Kelvin Probe measurements of polymer coated gold substrates: Mechanism studies

The origin of work-function changes induced in polymer/metal structures (polyacrylic acid (PAA), ammonium and sodium polyacrylate) upon ammonia exposure is studied. To understand and explain the mechanism systematic measurements of uncoated and polymer coated metals are performed in Kelvin Probe (KP) setups. Additional data have been acquired through gravimetric and electrochemical experiments (cyclic voltammetry (CV)). The results obtained confirm that the field effect sensitive processes are taking place at the metal/polymer interface and allow their modelling. The intrinsic sensitivity of metallic samples upon ammonia exposure is influenced by the presence of coating polymers, by their ability to sorb water and to keep the metal surface wet or dry.     

游戏程序设计中若干问题的探讨

游戏编程是当今程序设计的一个热点,开发过程会遇到各种各样的问题。通过限制构造函数和拷贝函数,设计一个单体全局管理类,可以避免不合适的调用。采用分块技术加栽地图,可以在时空性能上优化游戏。阐述了D3D的空间坐标变换。分析了万向节死锁问题发生的原因,并提出了解决办法。     

下一代跨校区数字化校园网实现策略与研究

我国高等教育的快速发展促使大校合并、校区扩建,VPN技术建设校园网使教学资源得到充分优化利用的一种虚拟教育环境。随中国互联网客户逐年增多,IPv4地址问题日趋严重,互联网向IPv6过渡已是大势所趋。本文从VPN和IPV6升级技术、实施方案等方面讨论下一代跨校区数字化校园网实现策略与研究。     

各种网络拥塞控制机制的实现及比较

随着网络应用的迅猛发展,网络拥塞成为一个不可避免的问题,拥塞控制已经成为当前网络研究的重点。为了使网络得到充分的利用,研究者提出了多种拥塞控制机制,并且得到不断的改进。该文通过比较各种典型控制算法的优缺点,来对网络拥塞控制机制作个综合阐述。     

一种高效无线传感器网络认证及密钥协商方案

随着无线传感器网络在社会各个领域的渗透,其安全机制的研究一直是无线传感器网络的研究热点。在分析了无线传感器网络中认证及密钥协商方案设计时应满足条件的基础上,基于单向HASH函数和对称密码算法,设计了无线传感器网络中传感器节点间一种高效的认证及密钥协商方案。并从互认证、会话密钥、可抵御攻击等方面对该方案的安全性进行了分析,说明了该方案的安全性能较好,可有效抵御典型攻击行为;详细比较该方案和现有类似方案的运行性能,结果表明,该方案在存储容量需求、计算复杂性和通信带宽需求方面均优于现有方案。     

选举策略在分布式系统死锁避免中的应用

将单机系统或集中式系统中的死锁避免策略移植到分布式需要面临并发性和冲突问题的解决。本文通过分析二阶段锁的机制,引入了一种应用选举策略来幽雅地解决分布式系统中死锁避免所碰到问题的算法。     

基于FPGA硬件实现的谐波检测方法

针对现有系统对谐波检测实时性差和精度低的问题,介绍一种基于傅立叶变换和FPGA硬件实现的谐波检测方法.分析了谐波检测中影响测量精度的关键因素,采用数字锁相环来同步被测信号,以减小由非同步采样所产生的误差.基-4FFT 处理器的硬件设计采用全并行的乘法运算单元结构和并行的存储分配方法,最大限度地提高谐波检测的速度.数字锁相环和基-4 FFT 算法用VHDL语言设计实现,并用MAX plus Ⅱ软件进行仿真,仿真结果表明,所设计的数字锁相环可以很好地跟踪被测信号,在180ms时,误差仅为0.01Hz,很好地消除了非同步采样所引起的测量误差;采用所设计的基-4FFT运算器对给定的谐波数据进行运算,得到的谐波幅值和相位误差小于0.05%,运算时间仅为8μs.     

One-Component Artificial Gustatory System Based on Hydrogen-Bond Organic Framework for Discrimination of Versatile Analytes

Hydrogen-bond organic frameworks (HOFs) with excellent structural and luminescent properties have emerged as a promising material for the construction of fluorescence sensors. However, designing a facile, universal and high throughput sensor with multiplex detection capacity still remains challenging. Herein, a one-component sensor array is constructed that mimics natural gustatory system for accurate and high-throughput discrimination and identification of versatile analytes. HOF as a single sensing element greatly simplifies the probe preparation in sensor array and detection procedure. Metal ions, proteins and bacteria as the model targets are rapid and accurately discriminated, presenting the universality of the system. Particularly, the system is successfully used for the classification of antibiotic mechanisms. The study expands the application scope of HOFs and provides a facile and universal system for sensing applications.     

Recent Development of Jumping Motions Based on Soft Actuators

Drawing inspiration from the jumping motions of living creatures in nature, jumping robots have emerged as a promising research field over the past few decades due to great application potential in interstellar exploration, military reconnaissance, and life rescue missions. Early reviews mainly focused on jumping robots made of lightweight and rigid materials with mechanical components, concentrating on jumping control and stability. Herein, attention is paid to the jumping mechanisms of soft actuators assembled from various soft smarting materials and powered by different stimulus sources. The challenges and prospects of soft jumping actuators are also discussed. It is hoped that this review will contribute to the further development of soft jumping actuators and broaden their practical applications.     

Relaxation-Induced Significant Room-Temperature Dielectric Pulsing Effects

Thermo-responsive dielectric materials are in urgent demand owing to the rapid development of smart electronic/electrical systems. Although different types and structures of thermally responsive dielectric materials have been continuously reported, their dielectric response behaviors all originate from thermodynamic phase transitions. Herein, it is demonstrated that structural relaxation in poly(vinylidene fluoride) (PVDF), a non-thermodynamic phase transition, can induce a significant thermal dielectric pulse at room temperature. The dielectric pulse strength of up to 6.3 × 10⁵ at 20 Hz, with a dielectric pulsing temperature of 24 °C, is achieved from polyethylene glycol (PEG)-PVDF coaxial nanofibrous films (PVDF@PEG), fabricated via a continuous blow spinning method. Moreover, the films exhibit excellent flexibility, adjustable strength and toughness, switchable hydrophilicity/hydrophobicity, and effective thermal management capability. The relaxation-induced dielectric pulsing effect, outstanding multifunctionality, and simple preparation combine to promote further scalability and prospects of PVDF@PEG. In particular, the work contributes to the discovery of the relaxation-induced dielectric response mechanism, which provides a new strategy for the generation of thermo-responsive dielectric materials.