改性淀粉与丙烯酸接枝共聚物的合成及应用性能

研究经过热处理的改性淀粉与丙烯酸的接枝共聚反应。接枝共聚产物在 790cm-1、85 0cm-1(物理改性淀粉的特征吸收峰 )和 172 0cm-1(聚丙烯酸的特征吸收峰 )处的红外光谱验证了接枝共聚反应的发生。探讨了引发剂过硫酸铵浓度、丙烯酸浓度、反应温度和反应时间等因素对接枝率和接枝效率的影响。当 ρ(淀粉 ) =70 g/L、t =6 0℃、反应时间为 3h、c〔(NH4) 2 S2 O8〕 =3 0× 10 -3 mol/L、c(丙烯酸 ) =0 4 2mol/L时 ,合成胶粘剂的初粘力为 10 0 % ,吸水率为 15 0 14 % ,吸油率为 2 0 6 % ,其压制的纸板冲击强度为 3 2 5kN/m ,拉伸强度为 3 75MPa ,与纯淀粉粘接剂相比较 ,所压制纸板的应用性能得到较大的改善。     

Ethanol production from raw starch by a recombinant yeast having saccharification and fermentation activities

In order to develop a method for converting raw starch into ethanol efficiently, direct fermentation of ozonized raw starch using a recombinant yeast was investigated. Ozonolysis was carried out as a pretreatment to convert raw starch into ethanol rapidly and efficiently, and then the effect of the ozone degradation conditions on the degree of polymerization and the amount of amylose in a raw starch was determined. Since the degree of polymerization was low and the amount of amylose was high, raw starch treated with an ozone concentration of 40 gm^?3 and an ozonation time of 30 min was the material chosen for alcohol fermentation. Though the recombinant yeast could not convert the untreated raw starch, it converted the soluble starch and the ozonized raw starch at a comparatively high yield into ethanol. About 56% of the ozonized raw starch decomposed, and the ethanol concentration obtained from the ozonized raw starch was markedly greater than that obtained from untreated raw starch. The dynamic behavior of cell growth, substrate degradation, and ethanol production was examined in a continuous culture under various dilution rates, and the optimal dilution rate, ie 0.15 h^?1, was determined for maximizing the ethanol productivity (amount of ethanol produced per unit time). © 2002 Society of Chemical Industry     

氧化玉米淀粉粘合剂稳定性的探究

探讨了氧化玉米淀粉粘合剂的稳定性的主要影响因素,初步分析其变质机理,以此为依据制备得到高稳定性的产品。     

快干型芭蕉芋淀粉粘合剂的制备

介绍一种快干型芭蕉芋淀粉粘合剂，它特别适合于粘结瓦楞纸板，其制法是芭蕉芋等直链淀粉含量较代低的天然植物淀粉为原料，经氧化、糊化、交联等步骤而制得；产品结力强，产品性能稳定，贮存期长。     

聚乙烯醇改性固体淀粉胶粘剂的研制

介绍新型固体淀粉胶的制备方法。以淀粉为主要原料，经加热催化分步氧化，再加入聚乙烯醇合成树脂改善其性能，然后用硬脂酸钠作为赋型剂。制得的淀粉胶剪切强度比泡花碱高0.01MPa。     

三氯氧磷交联木薯淀粉的消化性能及酶降解程度

采用In Vitro消化模型模拟人体消化道环境 ,对不同交联度 (DC)的三氯氧磷淀粉 (DC =3.70× 10 -5至 2 .2 7×10 -2 )的消化性能进行了研究 ;同时用微生素酶对三氯氧磷交联木薯淀粉进行生物降解并测定各个样品的抗酶解淀粉 (RS)含量。三氯氧磷交联变性处理对木薯淀粉的消化速度和生物降解程度的影响随交联度的不同而不同。高交联特别是使淀粉达到完全非晶化时对淀粉的消化速度和生物降解程度影响更大。     

多孔淀粉在内墙涂料中的应用

本用多孔淀粉和淀粉吸附天然除虫菊酯后加入内墙涂料，通过对两解吸附量、释放时间的比较，说明在内墙涂料中加入杀虫剂的可行性，同时也表明多孔淀粉作为一种新型的吸附和缓释剂，有着广泛的用途。     

Formation of hydrophilic starch coatings on polyethylene films

Thin starch coatings were deposited onto polyethylene (PE) film surfaces when PE films were immersed in 1% jet cooked starch solutions and the hot solutions were allowed to cool. Normal cornstarch, waxy cornstarch, high amylose cornstarch, and solvent‐extracted normal cornstarch (to remove native lipid) were used in these experiments. Amounts of adsorbed starch varied from about 0.03–0.05 mg per cm² of PE, and these starch coatings imparted hydrophilic properties to film surfaces, as evidenced by contact angle measurements. Although starch could be removed by gently rubbing water‐wet PE surfaces, air‐dried coatings were more firmly attached, and did not separate from the PE surface when films were bent or flexed. SEM images of starch‐coated film surfaces showed that starch was deposited as particles less than 1 μm in diameter, and also as aggregates of these submicron particles. Despite the fact that some starch samples contained only very small amounts of amylose and native lipid, surface‐deposited starch in all experiments contained 90–100% amylose; and exhibited the same V_h X‐ray diffraction pattern, indicative of helical inclusion complex formation. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1781–1788, 2002; DOI 10.1002/app.10589     

玉米淀粉胶粘剂的改性研究

以玉米淀粉为主要原料 ,通过预糊化、氧化、加碱糊化进行化学改性 ,并加入稳定剂可制备固含量高、贮存稳定性好 ,具有一定初粘力和透明性的改性淀粉胶粘剂。本论文主要研究了改性玉米淀粉胶粘剂的主要成分配比及工艺条件对产品性能的影响。结果表明 :淀粉氧化前是否进行预糊化处理、氧化剂的用量、体系pH值、加碱糊化时碱液用量、稳定剂的种类和用量等对改性玉米淀粉胶粘剂性能影响较大。     

变性淀粉取代聚乙烯醇生产Al2O3刚玉陶瓷的胶粘剂研究

论述了变性淀粉取代聚乙烯醇(PVA)生产Al2O3刚玉陶瓷的意义及聚乙烯醇结构与吸附性能的关系，并且根据胶粘机理，通过分析Al203胶粒的表面特性和变性淀粉的结构，说明了变性淀粉可以取代聚乙烯醇。