A new approach to the mechanism of chlorine evolution: Separate examination of the kinetic steps using ac impedance on a rotating thin ring electrode

In the absence of a bulk diffusion effect, it is shown for the first time that the impedance spectra for the chlorine evolution reaction on a rotating thin ring electrode comprise three consecutive semicircles in the capacitive half of the complex plane. The first (highest frequency) semicircle is due to the charge-transfer resistance for chloride discharge and the simultaneous chlorine adsorption coupled to the double-layer capacitance. The second semicircle (around 5 Hz) is due to the adsorption and desorption of a chlorine intermediate. The third (lowest frequency, around 0.5 Hz) semicircle is due to the relaxation of surface oxygen species. The impedance data allow the steps of the overall reaction to be examined individually. On a Pt surface the rate of chloride discharge and simultaneous chlorine adsorption (the admittance of the first semicircle) is first order with respect to chloride concentration and has a potential-dependence close to 58 mV/decade. The rate of the adsorption and desorption process (the admittance of the second semicircle) is second order with respect to chloride concentration, and has a potential dependence close to 30 mV/decade. The time constant for the adsorption/desorption processes is ca 20 ms, independent of electrode potential in the range studied. These features are consistent with a mechanism in which a faster discharge reaction (Cl⁻ Cl_ad + e) is followed by a slower surface combination reaction (2Cl_ad → Cl₂), but inconsistent with mechanisms in which ion + atom desorption is predominant, the initial chloride discharge is slow, or a unipositively charged chlorine species is involved.     

大坝水平位移监控指标拟定的混合法

用混合法拟定了大坝水平位移的监控指标，即通过结构分析和建立数值 模型，计算大坝水平位移的水压分量和给定概率水平下的温度分量极值，进而拟定水平位移 监控指标，并给出了实例。     

罗茨真空泵的溢流阀与旁通阀的组合

在简要地介绍了罗茨泵功能的基础上，通过溢流阀的改进设计，使溢流阀成为既能旁通又能溢流的组合阀，罗茨泵的功能将更加完备。     

A Novel UWB Pulse Shape Modulation System

In this paper novel modified Hermite polynomial functions for use in impulse radio (ultra-wideband) communications are proposed. With these functions pulse shapes which are orthogonal and have nearly constant pulse width regardless of the pulse order are generated. These properties hold under the effects of differentiation. An M-ary communication system is constructed using these pulse shapes. A Matlab model for generating the pulses is designed and the effect of timing jitter on the performance of the system is investigated by computer simulation.     

Spreading Codes Generator for Wireless CDMA Networks

The prime characteristic of spread spectrum modulated signals is that their bandwidth is greater than the information rate. In this way a redundancy is introduced that allows the severe levels of inteference inherent in the transmission of digital information over radio and satellite links to be overcome. Current spread spectrum applications are primarily in military communications; nevertheless, there is growing interest in this technique for third generation mobile radio networks (UMTS, FPLTS, etc.) with open discussion regarding the practicality of using a multiple access system based on spread spectrum techniques (CDMA). However, in order to support as many users in the same bandwidth as other multiple access techniques such as TDMA or FDMA, it is important how to generate large families of sequences that present low cross-correlation. The aim of this paper is to describe a spreading codes generator that can produce a large number of PN sequences with good properties of auto- and cross-correlation. Moreover, the codes generated shows high unpredictability and good statistical behaviour. This also allows the implementation of some features that are common on military networks such as message privacy (increasingly important in commercial networks) without additional cost. The structure presented shows itself to be advantageous for high speed generation of codes at a low cost, low power consumption (allowing longer life for batteries), small size and simplicity of implementation, essential ingredients for commercial equipment. Another attractive feature is its structural parallelism, useful in VLSI implementations. All of these features render it potentially suitable for the implementation of channel bandwidth sharing systems in future wireless personal communications networks.     

由1,4-萘醌催化合成1,4-二烷氧基萘-2,3-二甲腈

研究了以 1 ,4-萘醌为原料 ,通过溴代、氰化和 O-烷基化三步合成 1 ,4-二烷氧基萘 -2 ,3 -二甲腈。在溴代反应中以溴化试剂代替液溴 ;在氰化和 O-烷基化反应中以溴化十二烷基三甲基铵 (DTMAB)和聚乙二醇(PEG)作为相转移催化剂 ,并采用正交设计法考察了相转移催化剂、固体碱、反应温度等因素对反应的影响 ,其中氰化产物收率达 88.7%。     

激光相变硬化性能与工艺参数关系的数学模型

用回归正文分析的方法．建立了中碳结构钢、碳素工具钢和合金结构钢的激光相变硬化性能与工艺参数间关系的数学模型。分析了回归力程的显著性并预测了各硬化指标的精度。     

一种适用于高数据速率和高速移动环境的新型信道估计方法——双正交通道信道估计方法

本文给出了一种适用于高数据速率和高速移动环境下的新型有效的信道估计方法-双正交通道信道估计方法(CETOC,Channel Estimation by using Two Orthogonal Channels),这种信道估计方法通过采用两个独立通道的联合估计,可以有效的克服快衰落的影响,从而使得在快衰落信道下应用多维状态调制成为可能.     

Time-Space Label Switching Protocol (TSL-SP)—A New Paradigm of Network Resource Assignment

In this paper we propose a new protocol called time-space label switching protocol (TSL-SP) in optical burst switching (OBS), and define the terms time-space label (TSL) and time-space routing (TSR). An important concept of response time is introduced in the time label mechanism. The TSL-SP is a new technology that can quickly and efficiently forward data with a label on the optical networks. A two-dimension label switched path (TD-LSP) can be set up, that is maintained and deleted by the TSL-SP. For clearly illuminating the operation principles of the TSL-SP, we propose a new approach of orthogonal time-space coordinates in which the vertical coordinate is the space label and the horizontal coordinate is the time label. The proposed TD-LSP can dramatically reduce the routing failure probability and greatly improve the link network efficiency compared with other signaling protocols. Moreover, we define the time-space label control plane that can achieve the higher efficiency. When the TSL-SP is applied to networks, switching performance can be improved by two orders compared to the switching performance with the conventional OBS signaling protocols. The fundamental goal of TSL-SP is to band the signaling and routing functions together closely. Also, the TSL-SP can reduce the complexity of the network, support automatic service offering, and provide traffic engineering.