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21.
《International Journal of Hydrogen Energy》2021,46(64):32403-32412
Porous carbon nanostructures are promising supports for stabilizing the highly dispersed metal nanoparticles and facilitating the mass transfer during the reaction, which are critical to achieve the high efficiency of hydrogen generation from sodium borohydride dehydrogenation. Herein, the catalytically active porous architectures are simply prepared by using 2-methylimidazole and melamine as reactive sources. The structural and compositional characterizations reveal the coexistence of metallic cobalt and N-doped carbon in porous architectures. Electron microscopy observations indicate that the synthesized products are smartly constructed from the carbon nanosheets with densely dispersed Co nanoparticles. Due to the notable structural features, the prepared Co@NC-600 sample presents the highly efficient activity for catalytic hydrolysis of NaBH4 with a hydrogen generation rate of 2574 mL min−1 gcat−1 and an activation energy of 47.6 kJ mol−1. The catalytically active metallic Co and suitable support-effect of N-doped carbon are responsible for catalytic dehydrogenation. 相似文献
22.
Serdar Akbayrak Yalçın Tonbul Saim Özkar 《International Journal of Hydrogen Energy》2021,46(27):14259-14269
Herein, we report the use of tungsten(VI) oxide (WO3) as support for Rh0 nanoparticles. The resulting Rh0/WO3 nanoparticles are highly active and stable catalysts in H2 generation from the hydrolysis of ammonia borane (AB). We present the results of our investigation on the particle size distribution, catalytic activity and stability of Rh0/WO3 catalysts with 0.5%, 1.0%, 2.0% wt. Rh loadings in the hydrolysis reaction. The results reveal that Rh0/WO3 (0.5% wt. Rh) is very promising catalyst providing a turnover frequency of 749 min?1 in releasing 3.0 equivalent H2 per mole of AB from the hydrolysis at 25.0 °C. The high catalytic activity of Rh0/WO3 catalyst is attributed to the reducible nature of support. The report covers the results of kinetics study as well as comparative investigation of activity, recyclability, and reusability of colloidal(0) nanoparticles and Rh0/WO3 (0.5 % wt. Rh) catalyst in the hydrolysis reaction. 相似文献
23.
阜阳地区石炭-二叠系煤系烃源岩特征 总被引:2,自引:0,他引:2
阜阳地区石炭-二叠系煤系地层发育,但由于勘探程度较低,对该区煤系地层烃源岩的生烃潜力认识不清,严重制约了该区的油气勘探。在已有资料的基础上,通过有机地球化学和有机岩石学方法并结合模拟实验,探讨了该区煤系烃源岩的生烃潜力。研究结果表明阜阳地区石炭-二叠系煤系烃源岩有机质丰度达到中等-好烃源岩标准,有机质类型以腐殖型为主,盆地模拟结果显示阜阳地区石炭-二叠系煤系地层油资源量为(30.47~152.33)×106t,气资源量为(266.7~1333.7)×108m3,展示阜阳地区石炭-二叠系煤系地层具有较好的生油气潜力。 相似文献
24.
R. Murgan F. Razak D. R. Tilley T. Y. Tan J. Osman M. N. A. Halif 《Computational Materials Science》2004,30(3-4):468-473
We derive an expression for transmittivity (TSHG) of second harmonic generation (SHG) signals from a ferroelectric (FE) film. Intensities of up and down fields in the medium are investigated in relation to TSHG. The derivations are made based on undepletion of input fields and nonlinear wave equation derived from the Maxwell equations. We present two cases: film without mirrors and with partial mirrors. Expressions for the newly derived nonlinear susceptibility coefficients of SHG for real crystal symmetry [J. Opt. Soc. Am. B 19 (2002) 2007] are used to get more realistic results. Variations in TSHG with respect to film thickness are illustrated. 相似文献
25.
As we approach 100 nm technology the interconnect issues are becoming one of the main concerns in the testing of gigahertz system-on-chips. Voltage distortion (noise) and delay violations (skew) contribute to the signal integrity loss and ultimately functional error, performance degradation and reliability problems. In this paper, we first define a model for integrity faults on the high-speed interconnects. Then, we present a BIST-based test methodology that includes two special cells to detect and measure noise and skew occurring on the interconnects of the gigahertz system-on-chips. Using an inexpensive test architecture the integrity information accumulated by these special cells can be scanned out for final test and reliability analysis. 相似文献
26.
Erik Jan Marinissen 《Journal of Electronic Testing》2002,18(4-5):435-454
Modular testing is an attractive approach to testing large system ICs, especially if they are built from pre-designed reusable embedded cores. This paper describes an automated modular test development approach. The basis of this approach is that a core or module test is dissected into a test protocol and a test pattern list. A test protocol describes in detail how to apply one test pattern to the core, while abstracting from the specific test pattern stimulus and response values. Subsequent automation tasks, such as the expansion from core-level tests to system-chip-level tests and test scheduling, all work on test protocols, thereby greatly reducing the amount of compute time and data involved. Finally, an SOC-level test is assembled from the expanded and scheduled test protocols and the (so far untouched) test patterns. This paper describes and formalizes the notion of test protocols and the algorithms for test protocol expansion and scheduling. A running example is featured throughout the paper. We also elaborate on the industrial usage of the concepts described. 相似文献
27.
28.
AutoCAD 下非结构网格自动生成 总被引:1,自引:1,他引:0
在AutoCAD环境下,从背景网格生成和数据结构两方面对推进阵面法进行修正。采用修理后的方法,使得在流场、泥沙输移和床面冲淤数值计算的前处理过程中无须精心预设内部控制点而只需给边界一个尺度,就能自动生成适应任意复杂边界的非结构网格,从而提高网格生成、优化的效率和通用性。 相似文献
29.
本文介绍了一个用户接口管理系统NUUIMS的设计和实现.重点叙述了该系统基于规范化目标用户接口模型的设计思想,系统组成及描述方法.文章也讨论了使用NUUIMS设计而成的用户接口的特点. 相似文献
30.
移动增值业务在全球的发展速度依然很快,非话音收入占电信总收入的比重越来越大.在移动增值业务的发展上,日本遥遥领先,韩国紧随其后.在中国,虽然短信业务收入开始下降,但无线应用协议(WAP)、交互式语音回应(lVR)等业务收入快速攀升,从而保证了移动增值业务在中国的发展速度.由于中国信息产业部整顿收费混乱的移动增值业务市场,使服务提供商/内容提供商(SP/CP)的暴利时代成为过去,增值业务市场进入精耕细作期.随着用户对移动增值业务新的需求的不断增长,整首音乐下载、移动E-mail以及手机电视等业务将成为未来全球最有前途的移动增值业务. 相似文献