氨基磺酸系高性能减水剂的研制开发

本文主要讨论了氨基磺酸系高性能减水剂的合成过程及后期混凝土试验情况。通过对反应温度、反应时间、溶液浓度和酸碱度、投料顺序及速度、第四单体的选择等反应条件的控制,合成具有最佳分子结构的最终产物,并通过红外光谱图和核磁共振谱图对合成主产物的分子结构进行了验证。同时,大量的混凝土试验说明氨基磺酸高性能减水剂具有优良的保坍性能。     

Surface designing of polypropylene by critical monitoring of the grafting conditions

The grafting of acrylic acid onto electron beam‐irradiated polypropylene was carried out using preirradiation method. The stability of peroxy radicals was investigated by electron spin resonance. It was found that the decay of peroxy radicals is much faster at 70°C than at 40°C and ambient temperature. The grafting has been observed to be strongly dependent on the monomer dilution in the reaction medium. The grafting was ascertained by attenuated total reflectance (ATR). The distribution of grafts across the samples was monitored by infrared microscopy. It was found that the graft management is considerably influenced by composition of the grafting medium. The grafting involving pure monomer leads to the surface enrichment with the polyacrylic acid chains. The samples grafted in pure monomer led to much lower contact angles as compared to the diluted monomer solution. The swelling of the grafted samples also showed a trend that was governed by the graft management. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 546–553, 2006     

Solar radiation climate in Malawi

Recently, Diabaté et al. [Diabaté, L., Blanc, Ph., Wald, L., 2004. Solar climate in Africa. Solar Energy 76, 733–744] created a map of solar radiation climate in Africa using clearness index for 62 sites. They established a solar climate class II located in Malawi and Madagascar. However, their analysis did not include any irradiation data from a site in Malawi. In this study, the solar radiation climate of Malawi has been studied using long-term global radiation data from a local site. The mean monthly (K_tm) and seasonal (K_ts) daily clearness indices for the site were computed. It is observed that K_tm has two maxima in a year (K_tm = 0.58 in May and K_tm = 0.64 in September), in close conformity with findings of Diabaté et al. (2004). Other results are presented and discussed.     

钛及钛合金中氧和氢的联合测定

叙述了用红外吸收法对钛及钛合金中氧和氢联合测定的方法，取得了测定的最佳条件。连续测定6次的相对标准偏差在10％以下，作加标回收试验的回收率为95．6％～103．9％。分析时间在3min以内，可应用于日常分析，结果满意。     

Preparation of an anion‐exchange adsorbent by the radiation‐induced grafting of vinylbenzyltrimethylammonium chloride onto cotton cellulose and its application for protein adsorption

Poly(vinylbenzyltrimethylammonium chloride)‐graft‐cotton cellulose, an anion‐exchange matrix, was synthesized by a mutual radiation‐induced grafting technique with a ⁶⁰Co γ‐radiation source. The grafted matrix was characterized by grafting yield estimation, elemental analysis, Fourier transform infrared spectroscopy, and scanning electron microscopy. The grafting yield decreased with the increase in the dose rate. However, the grafting yield and nitrogen content of grafted samples increased almost linearly with an increase in the total irradiation dose. To evaluate the performance of the grafted anion‐exchange matrix, the protein adsorption and elution behavior were investigated in a continuous column process under various experimental conditions, with bovine serum albumin used as a model protein. The binding and elution behavior of the anion‐exchange matrix depended on different experimental parameters, such as the grafting yield, ionic strength, pH of the medium, and amount of protein loaded. From a breakthrough curve, the equilibrium binding capacity and elution percentage of the grafted anion‐exchange matrix were estimated to be 40 mg/g and 94%, respectively. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5512–5521, 2006     

Non‐reflecting artificial boundaries for transient scalar wave propagation in a two‐dimensional infinite homogeneous layer

This paper presents an exact non‐reflecting boundary condition for dealing with transient scalar wave propagation problems in a two‐dimensional infinite homogeneous layer. In order to model the complicated geometry and material properties in the near field, two vertical artificial boundaries are considered in the infinite layer so as to truncate the infinite domain into a finite domain. This treatment requires the appropriate boundary conditions, which are often referred to as the artificial boundary conditions, to be applied on the truncated boundaries. Since the infinite extension direction is different for these two truncated vertical boundaries, namely one extends toward x →∞ and another extends toward x→‐ ∞, the non‐reflecting boundary condition needs to be derived on these two boundaries. Applying the variable separation method to the wave equation results in a reduction in spatial variables by one. The reduced wave equation, which is a time‐dependent partial differential equation with only one spatial variable, can be further changed into a linear first‐order ordinary differential equation by using both the operator splitting method and the modal radiation function concept simultaneously. As a result, the non‐reflecting artificial boundary condition can be obtained by solving the ordinary differential equation whose stability is ensured. Some numerical examples have demonstrated that the non‐reflecting boundary condition is of high accuracy in dealing with scalar wave propagation problems in infinite and semi‐infinite media. Copyright © 2003 John Wiley & Sons, Ltd.     

超Jaynes-Cummings模型中的原子置于热辐射场时的相干特性

超Jaynes一Cummings模型中的两能级原子置于热辐射场。通过求解原子与热辐射场相互作用过程中原子约化密度算符非对角元．精确得出子原子相干性的衰变规律。研究了在相互作用系统中外加驱动场时可保持原子的相干性，此时外加驱动场的时间演化与原子的跃迁频率、原子偶极矩、热库的温度和k模光子频率等因素有关。     

Influence of a Jump in the Power of Laser Radiation on Its Measurement

Simulation and investigation of the effect of an isolated jump on realization of the unit of power of laser radiation and dissemination of the size of the unit are considered. Results are obtained by means of a newly developed algorithm that characterizes the behavior of the mean value of a signal and the standard deviation of a system as functions of the parameters of a jump in the power of laser radiation and the length and amplitude of the jump. If information concerning the time when a jump occurs is available, the proposed algorithm makes it possible to take into account how a jump affects the ultimate result of a measurement.     

主动式红外光电靶的研究

提出了采用红外光源的主动式光电靶的设计构想，用以消除传统天幕靶在对低速弹测量时，声音对测量的干扰，并设计了整个实验方案，在对静态实验结果进行分析的基础上，证明了该种方法的可行性。     

同步辐射光刻技术

同步辐射光刻有希望代替传统光刻技术,用于0.25μm以下图形的超精细加工。本文叙述了它的原理、相关技术的开发现状和工艺应用。