沸石孔结构对1-己烯异构化性能的影响

采用1-己烯为原料,对硅铝比相近、不同孔结构的沸石在脉冲微反装置上进行了评价试验,考察了FCC条件下沸石孔结构对烯烃异构化性能的影响。结果表明,大孔径的Y型沸石具有良好的异构化性能,异构化能力由强到弱的排列顺序为Y>β>ZRP>丝光沸石>镁碱沸石。     

Synthesis, Characterization and Crystal Structure of Quaternary Complex of Gadolinium （Ⅲ）

Ａｎｕｍｂｅｒｏｆｌａｎｔｈａｎｉｄｅｔｅｒｎａｒｙｃｏｍｐｌｅｘｅｓｃｏｎ ｔａｉｎｉｎｇｈｅｔｅｒｏｃｙｃｌｉｃａｍｉｎｅｓｈａｖｅｂｅｅｎｒｅｐｏｒｔｅｄｓｉｎｃｅ1960 [1] .Ｉｎｒｅｃｅｎｔｙｅａｒｓｍｕｃｈａｔｔｅｎｔｉｏｎｈａｓｂｅｅｎｐａｉｄｔｏｑｕａｔｅｒｎａｒｙｃｏｍｐｌｅｘｅｓｏｆｌａｎｔｈａｎｉｄｅｓｂｅｃａｕｓｅｏｆｉｎ ｔｅｒｅｓｔｉｎｇｓｔｒｕｃｔｕｒｅ ,ｃｏｏｒｄｉｎａｔｉｏｎｍｏｄｅ ,ｃｏｍｐｅｔｉｔｉｏｎｒｅ ａｃｔｉｏｎａｎｄｐｒｏｐｅｒｔｙ[2～ 9] .ＥＳＲｃａｎｅ…     

Mesh结构P/G布线网络层次化快速分析方法

本文提出了一个基于网络划分的P／G布线网络层次化快速分析方法。其中，对于子网运算，通过对Cholesky分解法三角化对称正定阵的图模型分析，并基于Mesh结构网络的自身特点，提出了一个基于图顶点排序的加速子网分析运算策略；并用基于MPI的并行结构实现了P／G布线网络分析的并行运算。     

Mesh-Tree两级层次结构P/G网布线优化方法

本文采用Mesh-Tree两级层次结构作为P／G网布线拓扑结构，并提出了一个对于该结构的线宽优化方法，使超大型P／G网的布线优化速度大大提高。     

Surface segregation studied by low-energy ion scattering: experiment and numerical simulation

The changes in surface composition of metallic alloys caused by segregation can be very efficiently studied by low-energy ion scattering (LEIS) due to the specific surface sensitivity of this technique. Investigations of single-crystal surfaces of ordered alloys are of particular interest because they provide the possibility to investigate the interplay between segregation effects and the order-disorder phase transition when passing through the transition temperature. Exemplifying these effects for bimetallic alloys we consider in particular the CuAu-system.For the quantitative interpretation of energy and angle resolved LEIS intensity distributions we compare experimental results with those from numerical simulations using the MARLOWE code which we extended with a detailed trajectory analysis. This allows us to apply various discrimination criteria, such as number of collisions, distance of closest approach, identification of the scattering crystal layer, total path length, etc. On this basis structural effects, ion survival probabilities and the influence of thermal vibrations can be studied.We demonstrate this potential by using CuAu(1 0 0) as a special example. The scattering potential parameters were calibrated with elemental single crystals of known structures and the anisotropic Debye temperatures taken from the literature showed good agreement, neutralization was of minor importance in this case. Our procedure could be successfully used for the quantitative analysis of the composition of the first and second layer as a function of temperature. These results are in good agreement with theoretical predictions.     

Crushing behaviour of the energy absorbing 'tensor skin' panels

ABSTRACT Research results concerning the simulation of the crushing behaviour of composite systems with energy absorption characteristics are presented in the present work. The study is focused on the ‘tensor skin’ concept, an energy absorbing composite system that was originally developed to improve the crashworthiness of helicopters under water impact and which is promising for utilization in the construction of the lower part of composite fuselage aircraft. The ‘tensor skin’ concept comprises a folded or corrugated composite construction, which upon loading unfolds by forming ‘plastic hinges’, leading to an increase in the load bearing capability of the structure. The numerical modelling issues and the critical aspects of the simulation are discussed. Verification of the numerical simulation procedure is performed by experimental work. The experimental results utilized to assess and validate the numerical procedure were derived within the European Research Project ‘Design for Crash Survivability – CRASURV’ (BRITE – Aeronautics Area). The results of the simulations are generally in good agreement with experimental data.     

金刚烷最新研究

金刚烷是近 30年来发展起来的一种新型精细化工原料。简要介绍了金刚烷的分子结构、性质及其主要用途 ,重点对近年来国内外报道过的金刚烷合成方法进行了评述 ,在此基础上指出了金刚烷化工的未来发展趋势。     

激光武器对抗效能指标体系研究

武器系统的效能是规划、研制、配置和部署武器系统的基本依据,是评价武器系统优劣最重要的综合性指标,建立正确的效能指标体系是进行效能分析与评价的前提。在详细研究了激光武器对抗机理、效能指标选用原则的基础上,构建了相对完整的激光武器对抗效能指标体系结构,并提出了在不同作战任务下量度激光武器对抗能力的效能定义。