松香及其衍生物在浮选分离中的应用

介绍了松香的来源、化学组成及理化性质；讨论了松香及其衍生物在非硫化物矿浮选分离、有色金属离子的浮选分离以及从水溶液中浮选分离有机物等方面的应用情况。     

Preparation of core–shell type nanoparticles of diblock copolymers of poly(L‐lactide)/poly(ethylene glycol) and their characterization in vitro

Core–shell type nanoparticles of poly(L ‐lactide)/poly(ethylene glycol) (LE) diblock copolymer were prepared by a dialysis technique. Their size was confirmed as 40–70 nm using photon correlation spectroscopy. The ¹H‐NMR analysis confirmed the formation of core–shell type nanoparticles and drug loading. The particle size, drug loading, and drug release rate of the LE nanoparticles were slightly changed by the initial solvents that were used. The drug release behavior of LE core–shell type nanoparticles showed an initial burst during the first 12 h and then a sustained release until 100 h. The degradation behavior of LE block copolymer nanoparticles was divided into three phases: the initial rapid degradation phase, the stationary phase, and the rapid degradation phase until complete degradation. It was suggested that lidocaine release kinetics were predominantly governed by the diffusion mechanism in the initial burst phase and after that by both of the diffusion and degradation mechanisms. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2625–2634, 2002     

有机EL的稳定性和寿命

介绍了有机ＥＬ在稳定性及寿命方面的最新研究动态，着重描述了器件功能层组合的相互接触、阴极、空穴传输层玻璃化温度和驱动条件等对有机ＥＬ稳定性和寿命的影响。     

A new approach to the mechanism of chlorine evolution: Separate examination of the kinetic steps using ac impedance on a rotating thin ring electrode

In the absence of a bulk diffusion effect, it is shown for the first time that the impedance spectra for the chlorine evolution reaction on a rotating thin ring electrode comprise three consecutive semicircles in the capacitive half of the complex plane. The first (highest frequency) semicircle is due to the charge-transfer resistance for chloride discharge and the simultaneous chlorine adsorption coupled to the double-layer capacitance. The second semicircle (around 5 Hz) is due to the adsorption and desorption of a chlorine intermediate. The third (lowest frequency, around 0.5 Hz) semicircle is due to the relaxation of surface oxygen species. The impedance data allow the steps of the overall reaction to be examined individually. On a Pt surface the rate of chloride discharge and simultaneous chlorine adsorption (the admittance of the first semicircle) is first order with respect to chloride concentration and has a potential-dependence close to 58 mV/decade. The rate of the adsorption and desorption process (the admittance of the second semicircle) is second order with respect to chloride concentration, and has a potential dependence close to 30 mV/decade. The time constant for the adsorption/desorption processes is ca 20 ms, independent of electrode potential in the range studied. These features are consistent with a mechanism in which a faster discharge reaction (Cl⁻ Cl_ad + e) is followed by a slower surface combination reaction (2Cl_ad → Cl₂), but inconsistent with mechanisms in which ion + atom desorption is predominant, the initial chloride discharge is slow, or a unipositively charged chlorine species is involved.     

大坝水平位移监控指标拟定的混合法

用混合法拟定了大坝水平位移的监控指标，即通过结构分析和建立数值 模型，计算大坝水平位移的水压分量和给定概率水平下的温度分量极值，进而拟定水平位移 监控指标，并给出了实例。     

小型密闭压力容器测试系统重复性的研究

小型密闭压力容器测试（MCPVT）法是安全工程领域中近几年发展起来的、评价有机过氧化物及自反应物质受热分解反应激烈程度的新方法。pmax是MCPVT方法中用来表征自反应物质受热分解反应激烈程度的物理量之一。文中通过大量实验，研究了样品容器容积V、升温速率R及样品质量M对pmax重复性误差的影响，研究了一系列典型的有机过氧化物和自反应物质在标准实验条件下pmax重复性误差。结果表明，小型密闭压力容器测试系统重复性好，测试结果可靠，从而为MCPVT法最终成为国际上评价自反应物质受热分解反应激烈程度标准方法奠定了基础。     

用于铜的化学机械抛光液的研究

文中介绍了一种以碱性抛光液对铜进行全局平面化的方法 ,讨论了以 Si O2 水溶胶为磨料的抛光液在Cu-CMP过程中的化学 (络合 )作用及反应机理 ,并给出了抛光液的配比及上机实验结果。结果表明 :该抛光液用于对带有阻挡层和介质层的铜抛光 ,达到了对铜层的高去除速率和高选择比 ,取得了较好的全局平面化效果     

罗茨真空泵的溢流阀与旁通阀的组合

在简要地介绍了罗茨泵功能的基础上，通过溢流阀的改进设计，使溢流阀成为既能旁通又能溢流的组合阀，罗茨泵的功能将更加完备。     

Hysys软件在分析精丙烯硫化物来源中的应用

气体分馏装置原料液化石油气 (LPG)中有机硫化物形态复杂 ,考察分析工业装置精丙烯硫化物含量变化难度大。利用Hysys模拟 ,分析判断LPG中小分子有机硫化物在气体分馏产品的分布并提出了控制措施。考虑操作条件对精丙烯硫含量的影响 ,并对工业装置精丙烯总硫超标原因进行了分析。