种子法制备聚合物乳液技术的进展

从建筑乳液的生产现状、自生种子法与外加种子法的区别、种子乳液的特点及外加种子法生产的乳液特性等方面介绍了种子法制备乳液技术的进展。     

JITL-based concentration control for semi-batch pH-shift reactive crystallization of l-glutamic acid

Although concentration control (C-control) strategy has been shown to give effective and robust control performance for batch cooling and semi-batch antisolvent crystallizations in recent years, no research work was reported concerning the potential application of conventional C-control for the more challenging semi-batch pH-shift reactive crystallization that is common in the process industries. To this end, this paper presents detailed analysis to find out that it is not feasible to apply the C-control to semi-batch pH-shift reactive crystallization. To circumvent this problem, a variant of C-control strategy by incorporating the Just-in-Time Learning (JITL) method to cope with strong process nonlinearity inherent in the pH-shift reactive crystallization is developed in this paper. Simulation results are presented to illustrate the proposed design and a comparison with conventional optimal control is made.     

A polyamide-silica composite prepared by the sol-gel process

Summary A new kind of organic-inorganic hybrid composite was prepared by means of the sol-gel process. The polymer employed was a mixed-isomer aromatic polyamide having good solubility and thermal stability. The silica constituting the inorganic phase was produced by the hydrolysis and condensation of tetramethoxysilane. The bonding between the phases involved aminophenyl-trimethoxysilane, in which the amino group can react with the phthaloyl chloride end-capped polymer, and the methoxysilane groups undergo hydrolysis. The composition of these composites was varied by changing the linear polymer chain length and relative amount of tetramethoxysilane. The gelation time was found to range from a few minutes to several days. Thermogravimetric analyses showed that decomposition starts at approximately 450 °C. Thin films cast from materials having a relatively high silica content were opaque and rigid, but those with low silica content were flexible and transparent.     

液氨贮存设计分析

氨是生产含氮肥料及尿素的基本原料，为确保原料供应，必须设置其贮存设施。介绍了常温中压、降温低压和低温常压三种不同的液氨贮存工艺及其特点，并以某大型氨站设计为例，分析了液氨贮存工艺流程、主要设备、材料的选型和工艺参数的确定。     

污水COD超标的影响因素及解决措施

通过对总排污口污水中主要还原性物质逐项进行掩蔽,分析掩蔽前后污水COD值的变化,找出了影响COD的主要因素并提出了改进措施,使排污总口COD值大幅降低。     

An Experimental Study of Fatigue Strength for Adhesively Bonded Tubular Single Lap Joints

In this paper, manufacturing technology of the tubular single lap adhesive joint was studied to obtain reliable and optimal joint quality. In addition, a surface preparation method and a bonding process for the joint were devised. The effect of the adhesive thickness and the adherend roughness on the fatigue strength of the joint was experimentally investigated. From experiments, it has been found that the fatigue strength of the joint increased as the adhesive thickness decreased and the optimal arithmetic surface roughness of the adherends was about 2 μm.     

印刷胶带生产中的几个问题

对印刷胶带生产中的几个问题如稀释剂、印刷中参数、涂布工艺等作了简述。     

Processing study of a high temperature adhesive

An adhesive-bonding process cycle study was performed for a polyimidesulphone. The high molecular weight, linear aromatic system possesses properties which make it attractive as a processable, low-cost material for elevated temperature applications. The results of a study to better understand the parameters that affect the adhesive properties of the polymer for titanium alloy adherends are presented. These include the tape preparation, the use of a primer and press and simulated autoclave processing conditions. The polymer was characterized using Fourier transform infrared spectroscopy, glass transition temperature determination, flow measurements, and weight loss measurements. The lap shear strength of the adhesive was used to evaluate the effects of the bonding process variations.     

4-氨基吡啶的合成技术进展及其应用

评述了4-氨基吡啶的合成研究进展,重点介绍了硝基氮氧化吡啶法工艺。概括介绍了4-氨基吡啶在医药、农药、染料等领域的应用状况以及在国内外的生产现状。指出4-氨基吡啶合成工艺的难点在于降低生产成本,提高反应收率以及减少环境污染。建议从催化加氢还原或电化学还原过程中找到一条合乎国情的工艺路线,以推动我国吡啶系列产品的研发工作。     

神华集团孙家沟选煤厂工艺流程及设备的评价

简述了孙家沟选煤厂工艺参数的选择和设计情况及投产后的运行效果,评价认为,该厂建设速度快,工艺流程合理,设备性能良好,产品质量合格、稳定。