Deactivation of V2O5-WO3-TiO2 SCR catalyst at a biomass-fired combined heat and power plant

The deactivation of a commercial type V₂O₅-WO₃-TiO₂ monolith catalyst under biomass combustion was studied at a full-scale grate-fired power plant burning straw/wood using a slip stream pilot scale reactor. The aerosols in the flue gas consisted of a mixture of potassium chloride and sulphate. Three catalyst elements were exposed at 350 °C, and one element was exposed at 250 °C for comparison. The catalyst activity was measured in the reactor at the exposure temperature by addition of NH₃ and extra NO. The activity, in terms of a first-order rate constant, dropped by 52% after about 1140 h indicating a very fast deactivation compared to coal firing. It was also found that the reactor temperature was not of importance for the deactivation rate. SEM-EDX analysis showed that particle deposition and pore blocking contributed to the deactivation by decreasing the diffusion rate of NO and NH₃ into the catalyst. However, potassium also penetrated into the catalyst wall and the resulting average K/V ratio in the catalyst structure was high enough (about 0.3–0.5) for a significant chemical deactivation. Chemisorption studies carried out in situ showed that the amount of chemisorbed NH₃ on the catalyst decreased as a function of exposure time, which reveals that Brøndsted acid sites had reacted with potassium compounds and thereby rendered inactive. When washed by 0.5 M H₂SO₄ the regenerated catalyst regains a higher activity than that of the fresh catalyst at temperatures higher than 300 °C, but even though reactivation is possible, the deactivation rate appears too high for practical use of the SCR process in straw combustion.     

裂隙岩体边坡稳定性的渗流与应力耦合分析

用裂隙岩体渗流与应力耦合分析的四自由度全耦合法对岩质边坡进行耦合分析,通过强度折减有限元法求解岩体边坡的稳定安全系数。四自由度全耦合法建立了同时以渗流水压和位移为未知量的耦合方程组,使得渗流场与应力场的求解能够一次性完成,与两场交叉迭代分析方法相比达到了彻底的完全耦合。通过强度折减,整个系统达到不稳定状态,有限元计算将不收敛,此时的折减系数就是安全系数。算例表明由此求得的边坡稳定安全系数和滑动面都与传统方法十分接近。     

红外背景干扰研究

根据从许多地区收集来的录象磁带上的图象数据和大量红外图象数据，对红外背景图象内的干扰进行了研究。图象内的噪声是以象元电平为单位的均方根形成计算。图象经过空间滤波处理，对其内的干扰再进行计算。为获得关于红外背景图象的空间频率构成的信息，在滤波和非滤波两种状态下计算了图象的光谱密度，把计算出的干扰值输入数据库取出多组数据并绘图，确定参数量（如天气、背景类型和测量条件等）对干扰电平的影响。     

光缆CATV用DFB激光器发射组件

介绍了国内首次研制的光缆ＣＡＴＶ用１．３μｍＤＦＢ激光器组件。组件工作频带达到１ＧＨｚ，带内起伏〈１ｄＢ，组件的ＲＩＮ〈－１５３ｄＢ／Ｈｚ；出纤光功率〉２ｍＷ，载噪比ＣＮＲ〉５０ｄＢ。首次实现用低反射尖锥端光纤的ＤＦＢ激光器耦合。     

噪声测量作为筛选光电耦合器件的一种方法

本文针对目前用于光电耦合器件筛选方法的不足，提出了用测量耦合器件噪声功率谱的方法来筛选掉噪声值大的器件，给出一批光电耦合器件的测量统计结果及在不同工作点时的噪声功率谱，并给出相应的筛选标准，实验结果表明，这种方法是有效、可行的。     

乘性和加性噪声中谐波恢复的循环统计量方法

本文从循环平衡的观点出发来研究乘性和加性噪声中的谐波恢复问题.首先，在一定条件下建立了一般复过程的有限长付里叶变换的大样本性质．然后，得到了任意阶循环矩的样本估计关于循环频率的一致收敛速度．对于乘性和加性噪声中的谐波信号，建立了一、二、三阶循环矩样本估计的统计性质．在此基础上，分别提出了基于不同阶循环矩的谐波分最个数和频率的估计方法，并得到了估计的强相容性质和强收敛速度，最后给出了模拟实验结果．     

Inhibiting and deactivating effects of water on the selective catalytic reduction of nitric oxide with ammonia over MnOx/Al2O3

The effect of water on the selective catalytic reduction (SCR) of nitric oxide with ammonia over alumina supported with 2–15 wt.-% manganese oxide was investigated in the temperature range 385–600 K, with the emphasis on the low side of this temperature window. Studies on the effect of 1–5 vol.-% water vapour on the SCR reaction rate and selectivity were combined with TPD experiments to reveal the influence of water on the adsorption of the single SCR reactants. It turned out that the activity decrease due to water addition can be divided into a reversible inhibition and an irreversible deactivation. Inhibition is caused by molecular adsorption of water. TPD studies showed that water can adsorb competitively with both ammonia and nitric oxide. Additional kinetic experiments revealed that adsorbed ammonia is present in excess on the catalyst surface, even in the presence of water. Reduced nitric oxide adsorption is responsible for the observed reversible decrease in the reaction rate; the fractional reaction order changes from 0.79 in the absence of water to 1.07 in its presence. Deactivation is probably due to the dissociative adsorption of water, resulting in the formation of additional surface hydroxyls. As the amount of surface hydroxyls formed is limited to a saturation level, the deactivating effect on the catalyst is limited too. The additional hydroxyls condense and desorb in the temperature range 525–775 K, resulting in a lower degree of deactivation at higher temperature. A high temperature treatment at 775 K results in a complete regeneration. The amount of surface hydroxyls formed per unit surface area decreases at increasing MnO_x-loading. The selectivity to the production of nitrogen is enhanced significantly by the presence of gas phase water.     

Polyspectral Analysis of Two-dimensional Mixed Processes and Coupled Harmonics

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柴油机低频排气噪声规律分析

针对柴油机（4－85）低频排气噪声，对其产生机理、规律及其影响因素等作了理论计算、分析及实验。对低频排气噪声信号进行频域分析后可知，其主要由一系列离散的谐波组成，是以柴油机点火频率为基频的一种类周期性噪声，有可能应用有源噪声控制技术。     

具有减少辨识参数的随机多变量极点配置自适应控制器

本文提出了一种新的限制输出个数减少随机多变量自适应控制中辨识参数的方法，并给出了减少辨识参数的极点配置自适应算法。虽然采用ｎ个输入１个输出的减少辨识参数的模型来设计控制器，但所提出的控制器能够保证被控系统的几个输出跟踪参考输入信号，仿真结果表明，所提出的方法是成功的。