VAc／MMA半连续乳液共聚合的研究：Ⅱ分子量及其分布

以过硫酸铵为引发剂，十二烷基硫酸钠为乳化剂，于７０℃下进行了ＶＡｃ／ＭＭＡ乳液共聚合试验。试验确定了不同组成ＶＡｃ／ＭＭＡ共聚物的Ｍａｒｋ－Ｈｏｕｗｉｎｋ方程参数Ｋ和α值。对ＧＰＣ测试数据处理给出了加料速率，乳化剂量，单体比例及种子与非种子法对分子是及其分布的影响。     

Information cut for clustering using a gradient descent approach

We introduce a new graph cut for clustering which we call the Information Cut. It is derived using Parzen windowing to estimate an information theoretic distance measure between probability density functions. We propose to optimize the Information Cut using a gradient descent-based approach. Our algorithm has several advantages compared to many other graph-based methods in terms of determining an appropriate affinity measure, computational complexity, memory requirements and coping with different data scales. We show that our method may produce clustering and image segmentation results comparable or better than the state-of-the art graph-based methods.     

人参皂苷Rg分子轨道微扰理论的研究

人参皂苷Rg是具有生理活性的物质，它包括三个异构体：Rg1；Rg2；Rg3其中R83具有很强的抗癌作用。本文通过休克尔分子图形理论对Rg异构体的各分子轨道进行约化，并且根据分子轨道微扰理论求出它们不同本征多项式和本征值。     

Molecular Diffusion Coefficients of Organic Compounds in Water at Different Temperatures

Molecular (or tracer) diffusion coefficient data were obtained for 2-naphthol, benzoic acid, salicylic acid, camphor, and cinnamic acid in water at temperatures that differ significantly from ambient value. Experimental values were determined for the dissolution of 2-naphthol in water at 283 to 368 K, of benzoic acid in water at 283 to 338 K, of salicylic acid in water at 283 to 343 K, of camphor in water at 283 to 318 K, and of cinnamic acid in water at 283 to 318 K. Empirical correlations are presented for the prediction of molecular diffusion coefficient over the entire range of temperatures studied, and they are shown to predict the obtained data with very good accuracy.     

活性碳和5A分子筛的吸附特性及其在真空获得中的作用

评述了活性碳和５Ａ分子筛的吸附等温线及其在真空佩温绝热夹层真空获得中的作用。分析了真空夹层抽真空除气时用Ｎ＿２气置换以及用“多次吸附－脱附Ｎ＿２气”方法活化吸附剂等先进工艺的机理。论述了根据吸附剂吸水的吸附等温线，合理确定活化工艺条件的方法。     

基于模糊修正熵权TOPSIS的战时装备供应链风险评估

针对战时装备供应链的特点,以远程精确打击、敌特后方袭扰和恶劣天气等三个因素为主要风险指标,运用修正的模糊信息熵权对TOPSIS法进行改进,提出了一种新的战时装备供应链风险评估方法。首先利用原始数据产生的模糊信息熵权进行客观赋权,并引入专家因素对权重进行主观修正,利用逼近理想解排序方法进行运算,最后通过实例计算与分析,验证该评估方法简便易行,结论合理,有效降低了指挥员决策的主观随意性。     

遗传算法和Dijkstra算法在动态权值系统中的比较

针对遗传算法和Dijkstra算法在求解动态权值系统中最短路径时的性能问题,采用比较法,将两种算法应用在同一个实际游戏模型中,对其算法的稳定性、智能性、时间复杂度进行对比测试。游戏模型模拟了各种条件下的动态权值系统。为了使遗传算法更加可靠,通过优化其变异过程使得收敛速度更快,可靠性更高。实验数据表明,遗传算法在每张地图上的得分数以及算法所用时间普遍高于Dijkstra算法,从而得出遗传算法在求解动态权值系统中最短路径问题时稳定性和预期效果明显好于Dijkstra算法,但其时间复杂度较高的结论。     

裂纹对石墨烯拉伸力学性能影响的数值仿真

为研究裂纹对石墨烯力学性能的影响,以锯齿型石墨烯为研究对象,基于分子动力学方法,采用Tersoff势函数分析裂纹长度对石墨烯拉伸力学性能的影响以及含有裂纹的石墨烯在不同应变率下的拉伸变形破坏过程.结果表明,裂纹长度的增加大大减小石墨烯的抗拉强度和抗拉应变,对弹性模量有一定影响;裂纹降低石墨烯的抗拉应变对应变率的敏感性,但对于含有裂纹的石墨烯,仍可以增大加载速率来提高石墨烯的抗拉性能.     

基于级差最大化组合赋权法的地下水功能评价

针对地下水功能评价中单独采用主观赋权法或客观赋权法存在的问题,结合二者的优点,采用基于主观赋权的层次分析法与客观赋权的熵权法相结合的级差最大化组合赋权法评价地下水功能,并通过计算不同赋权方法权重结果与平均值的相对偏差来衡量级差最大化组合赋权法的准确性。将该方法应用于伊犁河谷西北部平原区浅层地下水功能评价,评价结果基本符合评价区实际情况,验证了该评价方法在地下水功能评价中的可行性。     

Viscosities of nonelectrolyte liquid mixtures. I. binary mixtures containing p-dioxane

Viscosity measurements are reported for p-dioxans with cyclohexane, n-hexane, benzene, toluene, carbon tetrachloride, tetrachloroethane, chloroform, pentachloroethane, and ethyl acetate at 303.15 K. Excess Gibbs energies of activation G ^*E of viscous flow have been calculated with Eyring's theory of absolute reaction rates. The deviations of the viscosities from a linear dependence on the mole fraction and values of G ^*E for binary mixtures have been explained in terms of molecular interactions between unlike pairs. The Prigogine-Flory-Patterson theory has been used to estimate the excess viscosity, ln , and corresponding enthalpy ln _H, entropy ln _S, and free volume ln _v terms for binary mixtures of p-dioxane with cyclohexane, n-hexane, benzene, toluene, carbon tetrachloride, and chloroform. Estimates of excess viscosities from this theory for p-dioxane with benzene, toluene, and carbon tetrachloride are good, while for the other three mixtures they are poor. The local-composition thermodynamic model of Wei and Rowley estimates the excess viscosity quite well even for p-dioxane mixtures with cyclohexane and n-hexane.