2024年 | 69篇 |
2023年 | 208篇 |
2022年 | 399篇 |
2021年 | 546篇 |
2020年 | 413篇 |
2019年 | 424篇 |
2018年 | 381篇 |
2017年 | 440篇 |
2016年 | 480篇 |
2015年 | 492篇 |
2014年 | 569篇 |
2013年 | 748篇 |
2012年 | 776篇 |
2011年 | 738篇 |
2010年 | 535篇 |
2009年 | 533篇 |
2008年 | 522篇 |
2007年 | 621篇 |
2006年 | 507篇 |
2005年 | 401篇 |
2004年 | 360篇 |
2003年 | 318篇 |
2002年 | 289篇 |
2001年 | 219篇 |
2000年 | 276篇 |
1999年 | 192篇 |
1998年 | 207篇 |
1997年 | 122篇 |
1996年 | 152篇 |
1995年 | 131篇 |
1994年 | 108篇 |
1993年 | 106篇 |
1992年 | 120篇 |
1991年 | 100篇 |
1990年 | 60篇 |
1989年 | 43篇 |
1988年 | 29篇 |
1987年 | 37篇 |
1986年 | 35篇 |
1985年 | 24篇 |
1984年 | 24篇 |
1983年 | 12篇 |
1982年 | 9篇 |
1981年 | 8篇 |
1980年 | 14篇 |
1979年 | 5篇 |
1978年 | 6篇 |
1976年 | 6篇 |
1975年 | 3篇 |
1974年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 78 毫秒
91.
92.
The electrochemical reduction of 2-hydroxy-5-[(4-sulfophenyl)azo]benzoic acid, 2-hydroxy-5-[(3-sulfophenyl)azo]benzoic acid, 2-hydroxy-5-[(2-sulfophenyl)azo]benzoic acid and 2-hydroxy-5-azo-benzoic acid has been carried out in aqueous solutions at glassy carbon electrode using cyclic voltammetry and chronoamperometry. The position of sulfo substituent relative to azo bridge as well as pH of the solution have significant impact on the electrochemical behavior of these compounds. It has been proposed that these compounds are reduced predominantly as hydrazone tautomers resulting in corresponding hydrazo compounds. The overall electrochemical reduction follows DISP2 mechanism, ultimately leading to the 5-amino salicylic acid and sulfanilic acid. The rate determining step is the homogenous redox reaction between intermediate hydrazo compound and 5-amino salicylic acid quinoneimine. The mechanism is proposed in which activated complex of 5-amino salicylic acid quinoneimine and intermediate hydrazo compound is formed with the simultaneous loss of one proton. 相似文献
93.
94.
95.
Henry?S.?Lam Andrew?ProctorEmail author 《Journal of the American Oil Chemists' Society》2003,80(6):563-567
The changes in milled rice FFA content and composition and in conjugated diene (CD) content and bacterial, yeast, and mold
counts were determined at 24, 37, and 50°C and 70% RH over 50 d. There was a rapid rate of FFA formation during the first
few days of storage, which was optimal at 37°C, but that slowed after 2, 4, and 5 d at 37, 24, and 50°C, respectively. There
was a second increase in FFA after about day 12 that increased with increasing temperature, indicating nonlipase hydrolysis.
Linoleic and oleic acids were the main components of the total FFA produced on the surface of milled rice. The pattern of
CD development followed that of FFA increase. Bacterial growth correlated with increased FFA levels after 12 d of storage,
suggesting that bacterial lipase rather than bran lipase may be responsible for rice lipid hydrolysis 相似文献
96.
The insecticidal nonprotein amino acid S-(-carboxyethyl)-cysteine (S-CEC) is the major free amino acid in the seeds of severalCalliandra spp. where it accounts for up to 2.9 % of dry weight. Lesser amounts of other related S-containing amino acids and an array of nonprotein imino acids derived from pipecolic acid are other constituents. High concentrations of imino acids, which also show insecticidal activity, are maintained in the mature leaves, but sulfur compounds are lacking. In this study the disappearance of S-CEC from the germinating seeds and young seedlings ofC. rubescens was monitored over time. After 10 weeks, S-CEC continues to be found in high concentrations in the stems and new leaves. As young leaves mature, sulfur compounds quickly decrease in concentration. Traces of S-CEC are found in new leaves of plants up to nine months after germination. Whether high concentration of S-CEC in young leaves is due to transportation from the seed or de novo synthesis is unclear. The ecological implications are discussed. 相似文献
97.
