全文获取类型
收费全文 | 2689篇 |
免费 | 431篇 |
国内免费 | 88篇 |
专业分类
电工技术 | 12篇 |
综合类 | 96篇 |
化学工业 | 568篇 |
金属工艺 | 338篇 |
机械仪表 | 108篇 |
建筑科学 | 56篇 |
矿业工程 | 292篇 |
能源动力 | 38篇 |
轻工业 | 36篇 |
水利工程 | 1篇 |
石油天然气 | 122篇 |
武器工业 | 10篇 |
无线电 | 120篇 |
一般工业技术 | 406篇 |
冶金工业 | 950篇 |
原子能技术 | 47篇 |
自动化技术 | 8篇 |
出版年
2024年 | 10篇 |
2023年 | 46篇 |
2022年 | 61篇 |
2021年 | 77篇 |
2020年 | 105篇 |
2019年 | 95篇 |
2018年 | 107篇 |
2017年 | 104篇 |
2016年 | 111篇 |
2015年 | 95篇 |
2014年 | 173篇 |
2013年 | 227篇 |
2012年 | 186篇 |
2011年 | 228篇 |
2010年 | 143篇 |
2009年 | 113篇 |
2008年 | 107篇 |
2007年 | 152篇 |
2006年 | 151篇 |
2005年 | 139篇 |
2004年 | 105篇 |
2003年 | 123篇 |
2002年 | 77篇 |
2001年 | 86篇 |
2000年 | 68篇 |
1999年 | 53篇 |
1998年 | 39篇 |
1997年 | 28篇 |
1996年 | 31篇 |
1995年 | 32篇 |
1994年 | 29篇 |
1993年 | 25篇 |
1992年 | 16篇 |
1991年 | 17篇 |
1990年 | 13篇 |
1989年 | 10篇 |
1988年 | 6篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1951年 | 2篇 |
排序方式: 共有3208条查询结果,搜索用时 15 毫秒
31.
退火温度对掺杂钼板性能的影响 总被引:1,自引:0,他引:1
本文简述了退火温度对掺杂钼板的室温抗拉性能、弯曲塑-脆转变温度及室浊反复弯曲性能影响。试样经1300℃真空退火-小时后,其室温抗拉强度为585MPa,伸长率为31%,弯曲塑-脆转转变温度低于-78℃,室浊进反复弯曲90度的次21次;经1800℃退火后,其室温抗拉强度为495MPa,伸长率为48%,弯曲塑-脆转变温度为40℃,室温时反复弯曲90度的次数为6次。 相似文献
32.
再谈高速走丝线切割机断丝原因的分析及对策 总被引:3,自引:0,他引:3
针对高速走丝电火花线切割加工的断丝问题,从各个方面补充分析了线切割加工中的断丝原因及解决方法,这些方法能切实有效地减少断丝的发生。 相似文献
33.
卡尔曼滤波分光光度法同时测定钛锡钼钨 总被引:5,自引:0,他引:5
以两性表面活性剂溴化十六烷基二甲基氨基乙酸作为新增效试剂,研究了钛、锡、钼、钨邻氯苯基荧光酮显色体系的光度性质,并用卡尔曼滤波分光光度法进行同时测定。合成试样中钛、锡、钼、钨的回收率范围及相对标准偏差分别为96.2%~106.3%、96.7%~104.5%、92.2%~107%、97.7%~105.6%和3.76%、3.24%、5.09%、2.81%;合金钢样中微量钛、锡、钼、钨测定的相对误差为5.0%~11.8%。 相似文献
34.
P. Da Costa C. Potvin J.-M. Manoli M. Breysse G. Djega-Mariadassou 《Catalysis Letters》2003,86(1-3):133-138
Hydrodesulfurization (HDS) of 4,6-dimethyldibenzothiophene on alumina-supported Mo2C has been studied. These catalysts are stable and active under deep HDS conditions (0-250 wt ppm S). However, although they are well known to have hydrogenation properties, they lead preferentially to a non-hydrogenated product of the HDS reaction: dimethylbiphenyl. For the same reaction, supported platinum and sulfided molybdenum oxide lead to the hydrogenated products dimethyldicyclohexyl and methylcyclohexyltoluene, respectively. The ranking of HDS activity is as follows: MoS2/Al2O3 < Mo2C/Al2O3 < Pt/SiO2. 相似文献
35.
