Defect structure and chemical diffusion in nickel sulfide β-Ni3S2

The chemical composition, defect structure, and diffusion in nickel sulfide -Ni₃S₂ have been investigated in H₂S-H₂ mixtures containing between 1 and 65% H₂S between 560 and 700°C. Gravimetric, density, and X-ray studies were carried out. In the thermodynamically stable compound the ratio of Ni/S varied between 1.3 and 1.75. The X-ray examination showed a step change in the lattice parameter at the Ni/S ratio 1.4. A linear dependence of the density values (between 5.5 and 6.2 g/cm³) on the composition was observed. On the basis of the chemical composition and density measurements the number of nickel and sulfur atoms in 1 cm³ were determined. It has been shown that the Ni₃S₂ phase is defected in both anion and cation sublattices and that its chemical formula may be described as follows: Ni_3±yS_2x, where y 2x. It has been found that in the mixture containing 10% H₂S the process of defect formation is determined by their diffusion in the sulfide. The temperature dependence of the diffusion coefficient is described by the equation D = 13.15 exp(-30,000/RT) cm²/sec. No dependence of D on the sulfur partial pressure was observed, but this may be due to the relatively large uncertainties in the measurement of the diffusion coefficients.     

ANALYSIS OF DISSIPATIVE STRUCTURE IN MATERIAL COMMINUTION

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Titanium in the rapidly cooled hypereutectic gray iron

The effect of titanium on the structure and properties of a rapidly cooled hypereutectic cast gray iron has been studied on the example of permanent mold (PM) casting. A microstructure study showed that titanium is a relatively strong element in controlling solidification structure by increasing undercooling and thus promoting type D graphite. The effectiveness of titanium additions depends on the base iron carbon equivalent (CE) with more pronounced changes in iron with a lower CE. The undercooling ability of the titanium decreases after exceeding a certain level. Increasing titanium from 0.09–0.12% slightly increases undercooling in iron with lower CE, but this effect was reduced in a more strongly hypereutectic iron. Alloying with titanium generally improves tensile strength, but the effectiveness of titanium additions also depends on the base iron CE range. Scanning electron microscope (SEM) studies revealed that most of the titanium-containing compounds were located in the metallic matrix: titanium carbides have been found in pearlite, while titanium nitrides and carbonitrides were located in ferrite. The presence of large amounts of extremely hard titanium-containing compounds, which often appear with steadite in a relatively high phosphorous content PM gray iron, amplifies the negative effect of titanium on machinability. This study suggests that for optimal combination of tensile strength/microstructure with good machinability, the titanium content in PM gray iron should not exceed 0.075%.     

系统失效的分支-界限分析法及其在桁架可靠性分析中的应用

本文首先介绍了系统失效的分支-界限分析法，然后以空间桁架系统为例用分支-界限分析法进行了可靠性分析。系统失效的分支-界限分析法直观、明了，适合对实际工程中的复杂系统进行可靠性分析。     

Ag-Cu-In-Sn合金的结构特性

借助金相、X光衍射及SEM方法研究Ag-Cu-In-Sn合金的结构特性及合金各组元在合金相中的分布规律,还讨论了某些相结构对合金力学性能的影响。四元合金的化学成分是(wt％)57～63Ag,17～23Cu,(20—x)In,xSn,其中:Ag+Cu=80wt％,In+Sn=20wt％,2≤x≤16。     

高线粗中轧机"浮动"检测结构设计及故障排除

为克服轧制中因机架锁紧功能降低而产生的机架沿轨座轴向移动的"浮动"现象,对其产生原因进行了分析,并通过改进锁紧装置结构及相关部件,使"浮动"故障得到预防和有效控制并及时排除。     

Influencing factors on elastic-plastic deformation of multi-layered surfaces under sliding contact

Stress distribution in the gradient multi-layered surface under a sliding contact was investigated using finite element method(FEM). The main structure parameters of layered surface discussed are total layer thickness,layer number and elastic modulus ratio of layer to the substrate. A model of multi-layered surface contact with rough slider was studied. The effect of the surface structure parameters on the elastic-plastic deformation was analyzed.     

汽车构造实验网络教学辅助系统设计

为切实提高汽车专业教学水平,建立全方位教学体系,设计基于网络的汽车构造实验教学辅助系统。系统充分利用学校现有计算机网络平台,利用多媒体和网络开发技术,开发或整合多媒体资料,开辟学习交流平台,依据课程学习规律和认知特点,建立起方便快捷、生动有趣的实验教学辅助系统。该系统基于现有教材,又高于教学内容,不仅对于传授汽车zai新技术和剖析专业难点,调动学习积极性,具有重要补充和推动作用,而且对于教学示范中心创建工作,也具有重要意义。     

基于贝叶斯的服务通告改装经济性决策方法

改装类服务通告的经济性决策是航空维修企业工程人员的一项重要工作内容。设计了改装类服务通告经济性决策程序;通过服务通告对飞机运营的经济性影响分析构建了成本分解结构,并对不同的成本项目建立了成本评估模型;针对模型的成本影响参数MTBUR和MTBF的估计采用了贝叶斯方法以解决小样本问题;通过投资回收期方法获得评价指标以决定是否进行服务通告改装投资。最后通过实例对决策方法的应用进行说明。此方法能够为航空企业的维修改装决策提供有效的技术支持。     

IT时代的第三种文化产业机遇

人类社会一直存在着并行不悖的科技与人文的两种文化与文化产业。如今,出现了第三种文化与第三种文化产业。第三种文化产业的思想基础是图灵的可计算原理;其物质基础是微处理器智力内核。第三种文化产业将打破两种文化产业界线,用人工智能与智能化工具等现代科技手段,实现人文文化领域中的艺术创作,这是人类文化领域中已经开始的没有硝烟的产业战争。