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81.
Zhixue Wu 《Structural and Multidisciplinary Optimization》2009,37(6):625-634
The goal of this work is to obtain optimal hole shape for minimum stress concentration in two-dimensional finite plates using
parameterized geometry models. The boundary shape for a hole is described by two families of smooth curves: one is a “generalized
circular” function with powers as two parameters; the other one is a “generalized elliptic” function
a and b are ellipse axes) with powers as two parameters and one of the ellipse axes as the third parameter. Special attention is
devoted to the practicability of parameterized equations and the corresponding optimal results under the condition with and
without the curvature radius constraint. A number of cases were examined to test the effectiveness of the parameterized equations.
The numerical examples show that extremely good results can be obtained under the conditions with and without curvature radius
constraint, as compared to the known solutions in the literature. The geometries of the optimized holes are presented in a
form of compact parametric functions, which are suitable for use and test by designers. It is anticipated that the implementation
of the suggested parameterized equations would lead to considerable improvements in optimizing hole shape with high quality. 相似文献
82.
Lingcai Zeng Haoyan Liang Bao Qiu Zhepu Shi Sijie Cheng Kaixiang Shi Quanbing Liu Zhaoping Liu 《Advanced functional materials》2023,33(25):2213260
Li-rich layered oxides (LLOs) have been considered as the most promising cathode materials for achieving high energy density Li-ion batteries. However, they suffer from continuous voltage decay during cycling, which seriously shortens the lifespan of the battery in practical applications. This review comprehensively elaborates and summarizes the state-of-the-art of the research in this field. It is started from the proposed mechanism of voltage decay that refers to the phase transition, microscopic defects, and oxygen redox or release. Furthermore, several strategies to mitigate the voltage decay of LLOs from different scales, such as surface modification, elemental doping, regulation of components, control of defect, and morphology design are summarized. Finally, a systematic outlook on the real root of voltage decay is provided, and more importantly, a potential solution to voltage recovery from electrochemistry. Based on this progress, some effective strategies with multiple scales will be feasible to create the conditions for their commercialization in the future. 相似文献
83.
Tuning Surface Structure and Strain in Pd–Pt Core–Shell Nanocrystals for Enhanced Electrocatalytic Oxygen Reduction 下载免费PDF全文
84.
The first measurement of a turnover rate with respect to surface intermediate concentration in a high pressure heterogeneous catalytic reaction is reported. By using infrared-visible sum frequency generation to study the hydrogenation of ethylene on Pt(111), it was found that the surface concentration of -bonded ethylene, the key reaction intermediate, represented approximately 4% of a monolayer. Thus the absolute turnover rate per surface adsorbed ethylene molecule is 25 times faster than the rate measured per platinum atom. To explain these results, we propose a model of weakly adsorbed ethylene intermediates reacting on atop sites. 相似文献
85.
针对蓄热式加热炉具有多变量、时变、非线性、耦合、大惯性和纯滞后等特点,当前时于蓄热式加热炉的空燃比控制主要还是人工操作完成的问题,通过对蓄热式加热炉空燃比变化这一复杂的工业过程的分析,提出了一种蓄热式加热炉空燃比控制方法,设计了一个基于智能的空燃比控制系统.用无辨识自适应方法预测热值,用模糊神经网络预测烟气残氧量,解决... 相似文献
86.
介绍了一种基于超声波技术的乳化液浓度在线检测技术,通过检测超声波的传播速度和乳化液的温度,并利用乳化液浓度、温度和超声波声速三者之间的曲线拟合关系,来实现乳化液浓度的在线连续监测,为实现乳化液的自动配比奠定了坚实的基础。 相似文献
87.
On-column solvent exchange, using many of the principles of solid-phase extraction, has been implemented to significantly reduce evaporation cycle time following reverse-phase preparative HPLC. Additional benefits, such as a reduced potential for salt formation, thermal decomposition, and residual solvent, are also described. Fractions obtained from preparative separations, typically in a large volume of acetonitrile:water, are injected into the preparative HPLC and then eluted in acetonitrile, creating a new fraction in a volatile organic solvent. Minimal modification to the instrument was required, and unattended operation is possible. Acetonitrile evaporation is achieved within 3 h, compared with 17 h for aqueous-based fractions; lower temperatures can be used during the evaporation step; mobile-phase additives, likely to form salts with the target compound if concentrated in the fraction, are removed before evaporation; sample recovery and purity are unaffected. 相似文献
88.
89.
Vishal BalouriaAuthor Vitae Arvind KumarAuthor VitaeA. SinghAuthor Vitae S. SamantaAuthor VitaeA.K. DebnathAuthor Vitae Aman MahajanAuthor VitaeR.K. BediAuthor Vitae D.K. AswalAuthor Vitae S.K. GuptaAuthor VitaeJ.V. YakhmiAuthor Vitae 《Sensors and actuators. B, Chemical》2011,157(2):466-472
The conductometric gas sensing characteristics of Cr2O3 thin films - prepared by electron-beam deposition of Cr films on quartz substrate followed by oxygen annealing - have been investigated for a host of gases (CH4, CO, NO2, Cl2, NH3 and H2S) as a function of operating temperature (between 30 and 300 °C) and gas concentration (1-30 ppm). We demonstrate that these films are highly selective to H2S at an operating temperature of 100 °C, while at 220 °C the films become selective to Cl2. This result has been explained on the basis of depletion of chemisorbed oxygen from the surface of films due to temperature and/or interaction with Cl2/H2S, which is supported experimentally by carrying out the work function measurements using Kelvin probe method. The temperature dependent selectivity of Cr2O3 thin films provides a flexibility to use same film for the sensing of Cl2 as well as H2S. 相似文献
90.