Application of structural curvature of coalbed floor on CBM development in the Zaoyuan block of the southern Qinshui Basin

Based on controls of structural style and the position in coalbed methane(CBM)development,we used a method of curvatures to study its relations with CBM development parameters.We calculated structural curvatures of contours of the No.3coal seam floor of the Shanxi Formation in the Zaoyuan block of the Qinshui Basin and analyzed its relations with development parameters of coalbed methane wells.The results show that structural curvature is negatively related to coal reservoir pressure,while positively related to permeability.With an increase in structural curvature,the average production of coalbed methane wells increases at first and then decreases,reaching the highest production at 0.02 m-1 of structural curvature.Therefore,structural curvature can be an important index for potential evaluation of coalbed methane development and provide a basis for siting coalbed methane wells.     

甲烷燃烧NO_x生成的数值研究

采用非预混燃烧模型与组分传输的一步反应模型,模拟了甲烷燃烧及NOx的生成,得出燃烧温度场、NO生成情况。模拟结果表明:采用非预混燃烧模型模拟时结果更接近实测值,模拟更准确;甲烷扩散燃烧时NO产生区域主要集中在高温火焰后侧,在前部低温区基本没有NO生成;燃烧中P-NO生成量比T-NO量小两个数量级,NO产生几乎完全被热力型NO机制支配,在燃烧过程中应特别注意高温区域的影响。     

煤层气压裂技术研究

煤层气与常规天然气有较大差异,采用压裂施工可达到煤层气开发的理想效果。根据煤层气的特性,在施工中应注意压裂液、煤粉、压实性等因素所造成的伤害。     

平板微反应器内甲烷-湿空气催化重整的数值分析研究

建立了二维稳态多组分传输反应的模型,对平板微反应器中Rh催化剂涂层上甲烷-干、湿空气催化重整制合成气进行了数值计算,并分析了采用湿空气时反应通道长度和高度对重整性能的影响.结果表明：进口速度低于2 m/s时,采用湿空气可提高甲烷转化率和产氢率,反应器出口的温度降低以及减少积碳的发生;采用湿空气时,反应通道长度增大,甲烷的转化率提高,出口氢气含量增大,出口温度相应地降低;反应通道高度增大,甲烷的转化率降低,出口氢气的含量减少,出口温度升高.     

Methane absorption and application of mixed organic aggregate prepared from Span80 and alkaline salt

The water-based materials for mine gas absorption and explosion suppression were prepared, in which the mixed organic aggregate of Span80 and alkaline salt can be used as methane absorbent. Methane was used as a model of mine gas, and the absorptions of methane with different complex materials were studied using head space gas chromatography. Then the state of aqueous material was characterized with laser light scattering instrument and the effects of different complex materials on explosion suppression were preliminarily studied in explosion chamber which can simulate mine gas explosion. The research results showed that complex material could absorb methane and there was some correlation between the mean diameter of organic aggregate in aqueous material and the absorption effect. Additionally, the aqueous material could suppress the methane explosion to some degree. The material can absorb mine gas in atomization condition, therefore, degrease mine gas concentration and influence the distribution of mine gas in the space, and then suppress the mine gas explosion to some extent.     

二甲基氨基甲叉二膦酸氮氧化物的合成

以二甲基氨基甲叉二膦酸(DMMP)为原料,双氧水为氧化剂合成二甲基氨基甲叉二膦酸氮氧化物(DMMPO)。研究了原料配比、温度、时间及合成时pH值等条件对目标产物阻磷酸钙垢效果的影响,结果表明:n(DMMP)∶n(H2O2)=1∶3、反应温度为75℃、反应时间为2.5 h,并控制pH值为9左右时合成的DMMPO静态阻垢效果最好。通过IR和31P-NMR对产物进行了结构鉴定,同时对产品进行了活性物含量、亚磷酸根和磷酸根含量的测定,直接合成产物中活性组分含量为22.7%,亚磷酸根和磷酸根含量均小于0.1%。     

The effect of sulfur on the dissociative adsorption of methane on nickel

The dissociative adsorption of methane was carried out on a Ni(100) surface covered with various amounts of sulfur under the high incident flux conditions of 1 Torr methane. Auger electron spectroscopy was used to measure the rate of carbon buildup and thus to determine the initial methane decomposition rates on the surface. It was shown that the sulfur atoms poison this reaction by a simple site-blocking process. These results are consistent with the activated dissociative adsorption of methane on Ni(100) occurring via a direct adsorption process.     

Calculation of single adsorption isotherms from gravimetrically measured binary gas mixture adsorption isotherms on activated carbon at high pressures

A method is developed for the calculation of single-component adsorption isotherms from gravimetrically measured binary gas mixture adsorption isotherms at high pressures, at two temperatures and for different mole fractions of the gas phase. The adsorption of nitrogen/methane on active carbon Norit R1 is taken as an experimental example.     

Promotion of hydrogen permeation on metal-dispersed alumina membranes and its application to a membrane reactor for methane steam reforming

A mesoporous membrane for selective separation of hydrogen was prepared usingthe sol-gel method. Some metal salts such as RuCl₃, Pd(NH₃)₄Cl₂, RhCl₃,, and H ₂PtCl₆, were added to the boehmite sol and coated on a porous alumina substrate before firing at 500°C. It was foundthat the permeability of hydrogen and the separation factor for a hydrogen-nitrogen gaseous mixture of these metaldispersed membranes exceeded the limitations of the Knudsen diffusion mechanism. Although the gas permeation through a neat alumina membrane is governed by the Knudsen diffusion, the metals dispersed in alumina membranes were effective in promoting hydrogen permeation. These metaldispersed alumina membranes were also used in a membrane reactor for methane steam reforming at low temperature. In the temperature range of 300 to 500°C, the membrane reactor attained a methane conversion twice as high as the equilibrium value of the packed bed catalytic reactor system as a result of the selective removal of hydrogen from the reaction system.