Michael Kmetz Steven L. Suib Francis S. Galasso 《Journal of the American Ceramic Society》1989,72(8):1523-1524
The strength and toughness of fibrous composites depend on the interface properties which control the bonding between the fibers and matrices. One method of controlling the interface involves coating the fiber with an appropriate material. In a previous study, it was found that there is a definite advantage in using low coating temperatures to prevent fibers from degrading. We therefore were interested in a report that Mo2 C could be deposited from Mo(CO)6 at temperatures as low as 300° to 475°C. Our studies indicated that the material was not Mo2 C, but an oxycarbide, which, with an analogous tungsten oxycarbide coating, was applied to SiC yarns. Both oxycarbides could be converted to the metals by heat-treating in N2 . 相似文献
36.
A set of Co promoted 10% Mo/Al2O3 samples have been characterized by means of Raman spectroscopy under ambient as well as in situ dehydrated conditions. Under ambient conditions, the degree of the polymerization of surface molybdenum oxide species decreases with increasing Co loading. Under dehydrated conditions, the polymeric molybdenum oxide species is absent with the addition of only 0.2% Co. At low Co loadings (2%), before the formation of CoMoO4 compound, the spectral features are very similar under ambient conditions. Dehydration causes the upward shift of the Mo=O symmetric stretching mode. A broad band around 920–930 cm–1 was thus observed. This band has been suggested to be associated with the Co-Mo interaction species. In contrast to crystalline CoMoO4, this species shows a reversibility on H2 reduction-O2 reoxidation treatments. From the results obtained, it is proposed that cobalt oxide interacts with the most polymerized molybdenum oxide species to form Co-Mo interaction species and/or crystalline CoMoO4; therefore, the amount of the surface molybdenum oxide species decreases with a change in the molecular structure as a function of the Co concentration. 相似文献
37.
Gang Wang Wan Jiang Guangzhao Bai Libin Wu 《Journal of the American Ceramic Society》2003,86(4):731-34
A type of aluminosilicate that has a good wetting property for molybdenum disilicide (MoSi2 ) was added to a MoSi2 matrix to study the effects on the microstructure and low-temperature oxidation. It was found that the composites had not only good low-temperature oxidation resistance but also high thermal shock resistance when the added oxides formed a network microstructure in the matrix. There was no appreciable oxidation gain for MoSi2 /oxide composites with a network microstructure at 773 K for 2500 h. The results indicate that microstructure design is a simple and effective solution to preventing the low-temperature oxidation of MoSi2 . 相似文献
38.
通过结构设计和负荷计算,研制出适合于实验室使用的以钼丝为电热体,电熔镁砂或镁铝尖晶石为沪芯材料,H2-N2混合气体为保护气氛和最高使用温度达1950℃的内挂式氢气钼丝炉。 相似文献
39.
Dehydroaromatization of methane to benzene occurs over a 2 wt% Mo/ZSM-5 catalyst at 700C under non-oxidizing conditions. Following an initial induction period, during which CH4 reactant reduces the original Mo6+ ions in the zeolite to Mo2C and deposition of coke occurs, a benzene selectivity of 70% at a CH4 conversion of 8–10% could be sustained for more than 16 h. X-ray photoelectron spectroscopy and X-ray powder diffraction measurements indicate that the reduced Mo is highly dispersed in the channels of the zeolite. Initial activation of CH4 reactant occurs on Mo2C sites, leading to the formation of C2H4 as the primary product. The latter then undergoes subsequent oligomerization reactions on acidic sites of the zeolite to form aromatic products. 相似文献
40.
The effect of Mo loading, calcination temperature, reaction temperature and space velocity on the catalytic performance of methane dehydrogenation and aromatization without using oxidants over Mo/HZSM-5 has been studied. The XRD and BET measurements show that Mo species are highly dispersed in the channels of the HZSM-5 zeolite, resulting from the interaction between the Mo species and the zeolite, which also leads to a decrease in its crystallinity. The Brønsted acidity, the channel structure and the state and location of Mo species in the zeolite seem to be crucial factors for its catalytic performance. It was found that 2% Mo/HZSM-5 calcined at 773 K showed the best aromatization activity among the tested catalysts, the methane conversion being 9% at 1013 K with the selectivity to aromatics higher than 90%. The experimental results obtained from the variation of space velocity gave evidence that ethylene is an initial product. On the basis of these results a possible mechanism for methane dehydrogenation and aromatization has been proposed in which both the heterolytic splitting of methane in a solid acid environment and a molybdenum carbene-like complex as an intermediate are of significance. 相似文献