Lamellar arrangements of linear polyethylene in ultrathin films

The crystal orientations of linear polyethylene films on silicon substrates are investigated using grazing incidence X‐ray diffraction and atomic force microscopy. From diffraction analysis, we can identify the structural arrangement of PE crystals in ultrathin film. The orientation of lamellar crystal in PE films changes from edge‐on to flat‐on with the decrease of film thickness in the film thickness below ～ 100 nm. The slightly inclined lamellae relative to the substrate are found to coexist with the flat‐on lamellae in thin PE films that we have investigated. We find that the crystal orientation and structures is governed by the constraint imposed by film thickness rather than enthalpy gain as the film got thinner especially in the thickness below 200 nm. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

UV-cured fluorinated coatings for plastics: effect of the photoinitiator and of the substrate filler on adhesion

A high-performance fluorinated acrylic coating, containing perfluoropolyether chains, was applied to polyethylene and polypropylene by means of the UV-curing technique. The conditions for a good adhesion onto the plastic substrates were studied. A chemical bonding between the cured network and both the substrates was achieved when the photopolymerization was performed in the presence of benzophenone as a photoinitiator: by hydrogen abstraction from the substrate, polymer radicals were formed and could then initiate the polymerization of the acrylic species; grafting experiments of hydroxyethylacrylate confirmed this mechanism. However, the grafting reaction did not take place when the plastic substrates contained carbon black as a filler, which acted as a radical scavenger. In this case, in fact the adhesion results are not good, similar to those obtained in presence of a cleavage-type photoinitiator.     

玻璃粉粒度对复合胶凝材料性能的影响

用激光粒度分析仪测定不同细度的玻璃粉粒度分布,以灰色关联方法( GIA)和扫描电子显微镜( SEM)研究了玻璃粉粒度对复合胶凝材料性能的影响。研究结果表明,玻璃粉中10μm以下的颗粒关联性均为正,说明这些颗粒对复合胶凝材料强度发展有积极贡献,其中以5~10μm的关联度为最大;而?45μm的颗粒呈负关联,其火山灰活性没有得到充分发挥;玻璃粉经适当物理磨细(35 min)后,能更有效地分散到复合胶凝材料的孔隙中,使复合胶凝材料的结构更加密实,从而提高了复合胶凝材料的抗压强度。     

Instantaneous uncut chip thickness modeling for micro-end milling process

The prediction model of instantaneous uncut chip thickness is critical for micro-end milling process, which can directly affect the cutting forces, surface accuracy, and process stability of the micro-end milling process. This paper presents an instantaneous uncut chip thickness model systematically based on the actual trochoidal trajectory of tooth and the tool run-out in micro-end milling process. The variable entry and exit angles of tool, which are affected by the tool run-out, are concerned in the model. The related instantaneous uncut chip thickness is evaluated by considering the theoretical instantaneous uncut chip thickness and the minimum uncut chip thickness, which is formulated by two types of material removal mechanisms, in the elastic-plastic deformation region and the complete chip formation region, respectively. In comparison with the instantaneous chip thickness obtained from the conventional model, the feasibility of the proposed model can be proved by the related simulation results with variable process parameters including feed per tooth, radial depth of cut, and tool run-out. In addition, the predicted and measured cutting forces are compared with validate the accuracy of the proposed instantaneous uncut chip thickness model for the micro-end milling process.     

Correction of GPR wave velocity at different oblique angles between traverses and alignment of line objects in a common offset antenna setting

Estimation of ground penetrating radar's wave velocity in materials is a critical step to accurately estimate depth of embedded line objects in concrete structures, and wetness of material. Errors of velocity are defined as the deviations between the velocities obtained in various oblique angles and those obtained in the traverse normal to the object orientation in a common offset antenna setting. In this paper, we quantified and corrected the errors of such estimation. GPR traverses were designed to travel in various oblique angles θ (90°, 75°, 60° and 45°) relative to the steel bars at 5 cover depths (55 mm, 85 mm, 115 mm, 145 mm and 175 mm). GPR wave velocity at any position within the lateral detection range of steel bars was measured with simple trigonometry in a semi-automated in-house program. It was found that reduction of oblique angles (i.e. θ<90°) causes flatter hyperbolic reflections and the associated errors of velocity can be as much as 30% in the case of an oblique angle 45° before correction. Such errors were corrected after re-scaling the horizontal travel distance with a multiplication factor of sin θ.     

