PVC新型改性剂AS的合成与应用

本文主要介绍ＰＶＣ新型改性剂ＡＳ树脂的合成方法、产品性能及其在ＰＶＣ异型材、管材、注射、压延片等加工领域中的应用。实验结果证明：该产品完全可以代替ＡＣＲ加工助剂，并有很好的经济效益。     

基于鲁棒性的链路权重规划算法

在IP网络中,链路权重规划是流量工程中的重要问题。为了优化网络流量并实现负载均衡,针对业务量矩阵的不确定性,依据鲁棒性理论提出一个链路权重规划的MIP模型。该模型使用Γ模型描述业务量矩阵的不确定集,通过表示扰动程度的参数Γ实现了对鲁棒性的调节,在此基础上求得不确定集中最差情况下的最优解。实验结果表明,与传统的链路权重规划方法以及新出现的MRC规划模型相比较,该算法可降低最大链路利用率,分别达到了40%和20%。     

Cold Crystallization of PLLA Studied by Simultaneous SAXS and WAXS

Summary: The cold crystallization process of initially amorphous poly(L ‐lactic acid), PLLA, with two different molecular weights, during a heating at 2 °C/min, was investigated by DSC and time‐resolved simultaneous SAXS and WAXS, using synchrotron radiation. Equatorial scans of the isotropic 2D‐SAXS patterns showed that the average Bragg long period (L_B) of PLLA samples was approximately constant with the development of cold crystallization up to a temperature that corresponded to a melt/re‐crystallization process that took place before the nominal melting peak seen by DSC. L_B values were found to be higher for the high molecular weight material. This was in accordance with the higher melting temperature observed in the high molecular weight PLLA that implied the existence of thicker lamellae. WAXS results showed that the molecular weight did not apparently affect the crystal form and the final degree of crystallinity of PLLA. The Avrami parameters from WAXS and DSC were consistent, showing that the non‐isothermal cold crystallization of the two PLLA samples corresponded mainly to a three‐dimensional growth, although an imperfect crystallization process was involved at early times. The crystallization rate of PLLA, observed both by WAXS and DSC, decreased with increasing molecular weight.

SAXS profiles of PLLA2 as a function of temperature. The inset shows the 2D‐SAXS pattern obtained at 180 °C.     

吸收剂量对二甲基硅橡胶与甲基乙烯基硅橡胶分子量和凝胶含量的影响

将ＧＰＣ和特性粘数［η］测定相结合，在室温和－７８℃下，用Ｃｏ~（６０）辐射源辐照，研究了二甲基硅橡胶（ＭＱ，吸收剂量２．０５×１０~３～３．９７×１０~４Ｇｙ）和甲基乙烯基硅橡胶（ＭＶＱ，吸收剂量１０~２～１０~４）分子量和凝胶含量的变化。结果表明，辐照ＭＶＱ较辐照ＭＱ易生成凝胶，在凝胶点前的较低吸收剂量时，溶胶的分子量出现极大值，分子量分布曲线呈单峰；随吸收剂量的增加，分子量分布变窄，分子量降低；出现凝胶的吸收剂量，ＭＱ大约是ＭＶＱ的１０倍。辐照ＭＱ时，凝胶点前的溶胶的分子量分布曲线为双峰，并随吸收剂量的增加，双峰消失，分子量下降；在凝胶点时，分子量出现极大值。     

不同分子量聚酯的羟值分析方法

用醋酐／高氯酸／乙酸乙酯法，醋酐吡啶回流法，分别对相对分子质量为１１００－１２０００的聚酯进行了羟值的测定，并用气压渗透法和析出物溶解重滴法进行了核对。结果表明醋酐／高氯酸／乙酸乙酯法对于Ｍ〈５０００的聚酯是适用的，而高分子量的聚酯则必须用醋酐／吡啶回流法，才能获得满意的结果。     

Kinetic study on the first stage during thermal degradation of polystyrene

The kinetic parameters of the first stage of polystyrene degradation have been investigated to elucidate the reaction mechanisms using the flow reactor system. The decrease in molecular weight of polystyrene was recorded at minute intervals over the temperature range 310°–390°C. Generally, the first and second stages were observed by thermogravimetric analysis (t.g.a.), however in the early stage of the degradation volatile yields of at least 5% occurred. Therefore, using t.g.a. analysis it is difficult to detect this earlier stage. It became evident that the first stage in the earlier part of the reaction could be detected by g.p.c. analysis. We have observed the hidden kinetic parameters of the nature of the first stage of the polystyrene degradation. The results indicate that the main chains were degraded randomly with the small quantitative volatile groups in the first stage and the rates of decrease in molecular weight in the first stage against reaction temperatures were evaluated as log k_s = 12.0 ? 41300/RT.     

新型有机磷系阻燃剂的热稳定性

利用STA490C热分析仪对8种新型有机磷系阻燃剂的热失重过程进行测定和对比,结果表明磷杂螺环阻燃剂3,9-二羟基-2,4,8,10-四氧杂-3,9-二磷杂螺环[5,5]十一烷-3,9-二氧化物和苯基次膦酸类阻燃剂4-甲氧基羟甲基苯基次膦酸热稳定性较好。     

基于差异路径权重的二部图网络推荐算法

针对二部图网络结构推荐算法中资源分配不合理的现象,同时为了丰富推荐结果多样性和促进冷门物品的推荐,提出了一种利用差异路径权重改变资源传递的二部图网络结构算法。利用用户相似性构造路径权重改变第一阶段资源传递规则,使资源较多地流向与目标用户相似的用户节点。通过物品属性相似的构造路径权重,使第二阶段资源更多地流向与目标用户已购物品具有相似属性的物品。实验结果表明,本算法相对于其他流行网络结构算法提高了推荐的综合性能,并且更好地解决推荐中的相关问题。     

饲料级磷酸氢钙中钙含量偏高的原因

通过不同温度下的烘干、灼烧实验 ,分析饲料级磷酸氢钙中钙含量偏高的主要原因是产品结晶水含量少 ,仅 0 .3个结晶水。取消中和槽蒸汽加热 ,保持常温反应 ;改闪蒸干燥为气流干燥 ;用氢氧化钙作中和剂 ;使饲钙产品中钙含量由平均约 2 8%降至 2 2 %。     

基于变权灰色关联法的长江荆南三口地区水资源短缺程度分析

对荆南三口地区水资源短缺程度进行分析研究,为实现区域水资源可持续合理利用提供科学依据。在水资源短缺评价研究中,前期研究成果大多采用常权法确定评价指标,致使评价指标产生状态失衡。将变权理论引入到水资源短缺程度分析中,从而确定评价指标变权重,并结合灰色关联法,构建水资源短缺程度分析的变权灰色关联法模型并加以应用。最终得出荆南三口地区三县的水资源短缺程度均为轻度缺水,其缺水程度排序为:华容县南县安乡县。利用变权灰色关联法计算水资源短缺程度,方法可行,结果合理,满足了评价指标均衡性要求。