Polyethylene mixed crystal infra-red spectroscopy: The influence of matrix isotopic species on guest conformation

The chain conformation of solution-crystallized polyethylene has previously been confirmed by infra-red spectroscopy, using the CD₂ bending bandshape for samples with a minority of the deuterated species^1–3. The method of calculating the i.r. band profile from molecular conformational models is now developed to give a more accurate representation of doublet splittings and to include the singlet component. The CH₂ bending profile is calculated for samples with a deuterated matrix, and the good agreement with experimental data indicates that the same molecular model is applicable for samples with the deuterated polymer as either guest or matrix, for identical crystallization conditions. This result implies that isotopic fractionation is unimportant under these conditions.     

打造现代建筑企业供应链 强化资源整合

根据建筑业产品的特性 ,指出建立供应链的意义及其建立的步骤和实施方法     

供应链管理的研究综述

首先阐述了供应链管理的概念，在此基础之上提出目前供应链的研究框架，并指出供应链管理实践中存在的问题，最后提出未来研究方向。     

大型钢制立式储罐的导链式倒装法施工

介绍了导链式倒装法安装大型钢制立式储罐的原理及制作工艺流程。     

密码学函数迭代原理信息论分析

在密码编码学中,经常利用密码学函数迭代技术来实现密码算法,其所依赖的理论基础包括相关免疫理论,扩散准则,雪崩原理等.本文利用信息论原理以及随机过程理论给出了密码学函数迭代原理分析,得到了经过密码学函数迭代之后,输出为均匀分布时,输入输出互信息极限为零的充分必要条件,以及在一定条件下输入输出互信息收敛速度的一个上界.     

西门子工业控制网络在棒材连轧生产线的应用

本文通过对包钢棒材连轧线的工业控制网络的由分体到整体的介绍,将西门子公司的三级控制网络(Profibus-DP网络、MPI网络、工业以太网)思想做了一个全面的说明.通过与现场实际相结合,使人们对这一概念有了更加清晰的认识.文章最后还结合作者的一些体会作了总结.     

硅酸铋晶体的蚀像形貌

本文研究了提拉法生长的硅酸铋晶体(BSO)的蚀像形貌,比较了{100},{110},{211},{111}面族的腐蚀像特征和腐蚀速度,并用周期性键链(PBC)的形貌理论分析了腐蚀形貌。通过蚀像形貌特征便可方便地进行晶体定向,准确地确定各族晶面之间的相对位置和极轴的方向等。     

Alternating,all-trans polyenynes: Model compounds for poly(diacetylene)s with defined conjugation length

The syntheses of polyenynes as model compounds for poly(diacetylene)s (PDAs) are described. Variation of properties (UV–VIS, Raman, NMR and bond geometries) as a function of the chain length was investigated. After extrapolation to infinite chain length these data were compared to those for PDAs. From UV–VIS spectra a value of λ = 551 nm (2.25 eV) was calculated corresponding to the electronic transition of a single polyenyne chain. This energy is located at the low energy end of a yellow PDA solution spectrum. From Raman scattering v_(C?C) = 2108–2128 cm^?1 and v_(C?C) = 1505–1532 cm^?1 were calculated after extrapolation. Similarly sp-C¹³C NMR data yielded a shift of δ = 100 ppm. These data are almost identical to data known for yellow PDA solutions. Bond geometries are almost identical to those of poly(diacetylene)s and theoretical data.     

C5/C6异构化催化剂的首次工业应用

采用中石化金陵分公司研究院研制的CI-50(Pd/丝光沸石)作C5/C6烷烃异构化催化剂.详细介绍了该催化剂的工业放大试验装置的工艺流程、首次开工过程中技术问题及处理方法.     

Skeleton chain coding for Chinese characters

The compression of Chinese characters is very important for Chinese office automation and desktop publishing. In this paper, various methods are used to compress 13,051 Chinese characters losslessly by coding their skeleton points. The skeleton points are composed of isolated points and curves. To trace every point in a curve once and consecutively is a NP problem. Therefore, we use contour path following and revisiting algorithms to trace skeleton curves with chain codes. The remaining isolated skeleton points are encoded by an Elias code. Our coding method has a better compression rate than that of conventional skeleton coding.