共析钢的过冷奥氏体动态相变和组织超细化

通过在Gleeble-1500热模拟试验机上进行单轴热压缩实验,研究了共析钢中过冷奥氏体在A1-Ar1之间变形时的组织演变,探讨了共析钢中复相组织球化超细化的机理.结果表明:随着应变量的增加,片层珠光体在原始奥氏体晶界形成的铁素体生长前沿形核长大,并向原始奥氏体晶内推进,直至相变完成.片层珠光体生成后继续变形,发生渗碳体的溶断和球化,及铁素体的动态回复再结晶等轴化等过程.渗碳体的球化有两种机制,其一是由于Gibbs-Thomson效应,珠光体中片层状渗碳体发生溶断和球化,生成的大颗粒渗碳体主要分布在铁素体晶界;其二是纳米级渗碳体粒子伴随铁素体动态再结晶在晶内重新析出.实验证实,在合适的变形工艺条件下可以得到亚微米级铁素体与亚微米、纳米级颗粒状渗碳体的双相组织.     

添加Mo-B对超高强度管线钢相变组织的影响

在超高强度管线钢中添加不同数量的Mo与B,研究了不同Mo/B(s)比(B(s)为酸溶硼)的管线钢的组织相变特性和显微硬度的变化.结果表明,Mo-B(s)共同作用有利于提高钢的淬透性,增加组织中的下贝氏体含量,提高该钢的显微硬度,其共同作用的效果优于两者单独作用之和.在Mo-B(s)共同作用下,钢中的Mo/B(s)比RMo/B(s)=200时,该钢得到最佳的组织和最高的显微硬度.对有关作用机理进行了讨论.     

A computational study of austenite formation kinetics in rapidly heated steels

Surface hardening of steels involves rapid austenitization and subsequent quenching of the surface. The resulting extent of hardening largely depends on the rate of austenitization of the surface under the applied high heating rates. In the present work the kinetics of austenite formation in Fe-C alloys during rapid, non-isothermal heating conditions, characterized by high heating rates and short austenitization periods, were studied by means of computational simulation. Austenitization of lamellar pearlite/proeutectoid ferrite microstructures was simulated by assuming two kinetically distinct stages: i) dissolution of lamellar pearlite followed by ii) dissolution of proeutectoid ferrite. The two stages were simulated by two corresponding 1-D diffusion models employed in series. Numerical solution of the resultant moving-boundary diffusion problems provide calculated results regarding the dependency of vol. fraction austenite on thermal cycle parameters and on initial microstructural features of the steel. Analysis of calculated results showed that the vol. fraction of pearlite transforming to austenite during pearlite dissolution depended on maximum temperature, dwell time and pearlite interlamellar spacing. A functional relationship between these variables, consisting of a thermodynamic and a kinetic term, was established. On the other hand, the total vol. fraction of austenite forming in the steel, after both stages of austenitization, was found to follow a typical sigmoidal kinetic behaviour.     

铁素体珠光体型非调质钢连续冷却转变的研究

采用DIL805L淬火相变膨胀仪研究了铁素体珠光体型非调质钢的连续冷却相变组织变化规律,分析了冷却速率和合金元素对相变组织、显微硬度和CCT曲线的影响。结果表明,Mo有助于获得针状铁素体组织,进而提高韧性,Mn与微合金元素V有助于提高钢的综合力学性能;冷速增大至0.5 ℃/s时,开始出现针状铁素体;冷速小于1 ℃/s时,获得完全的铁素体+珠光体组织;随着冷速的增大,钢的硬度不断增大。     

热轧带钢表面边部与中部氧化铁皮颜色差异探究

针对邯宝热轧厂热轧卷开卷后边部表面氧化铁皮呈蓝黑色,中部表面氧化铁皮呈灰白色,用户把这种氧化铁皮颜色差异与产品的力学性能差异相关联的问题,分析了热轧钢卷边部与中部氧化铁皮颜色差异的根本原因,即钢卷边部与中部层间缝隙大小和降温速率存在差异,导致热轧钢卷表面氧化铁皮结构不同。为此,提出了减小带钢凸度、杜绝带钢边部厚度突降、适当增加卷取张力、保证带钢均匀降温等措施,有效改善了带钢表面氧化铁皮颜色差异现象。     

以煤代重油改造中型氮肥厂的研讨

以煤代重油改变原料路线，对单产尿素、效益较差的企业提出了两种改造方案。     

Fe3+掺杂对氧化钛凝胶相变过程的影响

采用溶胶-凝胶法制备不同含量Fe3+掺杂的纳米氧化钛粉体,利用X光衍射仪研究了氧化钛凝胶的相变过程,分析了产物的晶体结构、金红石转变量和锐钛矿晶粒尺度.试验结果表明,Fe3+的掺杂抑制了锐钛矿相变,促进锐钛矿向金红石相的转变;阻碍锐钛矿晶粒的长大.Fe3+掺杂量大于2mol%时,在600℃烧结获得小于40nm的锐钛矿晶体.     

设备技术改造支撑企业的发展

本文着重介绍近几年来对热处理设备进行技术改造,改善了设备的各项综合性能指标,提高了产品质量、降低了成本,使企业走向良性循环发展.     

固溶温度对Cu-Zn-Al-Zr合金低频阻尼性能的影响

研究了固溶温度(650～900 ℃)对Cu-Zn-Al-Zr合金低频阻尼性能的影响.结果表明,随固溶温度升高,合金的阻尼性能提高,在800 ℃达到最大值,对数衰减率δ约为0.12;继续升高温度,合金的阻尼性能下降. 随应变振幅γmax增大,当γmax＜1.5×10-4时,阻尼迅速增加;当1.5×10-4＜γmax＜3×10-4时,阻尼增加缓慢; 当γmax＞3×10-4时,阻尼趋于稳定.