Accelerator Analysis of Tributyltin Adsorbed onto the Surface of a Tributyltin Resistant Marine Pseudoalteromonas sp. Cell

Tributyltin (TBT) released into seawater from ship hulls is a stable marine pollutant and obviously remains in marine environments. We isolated a TBT resistant marine Pseudoalteromonas sp. TBT1 from sediment of a ship’s ballast water. The isolate (10^{9.3 ± 0.2} colony-forming units mL⁻¹) adsorbed TBT in proportion to the concentrations of TBTCl externally added up to 3 mM, where the number of TBT adsorbed by a single cell was estimated to be 10^8.2. The value was reduced to about one-fifth when the lysozyme-treated cells were used. The surface of ethanol treated cells became rough, but the capacity of TBT adsorption was the same as that for native cells. These results indicate that the function of the cell surface, rather than that structure, plays an important role to the adsorption of TBT. The adsorption state of TBT seems to be multi-layer when the number of more than 10^6.8 TBT molecules is adsorbed by a single cell.     

Response surface methodology applied for Orange II photocatalytic degradation in TiO2 aqueous suspensions

BACKGROUND: Heterogeneous photocatalysis is influenced by a number of parameters involving synergistic effects; hence, an experimental strategy design that considers interactions between the main variables is needed. The response surface methodology was applied for the investigation of photodegradation of 20 mg L^?1 Orange II in aqueous solutions and for optimization of color removal efficiency. Preliminary studies were performed to identify the parameters to be selected for optimization. RESULTS: The input variables considered for experimental design were: solution initial pH, oxidizing agent (H₂O₂) initial concentration and UV‐A irradiation time. The multivariate experimental design allowed the development of a quadratic response surface model to be used for the prediction of color removal efficiency over the full range of the experimental region. Under the optimum conditions established in the region of experimentation (pH = 6.9, [H₂O₂]₀ = 183 mg L^?1 and t = 32 min), a 100% color removal efficiency was obtained in experiments. CONCLUSIONS: It was found that the variables considered have important effects on color removal efficiency. The results demonstrate that the use of experimental design strategy is indispensable for successful investigation and adequate modeling of the process because the interdependence of the reaction parameters cannot be neglected. Copyright © 2008 Society of Chemical Industry     

颗粒表面改性法制备PTC粉体的研究

本文介绍了一种通过液相颗粒表面改性技术添加二次掺杂物来制备ＰＴＣ粉体的新方法。即将烧结助熔剂Ａｌ２Ｏ３，ＳｉＯ２以及受主杂质ＭｎＯ采用溶液形式，包裹在ＢａＴｉＯ３基粉体颗粒表面进行改性，由此可以得到二次掺杂物Ａｌ２Ｏ３、ＳｉＯ２和ＭｎＯ分布均匀的ＰＴＣ粉体。     

碳化硅加热元件的电性能和使用

本文介绍碳化硅加热元件的电特性、表面负荷以及工作气氛对它的影响，并对它设计和使用要点举例予以说明。     

多层住宅砖混房屋设计中两点问题的探讨

浅议多层住宅砖混房屋中构造柱的作用及设置方法；探讨了砖混结构墙下条形基础底面积重复利用问题及其解决方法。     

Nondestructive evaluation of pavements using spectral analysis of surface waves in the frequency wave-number domain

The potential of using Spectral analysis of surface waves (SASW) for nondestructive testing of pavement and soil sites has been demonstrated in several publications. The usual SASW field testing and data analysis procedures and the assumption of a single propagation mode yield accurate results when there are no sharp changes in the stiffness of the site with depth. When this is not the case, however, difficulties arise in the interpretation of experimental data due to the participation of more than one mode in the wave field. In an earlier study, the multiple filter/crosscorrelation technique was suggested for analyzing multi-mode SASW signals. This technique, however, may not yield accurate results when propagation modes are closely spaced. A more general method using spectral analysis in the frequency wave-number domain is presented in this paper. Formulas are presented for determining a reasonably small number of surface measurements, and the accuracy of this method in resolving experimental dispersion curves is demonstrated for a pavement site.     

溶胶－凝胶二氧化硅驻极体薄膜的物理化学改性

实验研究了由溶胶－凝胶法制备二氧化硅驻极体薄膜的工艺。用红外透射谱、扫描电子显微镜以及驻极体等温表面电位测量和热刺激放电等实验考察了热处理和化学表面修正两个关键工艺对溶胶－凝胶二氧化硅样品驻极体性能的影响。结果表明经过高温条件下一定时间的热处理和化学表面修正，可以制备出性能优良的驻极体薄膜     

钻井泵阀箱密封面CO2堆焊试验研究及应用

介绍了用CO_2堆焊35CrMo钢钻井泵阀箱密封面磨损修复工作,通过试验表明,采用Φ1.2mm的H08Mn2Si焊丝,以短路过渡CO_2焊法施焊,可以获得致密、耐磨的堆焊金属层。该法已成功地用于生产,取得了良好的经济效益。     

固载杂多酸催化剂气相催化合成乙酸丁酯的研究

在气固相反应体系中研究了酸处理膨润士固载的具有 Keggin结构的四种杂多酸在乙酸丁酯合成中的催化性能。实验结果表明 :同一载体负载不同杂多酸催化活性相似 ;不同载体负载的同一种杂多酸的催化活性与催化剂的表面酸性呈顺变关系。同时考察了反应温度 ,空速 ,酸 /醇比对催化活性的影响。在酸 /醇比为 1 ,温度为 1 2 0℃ ,空速为 3～ 5h- 1时 ,正丁醇和乙酸有较高的转化率 ,选择性接近 1 0 0 %。