Electrical properties of paraelectric PLT(28) thin films deposited by dc magnetron sputtering

Abstract

Paraelectric [Pb, La]TiO₃ (PLT, La = 28 mol%) thin films were prepared by dc magnetron sputtering using a multi-element metal target. In order to crystallize the as-deposited PLT thin films into the cubic perovskite structure, a heat treatment was applied at annealing temperatures ranging between 450 and 750°C. The electrical measurements such as dielectric properties, polarization-electric field (P-E), and current-voltage (I–V) were investigated with the change of annealing temperature. The dielectric constant and dissipation factor of paraelectric PLT film annealed at 750°C were 1216 and 0.018, respectively. The charge storage density was approximately 12.5 μC/cm². The leakage current density in PLT film annealed at 650°C was around 0.1 μA/cm² at the electric field of 0.25 MV/cm.     

Dielectric relaxation phenomenon of rare earth Nd3+ modified bismuth layer ferroelectric ceramics fabricated by plasma active sintering method

Abstract

The crystalline structure, dielectric relaxation and ferroelectric properties of the solid solution, Nd _x Bi_4-x Ti₃O₁₂ (NBIT) compound were measured. The Curie temperature of the NBIT ceramics was determined to be 490°C from dielectric measurements. The dielectric constant of the NBIT ceramics shows a small anisotropic property. Polarization switching was observed using a Sawyer-Tower circuit at 50 Hz. Remnant polarizations and coercive fields could not be confirmed since the hysteresis loops were not saturated. The large dielectric relaxation is observed in the frequency range between 100 kHz and 1 MHz.     

Abnormal resistivity-temperature characteristics of semiconducting (Ba1-x Pb x )TiO3 materials prepared by microwave sintering

Abstract

(Ba_0.7Pb_0.3)TiO₃ and (Ba_0.4Pb_0.6)TiO₃ materials possessing double critical temperature (T_c ) and single high-T_c in resistivity-temperature (ρ-T) behavior, respectively, were obtained by microwave sintering at 1050°C for 5 minutes. These characteristics were ascribed to the existence of the dual phases with core-shell structure. The cooling-rate control modified the relative magnitude of low-T_c and high-T_c resistivity jumps, without altering the T_c -values. It occurred via the change in relative proportion of the core and shell phases.     

(111)-Oriented BaTiO3 thin films hydrothermally formed on TiO2/Si substrate

Abstract

Barium titanate (BaTiO₃) thin films with high (111)-orientation were successfully grown on TiO₂-covered Si(111) substrate using hydrothermal method, where the TiO₂ layer was previously fabricated at room temperature by means of ion-beam-assisted deposition. This processing method provides a simple mild-chemical route for directly producing the analogous crystalline films on different substrates. The BaTiO₃ films did not reach the TiO₂/Si interface even if the hydrothermal treatment was prolonged to 24 hours. Both Rutherford backscattering and spread-resistance profiling characterizations confirmed the diffusion nature of the formed Ba-TiO₃/TiO₂/Si system.     

PZT capacitor with Ir/IrO2/Ir electrode fabricated by RTA

Abstract

PZT capacitor with direct contact between Si substrate and bottom electrode of the capacitor was obtained with Ir/IrO₂/Ir/Ti electrode, by crystallizing sol-gel PZT thin film using RTA (650°CC 30 sec.). Contact resistance for hole diameter of 0.72 μm was 19 Ω. It was observed by cross-sectional TEM that Ti silicide was formed at the interface, but there was not oxygen diffusion from PZT thin film. Fatigue property of the PZT thin film was improved by RTA compared with furnace annealed film (600°CC 60 min.). The absolute value of the remnant polarization was 13 μC/cm² for both films, but it did not degrade until 10⁸ cycles of switching for the film by RTA, while it degraded before 10⁵ cycles for furnace annealed film.     

手绘图形结构的识别方法研究

研究了手绘图形的结构识别问题,讨论了如何用属性关系图描绘图形的结构,定义了手绘图形的相似度,给出了计算该相似度的方法,提出了一种模板匹配策略及相应的模板库组织方式以提高识别速度。     

谓词逻辑在答疑系统中的应用

提出了一种新的答疑系统模型。该模型引入了谓词逻辑,在系统完成关键词匹配后,进行二次谓词匹配,最后把仅和问题语义相符的答案予以反馈。实验证明,这种方法较好地提高了系统的智能性和准确率。     

紧支波波基的非对称性及改进

文中给出了紧支正交小波基的非对称性的一种简捷且容易理解的证明方法,在讨论了紧支 交小波基的这种非对称性在实际应用中的不便后,系统地总结了两大类的改进方法,提出了一种用多尺度函数来改进其对称必的思路,并对重要的改进法给出了具体的算例。     

区块链与可搜索加密结合的电子病历共享方案

电子病历（Electronic Medical Record,EMR）数据的共享被认为是提高医疗服务质量和降低医疗成本的关键方法。然而,EMR分散存储在各个医疗机构中,这阻碍了数据共享,并使患者的隐私面临风险。为了解决这些问题,提出了一个基于区块链的EMR隐私保护数据共享方案。将原始EMR安全地存储在私有链中,而将关键词索引保存在联盟链中,从而有效降低医疗数据泄露的风险,并保证EMR的不可篡改性。利用布尔函数改进基于密文策略属性的关键字搜索算法,用属性上的布尔公式指定表达性访问策略,有效优化了带宽和通信消耗,并引入了门限签名机制,有效地缩短了密文长度。使用私有链服务器执行配对操作,使得搜索速度更快。通过公共验证者检查搜索结果,保证了数据安全并降低了计算开销。安全性和性能分析的结果表明,该方案是实现EMR数据共享的一种安全有效的方法,可减轻用户设备的额外计算负担,最小化带宽和通信消耗。     

一种无安全信道的模糊关键字搜索加密方案

在互联网技术高度发达的今天,人们越来越习惯把个人数据上传到云端进行存储。传统可搜索公钥加密方案仅支持对精确的关键字进行搜索,用户需要精确地输入搜索关键字,且需要使用安全信道来传输陷门,降低了系统的可用性。针对安全信道,本文结合公钥加密技术提出一种无安全信道的模糊关键字搜索加密方案。该方案在不使用安全信道的情况下也能保证信息的隐私性,使用通配符技术来降低关键字集的空间大小,并且给出安全性验证。