油墨用聚氨酯胶粘剂的性能研究

主要研究用于印刷油墨的单组分溶剂型聚氨酯粘合剂，考查聚合物多元醇类型对树脂微观形态、机械性能以及印刷适应性和附着性等性能的影响。研究结果表明，聚酯型树脂的微相分离程度低于聚醚型，具有较好的机械性能、印刷适应性和附着性。     

定向凝固Al/C复合材料研究

本文首次进行了Al/C(SiC)复合材料定向凝固,研究了复合材料定向凝固过程以及组织形态与凝固速率的关系,获得了纤维束间胞晶和不同间距的树枝晶,发现非润湿系统复合材料定向凝固后性能降低,文中对其机制进行了探讨.     

尼龙6/马来酸酐-苯乙烯多单体接枝聚丙烯反应共混物

用双螺杆挤出机制备了聚丙烯(PP)与尼龙6(PA6)的共混物．先用多组分熔融接枝的方法将马来酸杆（MAH）和苯乙烯（St）共同接枝于聚丙烯（PP）上，制得多单体接枝聚丙烯PP-g-(MAH-St），该接枝物具有较高的MAH接枝率。利用MFR、SEM、TEM和力学性能测试等分析方法，研究了多组分熔融接枝聚丙烯PP-g-(MAH-St)对PA6/PP共混物的形态结构和力学性能等的影响。结果表明，PP-g-(MAH-St)中的酸酐基团与PA6末端的氨基发生化学反应，原位形成的PP-PA6共聚物能有效地改善PA6与PP的相容性，可以使PP均匀地分散在PA6基体中，相区尺寸明显减小，可至0.1μm，并使共混物的力学性能得到均衡的提高，冲击韧性的提高尤其显著，达到了橡胶改性所难以达到的效果。     

Synthesis and characterization of poly(siloxane-urethane)s

A series of polyurethane block copolymers based on hydroxy-terminated polydimethylsiloxane and poly(propylene glycol) soft segments of molecular weights 1818 and 2000, respectively, were synthesized. The hard segments consisted of 4,4′-diphenylnethane diisocyanate and 1,4-butanediol as the chain extender. Samples with different molar ratios were prepared. We tried to synthesize polydimethylsiloxane-based polyurethanes (PDMS-PU) containing a hard block as major fraction and a soft block as minor fraction for preparing toughened rigid systems. After a study of the pure polydimethylsiloxane-based polyurethane and poly(propylene glycol)-based polyurethane (PPG-PU), (mixed polyol)-based block copolymers and blends of PDMS-PU and PPG-PU were synthesized, and characterized by means of differential scanning calorimetry, tensile testing and scanning electron microscopy. In (mixed polyol)-based copolymers and lower hard-segment content blends, macro-phase separation occurred, but blends with higher hard-segment contents showed significant reduction in amounts of phase separation.     

Morphological and kinetics study of PEO/PVC blends

The kinetics of spherulite radial growth and the morphology of the compatible system PEO/PVC have been studied by optical microscopy. The usual spherulite radial growth behaviour has been found for compatible blends with PEO content higher than 70%. For lower composition, distortion of the usual spherulite morphology has been observed; the anomalies have been attributed to partial miscibility of the components.     

Thermal Characterization of 1.3 μm InAsP/InGaAsP Ridge Waveguide MQW Lasers Based on Spectroscopy Method

An experimental way to analyze the thermal characterization of semiconductor lasers based on spectroscopy method under pulse driving conditions has been developed. By using this way the thermal characteristics of strain compensated 1.3 μm InAsP/InGaAsP ridge waveguide MQW laser diodes have been investigated. Results show that by measuring and analyzing the lasing spectra under appropriate driving parameters and temperature ranges, the thermal resistance of the laser diodes could be deduced easily. A higher thermal resistance of 640 K/W has been measured on a narrow ridge laser chip without soldering. Other thermal and spectral properties of the lasers have also been measured and discussed.     

HPVC／PP共混改性研究：Ⅲ低分子量反应性化合物作相容剂

采用低分子量反应性化合物作相容剂，即化学交联体系来改善ＨＰＶＣ／ＰＰ共混物的相容性。考察了在不同共混比下，不同化学交联体系对共混物力学性能的影响，并观察了共混物的微观形态。结果表明，采用低分子量反应性化合物作相容剂，共混物的拉伸强度提高，但冲击强度无改善。分散相尺寸减小，相间粘接得到改善。并比较了３种增容方法的效果，发现ＣＰＥ是ＨＰＶＣ／ＰＰ共混物的最佳相容剂。     

聚苯硫醚酰胺的合成与表征

用4-氯苯甲酰4′-氯苯胺和硫化钠为原料在常压下合成了聚苯硫醚酰胺,并对其进行了表征。结果表明所合成的产物为结晶性聚合物,并且有较高的热稳定性。     

Hydrothermal Synthesis of Acicular Lead Titanate Fine Powders

A pure, acicular lead titanate (PbTiO₃) fine powder with a white color has been prepared by hydrothermal synthesis. It is a new phase of PbTiO₃ with I 4 symmetry, cell parameters of a = 12.358 Å and b = 14.541 Å, and a density of 6.80 g.cm⁻³. The influences of pH (12.5 to 14.4), Pb/Ti ratio (1.0 to 1.6) in the feedstock, reaction temperature (130° to 230°C), time (0.25 to 4 h), starting materials, and additives on the formation of acicular PbTiO₃ under hydrothermal conditions have been investigated. The acicular PbTiO₃ with I 4 symmetry, referred to as the PX phase, can be converted to the perovskite-type (PE phase) of PbTiO₃ at about 605°C while its acicular morphology is essentially unchanged. The preferable conditions for preparing pure acicular PX-phase PbTiO₃ are that the pH is 13.0 to 14.0, Pb/Ti ratio is >1.3, reaction temperature is 170° to 200°C, time is 0.5 to 1.0 h, titanium butoxide (Ti[O(CH₂)₃CH₃]₄) is the starting material, and poly(vinyl alcohol) is an additive. The acicular grain of the PX phase is usually less than 100 nm in diameter and more than 1000 nm in length.     

降凝剂对高蜡稠油的改性效果及机理研究

实验研究了工业品原油降凝剂WHP改善含蜡56.9%、其中96.6%为正构烷烃的胜利郑王庄稠油流动性的效果。WHP含乙烯/醋酸乙烯/乙烯醇嵌段聚醚三元共聚物30%-35%。在60℃将WHP加入稠油中,测定其凝点和32℃、0-42.6 s^-1范围5个剪切速率下的黏度,均随WHP加量的增加（50-300 mg/L）而降低,200 mg/L为最佳加量,在该加量下0.32 s^-1黏度由34.16 Pa·s降至79.2 mPa·s,凝点（℃）、屈服值（Pa）、稠度系数（Pa·s^n）分别由49.0、32.42、31.57降至39.5、0.1297、0.02142,流型指数由0.1176升至0.9790。由黏温曲线求出,加入200mg/L WHP使该稠油析蜡点由65℃降至58℃,反常点由70℃降至50℃。根据空白和加剂原油扫描电镜照片显示的蜡晶形态,利用共晶机理分析讨论了WHP这种高分子表面活性剂的降凝、降黏、改善流动性的作用。图3表3参5。