含氟核壳苯丙乳液的合成与涂膜性能研究

以全氟烷基乙基甲基丙烯酸酯(FMA)为含氟单体、可聚合型烯丙氧基壬基酚聚氧乙烯(10)醚硫酸铵(DNS-86)为乳化剂,采用半连续法制备了具有核壳结构的含氟苯丙乳液。采用FT-IR、TEM、TGA分别对共聚物的组成、乳胶粒形态与涂膜热稳定性进行了表征,并对涂膜接触角及耐化学性进行了分析。结果表明,当FMA用量为8.0%时,所得乳液涂膜的水/油接触角分别为111.5°与67.9°,涂膜的耐化学和热稳定性优良。     

新型游动坐标法及其在复杂形状刀具数控磨削中的应用

通过分析复杂形状刀具的几何角度和数控磨削工艺 ,提出一种新型游动坐标系的刀位计算方法 ,应用该方法可简便地进行复杂形状刀具数控磨削的刀位计算 ,并可实现复杂形状刀具几何角度的精确磨削。通过三维仿真及实际磨削加工试验验证了该刀位计算方法的实用性。     

突发性天然气供应中断的应急决策

近年来我国突发性天然气供应中断事件的发生率呈现增长趋势,对我国经济、社会稳定和人们的正常生活带来了严重影响。突发性事件发展过程是一个处于快速变化中的动态过程,信息具有不确定性和模糊性的特征,难以运用单一的方法和模型进行分析和决策。因此,结合Markov预测法、三角模糊数和改进型TOPSIS法,构建了应对突发性天然气供应中断的动态多目标应急决策模型(Markov-TOPSIS模型)。即采用Markov动态预测来反映天然气中断应急决策的动态特性,运用模糊理论以实现专家决策的量化分析,结合灰色关联和TOPSIS方法对应急决策中模糊的、不确定信息进行有效处理,并实现多目标综合评价。最后,以某区域天然气供应中断为例,对该模型进行了验证。结果表明:该模型能够有效处理天然气中断应急决策过程中面临的动态变化、信息模糊和多目标决策问题,可根据突发事件的不同发展阶段选择最优决策方案。     

弹性界面Knott方程表达形式的差异性和统一性

Knott(诺特)方程是地震波传播理论和应用的主要内容,在理论研究和油气勘探等应用领域具有重要意义。同一个弹性界面的边值定解问题在数学上的不同表述方式将导致Knott方程出现多种表达形式。研究结果表明,XOZ平面内,P和SV平面简谐波入射到弹性界面时遵循的Knott方程共有8种独立表达形式,其中纵波和横波各有4种;对于相同类型的平面简谐波入射和相同的入射介质,不同形式的Knott方程可以完全统一于相同表达形式的能量平衡方程。     

Investigation of the chalcogen interdiffusion in CuIn(TeSe)2 thin films

Graded thin films of CuInSe₂ on CuInTe₂ have been obtained by annealing of precursor structures containing Se and Te separated in depth. The depth profile of the phases in the film was investigated using X-ray diffraction with grazing incidence of the primary beam. Quasi-epitaxial growth of CuInSe₂ on a CuInTe₂ film next to the Mo back-electrode was observed after annealing at 450°C in vacuum. Annealing at higher temperature lead to chalcogen interdiffusion resulting in quaternary films. However, heat treatments of already reacted films did not result in any detectable interdiffusion. From these results the mechanisms governing the growth of films from precursors containing the chalcogens Se and Te separated in depth are discussed with respect to their application for thin film solar cells.