Use of15N for fertilizer N recovery and N mineralization studies in semi-arid Kenya

Maize and beans were grown on a ferralsol at Kiboko, Kenya, with up to 120 kg N ha^–1. Within the 10 kg N ha^–1 plots,¹⁵N labelled fertilizer was applied in microplots. There was no significant response in yield to fertilizer N and labelled N recovery was low, being 7.5% or less in one season and 17.7% or less in the second season. Samples of Kiboko soil at four different water contents were incubated and the rate of gross N mineralization over 7 days was calculated, utilizing¹⁵N labelling of the mineral N. Gross N mineralization increased greatly with soil moisture and a fitted relationship between gross N mineralization rate and soil water content was obtained. Using measurements of soil water content at the field site, daily values of the soil N supply by gross mineralization were calculated. On average, modelled gross soil N mineralized could supply much (> 69%) of the N removed from the plots. It is suggested that the lack of response to fertilizer N may be explained by the coincidence of a high rate of N mineralization, and increased crop demand, caused by the onset of rain.     

钽平台-石墨炉原子吸收法测定高背景废水样品中的Cd、Pb

运用钽平台石墨管测定基体成分复杂的废水样品中的Cd、Pb元素,基本消除了基体残留影响和记忆效应,降低了背景吸收,提高了灵敏度。样品经超声波仪粉碎后直接进样,用校正曲线法测定,简化了操作步骤,减少了测定时间,延长了石墨管使用寿命。其测定值与石墨平台标准加入法测定值结果一致。样品回收率:Cd为96.9%～104%,Pb为98.2%～106%,Cd的相对标准偏差(RSD)为3.04%～4.24%,Pb的RSD为2.93%～6.53%。     

Synthesis of Super-Microporous Aluminosilicate Having Excellent Water Vapor Adsorption Property as an Adsorbent for an Adsorption Heat-Pump

The synthesis of super-microporous aluminosilicate with a pore diameter of 14.6 Å has been achieved, by means of synthesis under specified conditions with a skeletal material comprising TMOS and a small quantity of sodium aluminate, and a conventional alkyl-trimethylammonium halide (C₁₀TMABr) as a template. This super-microporous aluminosilicate has an adsorption capacity of 0.2 ml/g at a relative water vapor pressure of 0.2, and thus is promising as an adsorbent for an adsorption heat-pump.     

PE 井口高压滤芯的研究与开发

本文介绍了一种新型的能在较高压力环境下进行细过滤的ＰＥ井口高压滤芯的结构特征、关键技术研究、技术特性，以及应用效果。     

Effect of operating conditions in removal of arsenic from water by nanofiltration membrane

The removal of arsenic from synthetic waters and surface water by nanofiltration (NF) membrane was investigated. In synthetic solutions, arsenic rejection experiments included variation of arsenic retentate concentration, transmembrane pressure, crossflow velocity and temperature. Arsenic rejection increased with arsenic retentate concentration. Arsenic was removed 93-99% from synthetic feed waters containing between 100 and 382 μg/L as V, resulting in permeate arsenic concentrations of about 5 μg/L. Under studied conditions, arsenic rejection was independent of transmembrane pressure, crossflow velocity and temperature. In surface water, the mean rejection of As V was 95% while the rejection of sulfate was 97%. The co-occurrence of dissolved inorganics does not significantly influence arsenic rejection. The mean concentration of As in collected permeated was 8 μg/L. The mean rejection of TDS, total hardness and conductivity were 75, 88 and 75% respectively.     

自含砷合碳难处理金矿中提取金的研究─Ⅰ.氨水脱砷-石灰加压氧化-氰化

针对甘肃省坪定金矿含金、砷高、金部分地赋存于脉石、脉石为碱性、属于难选难冶矿的特点，提出了氨水脱砷－石灰加压氧化－氰化新工艺．当原矿含金8．7g／t及13．0％砷时，砷可脱除95％，金可浸出85％．技术及经济指标预计均较满意．     

金昌冶炼厂污酸污水处理装置简介

介绍了污酸污水处理装置的工艺流程、工艺特点和主要设备。来自净化工序的污酸脱出二氧化硫后进行两级石灰石乳中和生成石膏浆；石膏浆经浓密机沉降，底液经hrox压滤机脱水，浓密机上清液和压滤机滤液汇入石膏滤液槽与硫化钠反应生成硫化物沉淀；硫化物沉淀经浓密机沉降，底流经陶瓷过滤机过滤，滤液和浓密机上清液自流到污水处理工序进一步处理。来自污酸处理工序和各车间的污水混合后进行一级石灰乳中和、硫酸亚铁除砷、二级石灰乳中和，实现达标排放。运行3年来，污酸污水处理装置各项指标均达到设计要求。     

Optical and surface properties of whey protein isolate coatings on plastic films as influenced by substrate,protein concentration,and plasticizer type

Composite film structures of common plastic polymers including polypropylene (PP) or poly(vinyl chloride) (PVC) with whey protein isolate (WPI) coatings may be obtained by a casting method. Optical and surface properties of the resulting WPI‐coated plastic films, as affected by protein concentration and plasticizer type, were investigated to examine the biopolymer coating effects on surface modification with polymeric substrates of opposite polarity. The measured properties involved specular gloss, color, contact angle, and critical surface energy. Regardless of the substrates, WPI‐coated films possessed excellent gloss and no color, as well as good adhesion between the coating and the substrate when an appropriate plasticizer was added to the coating formulations. The protein concentration did not significantly affect gloss of WPI‐coated plastic films. Among five plasticizers applied, sucrose conferred the most highly reflective and homogeneous surfaces to the coated films. The WPI coatings were very transparent and the coated films with various protein concentrations and plasticizers showed no noticeable changes in color. Experimental results suggest that WPI coatings formulated with a proper plasticizer can improve the visual characteristics of the polymeric substrate and enhance water wettability of the coated plastic films. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 335–343, 2004     

稠油O/W型乳状液稳定性的研究

以大庆黑帝庙稠油为研究对象，依据稠油乳化降粘原理及O／W型乳状液的形成机制，考察了表面活性剂类型及添加量，碱的添加量，温度、油／水比、振荡方式等因素对稠油O／W型乳状液稳定性的影响。为筛选降粘剂复合配方及选择降低粘工艺提供了必要的基础数据。     

掺煤矸石的水泥性能与颗粒群分布的关系研究

将不同细度的煤矸石、纯硅酸盐水泥分别按30％和70％的比例混合，测其胶砂流动度、净浆标准稠度用水量和3d、28d胶砂抗压强度。以宏观性能指标为z轴，水泥与煤矸石的中位径D50之差为x轴，水泥与煤矸石混合样的中位径D50为y轴，进行三维区域图分析。给出各项性能指标发展趋势与水泥、煤矸石的相对位置以及混合体系总体细度的相互关系。