Pool boiling on a superhydrophilic surface

Titanium Dioxide, TiO₂, is a photocatalyst with a unique characteristic. A surface coated with TiO₂ exhibits an extremely high affinity for water when exposed to UV light and the contact angle decreases nearly to zero. Inversely, the contact angle increases when the surface is shielded from UV. This superhydrophilic nature gives a self-cleaning effect to the coated surface and has already been applied to some construction materials, car coatings and so on. We applied this property to the enhancement of boiling heat transfer. An experiment involving the pool boiling of pure water has been performed to make clear the effect of high wettability on heat transfer characteristics. The heat transfer surface is a vertical copper cylinder of 17 mm in diameter and the measurement has been done at saturated temperature and in a steady state. Both TiO₂-coated and non-coated surfaces were used for comparison. In the case of the TiO₂-coated surface, it is exposed to UV light for a few hours before experiment and it is found that the maximum heat flux (CHF) is about two times larger than that of the uncoated surface. The temperature at minimum heat flux (MHF) for the superhydrophilic surface is higher by 100 K than that for the normal one. The superhydrophilic surface can be an ideal heat transfer surface. Copyright © 2002 John Wiley & Sons, Ltd.     

氧浓度对近临界水中纤维素分解的影响

研究了不同初始氧浓度对纤维素在近临界水中分解的影响，实验结果表明，氧浓度显著地影响产物总碳收支平衡，液相不同组分的收率、气体的产量以及气相产物的组成，微量氧对产物总碳收支平衡影响不大，而对液相不同组分的收率有一定的影响。从实验结果可以看出，离子型反应机理在纤维素水解的第一步中起主导作用。而单糖的进一步分解是一个以自由基反应机理为主的过程。     

干扰抵消型多用户检测器性能分析

用模块化的方法描述了 ＳＩＣ、ＭＳＳＩＣ、ＰＩＣ和ＰＳＩＣ干扰抵消多用户检测算法，给出算法的实现结构图，并且在渐近有效性、抗远近效应、系统容量和实现复杂度诸方面进行了性能比较分析。分析表明需要进行功率排序的ＭＳＳＩＣ、ＰＳＩＣ和ＳＩＣ算法比ＰＩＣ算法具有更好的抗远近效应的性能，ＭＳＳＩＣ和 ＰＳＩＣ算法在渐近有效性和系统容量方面要显著强于ＳＩＣ和ＰＩＣ算法。     

New developments in speciality polymers: polymeric stabilizers

Many new speciality polymers have been developed in the last few years. In this paper polymeric stabilizers (antioxidants, flame retardants and ultraviolet stabilizers) will be discussed. Polymeric antioxidants of the hindered-phenol type, copolymers of 2,6-ditertiarybutyl-4-vinyl(or isopropenyl)phenol with styrene, methyl methacrylate, or more importantly butadiene or isoprene have been prepared; hydrogenation of the latter copolymers gave copolymers of the two polymerizable phenolic antioxidants with ethylene or ethylene/propylene. The polymeric antioxidants have been blended with diene polymers and selected polyolefins and have improved the long-term oxidative stability of these polymers. Polymeric flame retardants have been prepared by copolymerizing styrene and/or acrylonitrile with acrylates and methacrylates of aliphatic bromine-containing alcohols or bromine-containing phenols. Polymers with polymer-bound flame retardants have a higher limiting oxygen index compared with the original polymer. A new class of polymerizable ultraviolet stabilizers has also been developed; these stabilizers are styryl, α-methylstyryl, acryloyl and methacryloyl derivatives of 2(2-hydroxyphenyl)2H-benzotriazoles. These monomers have been copolymerized with styrene, acrylates and methacrylates. 2(2-Hydroxyphenyl)2H-benzotriazoles substituted in the 4 position of the benzotriazole ring with hydroxyl, acetoxy or carboxyl groups suitable for incorporation into polyesters, polycarbonates, polyamides and epoxy resins have also been synthesized. All 2(2-hydroxyphenyl)2H-benzotriazole ultraviolet absorbers and the polymers into which they are incorporated have high light absorbency with γ_max between 330 and 350 nm and extinction coefficients in some cases as high as 4.5 × 10⁴ 1 mol^?1 cm^?1.     

