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41.
Hydroprocessing catalysts based on Ni, Co, Mo and W are used in various refinery processing applications where several deactivation mechanisms become of importance (coke formation, active phase sintering, metals deposition, poisoning) in the catalyst's life cycle. The life cycle of commercial hydroprocessing catalysts is very complex and includes the catalyst production, sulfidation, use, oxidative regeneration followed by re-sulfidation and reuse or, if reuse is not possible, recycling or disposal. To understand the changes in catalyst properties taking place during a life cycle, the catalyst quality in the different stages can be best monitored by using advanced analytical techniques. The catalyst's life cycle is further complicated by numerous technical, environmental and organizational issues involved. In principle, different companies can be involved in each of the life cycle steps. Leading catalyst manufacturers, together with specialized firms, offer refineries a total catalyst management concept, starting with the purchase of the fresh catalyst and ending with its final recycling or disposal. Total catalyst management includes a broad range of services, ensuring optimal timing during the change-out process, reliable, smooth and safe operations, minimal downtime and maximum catalyst and unit performance. 相似文献
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43.
High crude oil prices and pollution problems have drawn attention to alternative vehicle technologies and fuels for the transportation sector. The question is: What are the benefits/costs of these technologies for society? To answer this question in a quantitative way, a web-based model (http://vehiclesandfuels.memebot.com) has been developed to calculate the societal life cycle costs, the consumer life cycle costs and the tax for different vehicle technologies. By comparing these costs it is possible to draw conclusions about the social benefit and the related tax structure. The model should help to guide decisions toward optimality, which refers to maximum social benefit. The model was applied to the case of Thailand. The life cycle cost of 13 different alternative vehicle technologies in Thailand have been calculated and the tax structure analyzed. 相似文献
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45.
利用寿命周期评价的思想,计算了炼铁生产过程中的环境负荷,并分析了各因素对环境负荷的影响,运用神经网络对炼铁生产过程环境负荷进行了预测。 相似文献
46.
在Booth算法的基础上,结合MIPS 4KC微处理器中的流水线结构和乘法器的工作过程,提出了一种改进的Booth乘法器的设计方法,并采用全制定方法实现,用这种方法实现的乘法器单元具有面积小、单元电路可重复性好、版图设计工作量小、功耗低等特点. 相似文献
47.
Yun‐Hwei Shen 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(5):581-586
A novel strategy of sweep coagulation to treat low turbidity water is presented herein. Study findings demonstrated that an Na+‐saturated bentonite with medium cation exchange capacity (CEC) resulted in significant turbidity removal at a bentonite dosage of 30 mg dm?3. Bentonite dispersion with fully delaminated platelets tended to undergo a more porous type of coagulation with intense face‐to‐face interactions of platelets and effectively entrapped TiO2 particles in band‐type structures. This type of coagulation usually results in a large volume of settled flocs with a fluffy structure and excellent turbidity removal efficiency for sweep coagulation. The sign and magnitude of electrical charge on TiO2 particles has a minor effect on the efficiency of sweep coagulation. Copyright © 2005 Society of Chemical Industry 相似文献
48.
Y. MURAKAMI K. TAKAHASHI R. KUSUMOTO 《Fatigue & Fracture of Engineering Materials & Structures》2003,26(6):523-531
ABSTRACT The fatigue crack growth behaviour of 0.47% carbon steel was studied under mode II and III loadings. Mode II fatigue crack growth tests were carried out using specially designed double cantilever (DC) type specimens in order to measure the mode II threshold stress intensity factor range, ΔKIIth. The relationship ΔKIIth > ΔKIth caused crack branching from mode II to I after a crack reached the mode II threshold. Torsion fatigue tests on circumferentially cracked specimens were carried out to study the mechanisms of both mode III crack growth and of the formation of the factory‐roof crack surface morphology. A change in microstructure occurred at a crack tip during crack growth in both mode II and mode III shear cracks. It is presumed that the crack growth mechanisms in mode II and in mode III are essentially the same. Detailed fractographic investigation showed that factory‐roofs were formed by crack branching into mode I. Crack branching started from small semi‐elliptical cracks nucleated by shear at the tip of the original circumferential crack. 相似文献
49.
YOSHIHARU KARIYA TADATOMO SUGA 《Fatigue & Fracture of Engineering Materials & Structures》2007,30(5):413-419
This paper details the deformation mechanism and low‐cycle fatigue life of eutectic solder alloys at high temperature (around 0.8Tm). Grain boundary sliding generally nucleates a wedge‐type cavity that reduces the low‐cycle fatigue life of metals. In this study, grain boundary sliding has promoted intergranular failure contributing to the reduction in fatigue life of Sn–Ag–Cu alloy. However, grain boundary sliding has exerted no deleterious effects on fatigue resistance of eutectic Pb–Sn and Bi–Sn alloys. The phase boundary sliding with very fine microstructure induces exceptional ductility in these alloys leading to superior low‐cycle fatigue endurance for theses eutectic Pb–Sn and Bi–Sn alloys. 相似文献
50.
P.-Y. CHANG J.-M. YANG H. SEO H. T. HAHN 《Fatigue & Fracture of Engineering Materials & Structures》2007,30(12):1158-1171
The off‐axis fatigue cracking behaviour of notched fibre metal laminates under constant amplitude loading conditions was investigated experimentally and numerically. It was found that the off‐axis fatigue crack initiation life decreased as the off‐axis angles increased. This indicated that the off‐axis laminates raised the applied stress level in the aluminium (Al) layer and subsequently resulted in earlier cracking in the Al layer. The off‐axis fatigue crack initiation lives of notched fibre metal laminates were predicted using lamination theory and an energy‐based critical plane fatigue damage analysis from the literature. After a crack initiated in the Al layer, it was observed that the crack path angles of the off‐axis specimens were neither perpendicular to the fibre nor to the loading direction. A finite‐element model was established for predicting the crack path angles. 相似文献