The establishment of the statistical-thermodynamic model of D81-structure and its application to α-Nb5Si3

A statistical-thermodynamic model for binary nonstoichiometric A₅B₃ with D8₁-structure has been established on the basis of the grand canonical ensemble. In the model the average chemical potentials according to the composition and a new extra equation as a boundary condition are proposed for more accuracy and free experimental data calculations. The model can be used in any A₅B₃ type compounds with D8₁ structure. The establishment method of the statistical-thermodynamic model can be extended to other complicated structures. We apply the statistical-thermodynamic model to α-Nb₅Si₃ and the parameters used in the model are obtained from the first-principles' calculations. From these parameters the expression for the point defect concentrations as a function of compositions and temperatures is obtained by numeral calculations. The constitutional defects and thermal defects in α-Nb₅Si₃ are discussed.     

A demerit-fuzzy rating system,monitoring scheme and classification for manufacturing processes

For monitoring online manufacturing processes, the proportion of weights imposed on each type of product’s defects (nonconformities or demerits) has a profoundly effective impact on control charts’ performance. Apparently, the demerit-chart approach is superior than the widely-used c-chart scheme, because it allows us to place relative precise weights (real numbers) on defects according to their distinctly inferior degrees affecting the product quality so that the abnormal variations of processes can be literally exposed. However, in many applications, the seriousness of defects is evaluated partially or entirely by the inspectors’ perceptive judgement or knowledge, so with the precise-weight assignment, the demerit rating mechanism is considered to be somewhat constrained and subjective which inevitably leads to the targeted manufacturing process with limited and possibly biased information for online surveillance. To cope with the drawback, a demerit-fuzzy rating system and monitoring scheme is proposed in this paper. We first incorporate fuzzy weights (fuzzy numbers) to properly reflect the severity measures of defects which are categorized linguistically. Then, based on properties of fuzzy set theory and proposed approaches for fuzzy-number ranking, we develop the demerit-fuzzy charting scheme which is capable of discriminating process conditions into multi-intermittent statuses between in-control and out-of-control. This approach improves the traditional process control techniques with the binary-classification restraint for the process conditions. Finally, the proposed demerit-fuzzy rating system, monitoring scheme, and classification is elucidated by an application in garment industry to monitor textile-stitching nonconformities conditions.     

Stochastic defect diffusion model for relaxation effects in crystalline polyethylene

It is suggested that some relaxation processes observed in crystalline polyethylene are consequences of the diffusive motion of a particular defect called a point dislocation or twist dispiration loop along the polyethylene stems in lamellar crystals. The motion of the defect, characterized by a diffusion coefficient and a mobility, is described by solutions of the Smoluchowski diffusion equation with boundary conditions that constrain the defect to move along routes that produce experimentally observable results. The fact that passage of the defect causes both a 180° rotation of the chain and moves an extra CH₂ group in the direction of the chain axis is important to the interpretation of the data according to this model. The diffusion coefficient for a defect is estimated to be around 2 × 10^?9 cm² s^?1 at 70°C. This value is shown to be reasonable both from the viewpoint of detailed computer modelling of defect motion and contemporary ideas about scaling.     

Structural characteristics of oxide nanosphere supported metal nanoparticles

Structural characterization by transmission electron microscopy of metal nanoparticle coatings on oxide nanospheres has been employed to point out the potential of such materials for use as porous support model catalysts. On silica and titania nanospheres of various origins surface-mediated metal deposition at mild temperature conditions has been utilized to fabricate Pt, Pd, Ag, and Au nanoparticle coatings on the oxide supports. Promising coating characteristics have been achieved for Ag and Au nanoparticles by direct reduction on terminating hydroxyl-rich St?ber silica. A high-resolution electron microscopy analysis directed to surface stress, lattice contraction and planar lattice defects of the latter particles revealed no strong metal-support interaction.     

Review of Mechanically Related Failures of Ceramic Capacitors and Capacitor Materials

This paper reviews the brittle fracture behavior of dielectric ceramics such as barium titanate, and describes some of the relationships between defects such as cracks and electrical degradation and failure of multilayer capacitors. Stresses arising from the ferroelectric phase transformation in these dielectric materials are shown to play a part as a driving force for crack growth. In addition, possible contributions to failure from stresses arising from thermal excursions in the capacitor are discussed. Low-voltage failures arising from a short between the electrodes in multilayer capacitors are shown to be related to the growth of cracks in the dielectric. A technique for predicting the onset of these types of failures based upon fracture mechanics techniques is described. Possible effects of the electric field itself in promoting or retarding the growth of cracks are discussed.     

刚玉瓷指痕缺陷的研究

本文采用两种不同Al2O3粉为原料，结合Al2O3预烧与材料的生产工艺，对刚玉瓷的指痕缺陷及其对材料性能的影响进行了研究。结果发现：Al2O3粉预烧温度不匀时，部分颗粒（γ-Al2O3）周边存在层错缺陷，激活能的存在，人体中颗粒粘连（团聚）；该团聚体在坯体及烧结体中的残留直接引起烧结体中的结构缺陷，由Al2O3预烧温度高且均匀的粉体制备材料，才能获得具有优良性能的刚玉体。     

Gravity optimised particle filter for hand tracking

This paper presents a gravity optimised particle filter (GOPF) where the magnitude of the gravitational force for every particle is proportional to its weight. GOPF attracts nearby particles and replicates new particles as if moving the particles towards the peak of the likelihood distribution, improving the sampling efficiency. GOPF is incorporated into a technique for hand features tracking. A fast approach to hand features detection and labelling using convexity defects is also presented. Experimental results show that GOPF outperforms the standard particle filter and its variants, as well as state-of-the-art CamShift guided particle filter using a significantly reduced number of particles.     

Understanding heterogeneous catalysis on an atomic scale: a combined surface science and reactivity investigation for the dehydrogenation of ethylbenzene over iron oxide catalysts

In order to study the dehydrogenation of ethylbenzene to styrene, epitaxial iron oxide model catalyst films with Fe₃O₄(111), -Fe₂O₃(0001) and KFe _x O _y (111) stoichiometry were prepared in single crystal quality on Pt(111). They were investigated using surface science techniques before and after atmospheric pressure reaction experiments in a newly designed single crystal flow reactor. As expected from low-pressure measurements, Fe₃O₄(111) is catalytically inactive. The catalytic activity of -Fe₂O₃(0001) starts after an activation period of about 45 min. After that, the surface is essentially clean but shows a high concentration of defects. On the potassium-promoted films, however, the activation period is much longer, the activity then is higher and the surface gets covered completely with carbon and oxygen during reaction. This indicates a different reaction pathway on the promoted films with a carbon–oxygen species as catalytically active species.     

宏应用遇到的问题及解决办法

本文指出了在Microsoft Word2002/2003中用宏录制器录制宏遇到的几个问题,并给出相应的解决办法。其中对宏无法实现将中文设置为指定的目标中文字体,用录制前将光标定位在指定字体的文本中及录制后修改代码的方法解决。     

均三甲苯氧化合成间二甲基苯甲酸的宏观动力学

研究了由均三甲苯液相富氧催化氧化制备间二甲基苯甲酸的动力学规律 ,考察了反应时间、温度、通气量和氧浓度等因素对均三甲苯和间二甲基苯甲酸浓度的影响 ,根据双膜理论建立了该反应的宏观动力学模型 ,并由实验数据拟合出模型参数 ,经检验模型计算值能较好地与实验数据相吻合