Spray forming technology for military applications

Over the past five years, the Annapolis Detachment, Carderock Division, Naval Surface Warfare Center (formerly David Taylor Research Center) has established a state- of- the- art spray forming facility for the study and exploitation of this near net shape manufacturing process. Spray forming is a single step gas atomization/deposition process which yields ferrous and nonferrous, near final shape, near fully dense preforms that has proven to be a viable and cost effective alternative to conventional metalworking technology for the production of material preforms with properties surpassing those of their cast and wrought counterparts. Current programs at Carderock Divison Naval Surface Warfare Center are aimed at optimization of the process, certification of the spray formed products and industrialization of the technology.     

改进的FD—TD法分析二维理想导体TM近区散射问题

本文针对一般ＦＤ－ＴＤ方法分析计算二维理想导体散射问题所遇到散射体边角处难以精确处理的缺点进行了改进。将边角处总场近似解析解直接引入ＦＤ－ＴＤ法差分公式，得到了有关修正系数，为了检验此方法的有效性，有无限长导体方柱为例分别用一般ＦＤ－ＴＤ法和本文的ＦＤ－ＴＤ方法进行了分析研究，并与ＭＯＭ法进行了比较，所得结果说明改进后的ＦＤ－ＴＤ方法对分析计算导体边角附近电流分布特性是较有效的。     

一种VDSL上行链路自适应功率回馈方案

上行链路功率回馈技术(UPBO：upstream power back-off)是VDSL(very high-speed digital subscriber lines)系统中的关键技术，它用于抵消同一电缆中短线对长线引起的严重的远端串扰(FEXT:far-end crosstalk)。文中从功率控制的角度分析了基于迭代注水的自适应UPBO方案，并进行了性能仿真分析。     

Near‐Infrared Light‐Emitting Diodes (LEDs) Based on Poly(phenylene)/Yb‐tris(β‐Diketonate) Complexes

Near‐infrared‐emitting electroluminescent (EL) devices using blue‐light‐emitting polymers blended with the Yb complexes Yb(DBM)₃phen (DBM = dibenzoylmethane), Yb(DNM)₃phen (DNM = dinaphthoylmethane), and Yb(TPP)L(OEt) (L(OEt) = [(C₅H₅)Co{P(O)Et₂}₃]^–) have been studied. EL devices composed of Yb(DNM)₃phen blended with PPP‐OR11 showed enhanced near‐IR output at 977 nm when compared to those fabricated with Yb(DBM)₃phen/PPP‐OR11 blends. The maximum near‐IR external efficiencies of the devices with Yb(DBM)₃phen and Yb(DNM)₃phen are, respectively, 7 × 10^–5 (at 6 V and at 0.81 mA mm^–2) and 4 × 10^–4 (at 7 V, and 0.74 mA mm^–2). The optimal blend composition for EL device performance consisted of PPP‐OR11 blended with 10–20 mol‐% Yb(DNM)₃phen. A device fabricated using Yb‐(TPP)L(OEt)/PPP‐OR11 showed significantly enhanced near‐IR output efficiency, and future efforts will focus on devices fabricated using porphyrin‐based materials.     

Simultaneous HPLC quantification of total cholesterol,tocopherols and β-carotene in Barrosã-PDO veal

A simple, rapid and sensitive procedure for the simultaneous determination of total cholesterol, tocopherols and β-carotene in meat is described. The method involves a direct saponification of the meat, a single n-hexane extraction and the analysis of the extracted compounds by normal-phase HPLC, using fluorescence (tocopherols) and UV–Vis photodiode array (cholesterol and β-carotene) detections in tandem. Rates of recovery of spiked meat samples were 93% for cholesterol, 83–86% for (α-, β- and -γ) tocopherols and 89% for β-carotene. Repeatabilities were high (CV < 6%) for all determined compounds, except for δ-tocopherol. This tocopherol, which is not usually present in meat, showed a much lower recovery percentage (73%) and repeatability (12.8%). This methodology was applied for the quantification of total cholesterol, tocopherols and β-carotene in three muscles (longissimus thoracis, longissimus lumborum and semitendinosus) of the Portuguese traditional Barrosã-PDO veal, obtained from autochthonous calves fed extensively during summer (with the least abundant green pastures) and slaughtered in early autumn (October). Barrosã-PDO veal showed median contents of total cholesterol (0.50–0.56 mg/g) and, depending on the analysed muscle, moderate to high contents of α-tocopherol (3.3–3.9 μg/g) and β-carotene (0.07–0.09 μg/g), suggesting an high sensorial and hygienic quality.     

紫外法测菜籽饼粕中硫代葡萄糖甙操作探讨

对用紫外法测菜籽饼粕中硫代葡萄糖甙过程中测试条件、操作质量等操作问题予以分析和探讨，以求提高测试结果的准确率。