分析恒载效应的有限元方法

本文在Takabatake关于恒载对梁静、动力影响的研究工作的基础上,导出了梁考虑恒载效应的动力分析有限元公式,提出了荷载影响刚度矩阵的概念。分析了分布和集中两种恒载型式对简支梁和悬臂梁自振特性的影响。计算结果表明,用本文方法与Takabatake应用Galerkin方法和近似闭合解方法的结果吻合良好。同时由于本文采用了矩阵形式,不仅便于编制计算机程序,且使方法有更广泛的适用性和灵活性,可更方便地用于各种不同的构造和边界条件下的实际结构。     

Natural zeolite utilisation in pollution control: A review of applications to metals' effluents

This paper assesses the potential of natural zeolite utilization as a low-cost ion-exchange and sorbent material in pollution control and recovery of metals. The improvement of the purity of natural zeolites coupled with their chemical modification capabilities in order to provide specific properties may provide a cost-effective alternative for the treatment of heavy metal contaminated soil and water. The application of natural zeolites in industrial pollution control is becoming important and the level of technical effort is increasingly expanding. The extent of application is unlikely to be related solely to their low cost, but also to improved properties and performance characteristics, which will advance the practical implementation of natural zeolites' technology.     

热致液晶性纤维素衍生物及其热塑性塑料复合物熔体流变行为的研究

用毛细管流变仪研究了乙基纤维素（ＥＣ）及其高密度聚乙烯（ＨＤＰＥ）复合物，纤维素芳族酯（ＣＡＥ）及其聚碳酸酯（ＰＣ）复合物的剪切流变特性和机理。结果表明，ＥＣ对ＨＤＰＥ／ＥＣ复合物的粘度影响不大，而少量（５％）ＣＡＥ的加入使ＰＣ／ＣＡＥ复合物粘度大大下降，且复合物流变曲线呈现新的特征。     

Photo-reversible Reaction in Polymer Langmuir-Blodgett Films

Preparation of photoreactive Langmuir-Blodgett (LB) films was carried out using polymers/oligomers prepared from long-chain dialkyl esters of di-and tetra-olefins and having cyclobutane rings in the main chain. These polymers/oligomers formed stable monolayers on a water surface when mixed with arachidic acid. These monolayers could be deposited onto a substrate successfully forming Y-type films. The oligomer LB films were polymerized on irradiation. The polymer LB films showed a photo-reversible process between polymers and oligomers, depending on wavelength of the irradiating light. On the basis of spectral data and molecular weight change, this behaviour was found to be caused by cleavage and formation of cyclobutane rings.     

Structure and damping properties of polydimethylsiloxane and polymethacrylate sequential interpenetrating polymer networks

By using the technology of the sequential interpenetrating polymer network, a series of novel damping materials based on a polydimethylsiloxane (PDMS)/polyacrylate (PAC) matrix with polymethacrylate (PMAC) were synthesized. They have a controllable broad transition peak spanning the temperature range of 150–220°C and the medial value of loss factor with maximum of 0.35–0.60. Dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), and atomic force microscopy (AFM) were applied to analyze and characterize the transition behavior and the microphase structure of the materials. It was found that the size and height of a transition peak at both the low‐ and the high‐temperature zones change as a function not only of the concentration of PMAC and PDMS but also of the kind of PMAC; simultaneously, the low‐ temperature behavior was also governed by the crystallization of PDMS. The content of the crosslinking agent exerts a significant influence on the configuration of the curves of the transition peaks. AFM shows a characteristic phase morphology of double‐phase continuity containing a transition layer and domain less than 1 μm, indicating that the interwoven multilayer networks are the key to incorporation of the immiscible components and form a broad damping functional region. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 545–551, 2002     

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本文简要介绍了国外在开发超酸性气体过程中遇到的材料选择、腐蚀监测、水化物堵塞、超酸性气的处理和加工等问题所采取的措施和办法。     

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本文在肯定聚合物泥浆提高钻井速度的同时,也指出了该种泥浆在井内使用较长时间以后将会出现网架结构强、包被抑制性能减弱的弊病。为此,文中强调推出新的聚合物材料,研究泥浆中聚合物剩余浓度的测定方法及控制浓度的要领,提高固控效率净化泥浆等措施以解决之。     

Synthesis, structure and fluorescence properties of a highly stable indium(III)-2,5-pyridinedicarboxylate coordination polymer

The hydrothermal reaction of 2,5-pyridinedicarboxylic acid (H₂PDC), diethylene triamine and In(NO₃)₃·4.5H₂O gave rise to a two-dimensional (2D) coordination polymer In(OH)(2,5-PDC). This compound crystallizes in the orthorhombic space group Iba2, with cell parameters, a = 12.656(3) Å, b = 20.114(4) Å, c = 6.2216(1) Å, V = 1583.9(5) Å³ and Z = 8. Its structure contains one-dimensional In–O–In–O– chains, which are further linked by 2,5-PDC ligands into a 2D supramolecular neutral framework. The adjacent 2D layers are parallel with each other and construct a three-dimensional framework via hydrogen bands. At room temperature, the compound exhibits intense photoluminescence. On the basis of the results of TG/DTA analyses, the structure is thermally stable up to 390 °C.     

Binodal and spinodal curves: a simulation for various high polymer mixtures

Flory's equation-of-state theory has been used to predict the lower critical solution temperature behaviour of polymer—polymer mixtures. The spinodal phase boundary of numbers of high molecular weight polymer mixtures have been previously simulated using this theory. In this paper a procedure for simultaneous predictions of the binodal and the spinodal curves by equating the chemical potential of each component in the mixture is presented. The method is tested for five different mixtures. The effects of the binary and pure component state parameters on the simulated curves are discussed and the simulated phase diagrams are compared with the experimental cloud point curves. It is found that in most cases the results are more consistent with the cloud point curve being closer to the spinodal curve than the binodal.     

OPC技术在天然气流量计算中的应用

介绍了OPC技术及其应用于天然气流量计算的实现过程 ,设计了基于SY/T6 14 3《天然气流量的标准孔板计量方法》标准的天然气流量计算软件。该软件在新疆某输气管道项目和成都某天然气项目中都获得了成功应用