We identified many novel oxygenated FA produced from linoleic acid by microbial strain ALA2: 12,13,17-trihydroxy-9(Z)-octadecenoic
acid (12,13,17-THOA); 12,13,16-trihydroxy-9(Z)-octadecenoic acid (12,13,16-THOA); 12-hydroxy-13,16-epoxy-9(Z)-octadecenoic
acid; and 12,17;13,17-diepoxy-16-hydroxy-9(Z)-octadecenoic acid. 12,13,17-THOA, the main product, inhibits the growth of some
plant pathogenic fungi. Recently, we reclassified strain ALA2 as Bacillus megaterium ALA2 NRRL B-21660 and opened a possible link with the well-studied catalytically self-sufficient P450 monooxygenase of Bacillus megaterium ATCC 14581 (NRRL B-3712) and B. subtilis strain 168 (NRRL B-4219). Now we have found that strain ALA2 also oxidizes palmitic acid into three oxygenated products:
13-, 14-, and 15-hydroxy palmitic acids. This indicates that strain ALA2 also possesses a monooxygenase system similar to
the abovementioned well-known strains. These data facilitate studies on the oxygenase system of strain ALA2. 相似文献
98.
J. F. Toro-Vazquez Alejandro Rocha-Uribe 《Journal of the American Oil Chemists' Society》1993,70(6):589-594
The adsorption of peroxides, unsaturated carbonyls, free fatty acids and carotenoids from unrefined sesame oil on vegetable
carbon (5%, w/w) in a miscella system was studied. Three different solvent conditions (hexane/ethanol, 100:0, 95:5 and 75:25,
vol/vol), combined in a factorial design with five levels of solvent (0, 10, 20, 30 and 40%, w/w), were used to develop the
miscella. Equilibrium adsorption was not achieved during the 100 min of adsorption, mainly because the oil components were
involved in oxidation reactions during the adsorption process. However, for a given solvent concentration, adsorption of the
oil components showed a significant linear regression on their respective initial concentration in the miscella (Ci). Peroxides and carbonyls showed, at all solvent levels investigated, an affinity for the carbon more independent of their
Ci than free fatty acids and carotenoids. In general, at the same Ci, a higher adsorption was achieved as solvent concentration increased. The results indicated that free fatty acid adsorption
may depend on competitive adsorption based on molecule hydrophobicity. However, in spite of the higher hydrophobicity of carotenoids,
compared with free fatty acids, they might not be competing for the same adsorbing sites. Ethanol showed a prooxidant effect
that increased peroxide production during adsorption but did not affect the reaction involved in carbonyl production. 相似文献
99.
Investigation of the effects of fatty acids on the compressive strength of the concrete and the grindability of the cement 总被引:1,自引:0,他引:1
In cement industry, a great energy consumption has been observed during grinding of clinker. To reduce this consumption, some waste products have been used as grinding aids.In this investigation, the effects of sunflower oil (SO), oleic acid (OA), stearic acid (SA), myristic acid (MA) and lauric acid (LA) on the fineness and strength of the cement have been examined. These aids were added into clinker in certain ratios based on the cement clinker weight and the grinding has been done for a definite time at the same condition.All of the fatty acids used increased the fineness as compared with the cement without the grinding additives. SO and OA decreased the strength significantly, LA decreased it to a lesser extent and SA increased it definitely according to the common cement. But MA did not alter the strength of the cement as much as SA. In addition, the covering of the balls influences the grinding of cement clinker unfavourably. 相似文献
100.
Peter?S.?Piispanen Bj?rn?Hedman Torbj?rn?NorinEmail author 《Journal of surfactants and detergents》2002,5(2):165-168
The syntheses of derivatives of dehydroabietic acid suitable for further manipulation into surfactants are presented. The
compounds are produced at very high yields and purity. They contain several different functional groups, e.g., carboxylic
acid, amine, ester, alcohol, and an aromatic group. The functional groups are useful as the linking unit to the hydrophilic
part in synthesizing surfactants. 相似文献