膜分离技术在水处理领域的应用

对2000年底巴黎“饮用水和工业用水制造领域中的膜技术”国际会议进行了简单的回顾，根据会议经历对当今膜分离技术在水处理领域的应用市场进行分析，提出今后液体膜分离技术的研究和发展的重点。最后对我国液体分离膜技术的发展提出一些建议。     

2,4,6‐Trichlorophenol and phenol removal in methanogenic and partially‐aerated methanogenic conditions in a fluidized bed bioreactor

A fluidized bed bioreactor (FBBR) was operated for more than 575 days to remove 2,4,6‐trichlorophenol (TCP) and phenol (Phe) from a synthetic toxic wastewater containing 80 mg L^?1 of TCP and 20 mg L^?1 of Phe under two regimes: Methanogenic (M) and Partially‐Aerated Methanogenic (PAM). The mesophilic, laboratory‐scale FBBR consisted of a glass column (3 L capacity) loaded with 1 L of 1 mm diameter granular activated carbon colonized by an anaerobic consortium. Sucrose (1 g COD L^?1) was used as co‐substrate in the two conditions. The hydraulic residence time was kept constant at 1 day. Both conditions showed similar TCP and Phe removal (99.9 + %); nevertheless, in the Methanogenic regime, the accumulation of 4‐chlorophenol (4CP) up to 16 mg L^?1 and phenol up to 4 mg L^?1 was observed, whereas in PAM conditions 4CP and other intermediates were not detected. The specific methanogenic activity of biomass decreased from 1.01 ± 0.14 in M conditions to 0.19 ± 0.06 mmolCH₄ h^?1 gTKN^?1 in PAM conditions whereas the specific oxygen uptake rate increased from 0.039 ± 0.008 in M conditions to 0.054 ± 0.012 mmolO₂ h^?1 gTKN^?1, which suggested the co‐existence of both methanogenic archaea and aerobic bacteria in the undefined consortium. The advantage of the PAM condition over the M regime is that it provides for the thorough removal of less‐substituted chlorophenols produced by the reductive dehalogenation of TCP rather than the removal of the parent compound itself. Copyright © 2005 Society of Chemical Industry     

PVDF中空纤维滤膜的形态结构

用Ｌ－Ｓ相转换法制备了聚偏氟乙烯（ＰＶＤＦ）中空纤维不对称滤膜。铸膜液由聚合物、溶剂和添加剂组成。用电子显微镜（ＳＥＭ）考察了聚合物浓度、添加剂用量及种类对膜形态结构的影响。实验结果表明，聚合物浓度对膜形态结构有显著影响，当铸膜液中聚合物浓度较低时，无论用什么种类添加剂，都能形成大、且多的孔，但孔的形状随添加剂不同而异。当恒定聚合物浓度时，添加剂的用量对膜形态结构有很大的影响，但孔的大小及多少与添加剂含量的多少不成正比。     

NH_4Cl水溶液在成膜过程中的致孔作用

本文以ＮＨ４Ｃｌ饱和水溶液做添加剂，对ＰＶＤＦ／ＮＭＰ体系在成膜过程中的致孔作用做了研究。铸膜液中随ＮＨ４Ｃｌ水溶液加入量的改变，膜孔径也发生变化，并出现最大值。通过Ｘ－射线衍射扫描发现制膜液中存在无机盐时膜中无定形态结构增加，表明无机盐的加入有助于膜孔形成     

PAA-PSF交联复合膜的制备及对低浓度有机醇水溶液反渗透分离性能研究

进行了ＰＡＡ（ＰｏｌｙａｃｒｙｌｉｃＡｃｉｄ）－ＰＳＦ（Ｐｏｌｙｓｕｌｆｏｎｅ）交联复合膜的制备，研究了交联剂、添加剂对膜性能的影响，并通过扫描电镜观察了膜的断面结构．研究了ＰＡＡ－ＰＳＦ交联复合膜对低浓度有机醇类水溶液反渗透分离性能．发现对于１０００×１０－６乙醇水溶液截留率达到６６．２％，透过流束可达０．９×１０－６（ｍ３·ｍ－２·ｓ－１）．随醇的分子量的增加，截留率不断上升，对戊醇的截留率达９４．３％，而透过流束则保持相对稳定．对不同结构醇类的分离性能研究表明，截留率存在有：ｔｅｒｔ－＞ｓｅｃ－＞ｉｓｏ－＞ｎ－的规律．     

Separation of di- and tripeptides with solvent extraction and an emulsion liquid membrane

The extraction equilibria of various di- and tripeptides with di-2-ethylhexylphosphoric acid (D2EHPA) were studied at low pH values. The complex extracted to organic phase consisted of one molecule of peptide and two molecules of D2EHPA dimer. The extraction constants of the peptides correlated well with the distribution coefficients of peptides between 1-octanol and water, which is a measure of hydrophobicity. The permeation rates of peptides through an emulsion liquid membrane were examined by using D2EHPA as a carrier, Span 80 as an emulsifier and kerosene as a diluent. The rates varied considerably with peptide type, depending upon the hydrophobicity.     

Corroles as receptors in liquid membrane electrodes and their potentiometric response towards salicylic acid

Here, we report on the application of corroles as analytically active compounds in liquid membrane electrodes (ISE) that are sensitive towards salicylic acid and salicylate.The potentiometric signals generated by corrole-incorporated ISEs strongly depend on the pH of the aqueous sample solution and the membrane composition, such as the presence of lipophilic sites. Corrole incorporating ISEs are characterised by a low detection limit (4.0 × 10⁻⁵ M) and a wide linear range (4.0 × 10⁻⁵ to 5.3 × 10⁻³ M). Also, they are free from interference versus other organic anions.The mechanism of the generation of the potentiometric signals of corrole incorporating ISEs in the presence of salicylate anion, as well salicylic acid, will be discussed.     

ISOFLUX膜——微滤膜极品

介绍一种新型的恒通量的微滤膜———ISOFLUX 膜 ,该种膜的膜通量衰减比通常的微滤膜要小得多 ,对ISOFLUX 膜的原理和数学模型进行了推导 ,并给出了对牛奶进行冷杀菌过滤的结果 .     

浸入凝胶法聚合物膜形成机理的研究现状

从热力学、传质动力学、相分离机制和固化过程几方面综述了浸入凝胶过程中聚合物膜形成机理的研究现状 .指出浸入凝胶成膜过程是传质交换和由传质交换引发的相分离以及其后的固化过程之间相互竞争的复杂非平衡过程 ,膜结构是上述几个过程竞争的结果     

二次盐水及离子膜电解工序常见问题简析

介绍了二次盐水及离子膜电解工序的主要设备和流程,对二次盐水及离子膜电解工序运行中出现的问题进行了分析,并提出了解决措施。