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122.
转炉试制超低硫低磷钻杆用钢的研究 总被引:1,自引:0,他引:1
为了满足塔里木油田对高韧性钻杆的需求,宝钢试制超低硫低磷钻杆用钢.试验表明,采用合适的冶炼工艺,大型转炉加炉外精炼能够批量生产超低硫低磷钻杆用钢,使钻杆获得高横向冲击韧性. 相似文献
123.
In order to determine the activities of phosphorus and iron in liquid {Cu‐Fe‐P} alloys, the two coexisting phases of liquid {Cu‐Fe‐P} alloys + <Cu‐Fe‐P> solid solutions were brought into equilibrium with a mixture of Al2O3 + AlPO4 + FexAl2O4 at temperatures of 1416K and 1526K. The oxygen partial pressures were measured with the aid of a solid‐oxide galvanic cell of the type: (+)Mo / Mo + MoO2/ ZrO2(MgO) / {Cu‐Fe‐P} + <Cu‐Fe‐P> + <Al2O3> + <AlPO4> + <FeAl2O4> / Fe(‐) The equilibrium reactions underlying the experiments can be expressed by 2[P]cu + (5/2) (O2) + <Al2O3> = 2 <AlPO4> and x[Fe]Cu + (1/2) (O2) + <Al2O3> = <FexAl2O4> The Henrian activity coefficient referred to 1 wt pct solution in pure liquid copper could be well expressed by the formula log fP° = (4.46±0.40) ‐ (8.67±0.59)/(T/K). The iron activities referred to pure solid iron could be formulated as log aFe =‐ (0.37 ± 0.12) + (500 ±200) /(T/K). 相似文献
124.
化学沉淀法处理高浓度含磷废水 总被引:3,自引:2,他引:1
采用氯化钙沉淀法处理高浓度含磷废水,考察了氯化钙投加量、pH值、反应温度及反应时间对除磷效果的影响。结果表明,氯化钙具有较好的除磷效果,在氯化钙的投加量满足n(Ca)∶n(P)=1.5∶1的条件,pH值为9.50,反应温度为25℃,反应时间为30 min的条件下,除磷率达到了99.90%。 相似文献
125.
污泥基生物炭内源重金属和养分含量因污泥来源的不同而差异较大。为探索污泥基生物炭“还田”后,其内源重金属变化和养分的去向问题,采用干湿交替对污泥基生物炭模拟老化处理,分析老化前后污泥基生物炭的Cu、Zn金属形态及TCLP浸出毒性的变化;研究污泥基生物炭BC1和BC2(分别以磷酸二氢钾、磷酸二氢钙与污泥混合后热解制备的生物炭)以5%和10%的质量分数与鲜土混合老化后对污泥基生物炭内源重金属稳定性及土壤有机碳和有效磷含量变化的影响。结果表明:两种污泥基生物炭与土壤混合老化后会使土壤中SiO2含量增加,但不会改变土壤的吸附类型;污泥基生物炭的添加会增加土壤的比表面积,其中BC2增幅较大,为36.17 m2/g;施加两种污泥基生物炭土壤中Cu、Zn生物有效性均有不同程度的降低。TCLP浸出毒性量相比老化前降低(BC1约降低37.5%)。此外,BC1对土壤有效磷的提升效果优于BC2(BC1 70 mg/kg,BC2 30 mg/kg);BC2对土壤有机碳的提升效果优于BC1(BC2 2.2%,BC1 1.15%)。BC2还田更有利于Cu、Zn的固定以及土壤有机碳和有效磷的提升。 相似文献
126.
《Journal of Nuclear Science and Technology》2013,50(10):944-949
A measurement method of tritiated moisture in gas stream has been developed by taking advantage of the high hygroscopic and deliquescent performances of phosphorus pentoxide P2O5. The method includes two techniques; one is of collecting moisture from gas stream using the desiccant, the other is of preparing homogeneous liquid scintillation cocktails containing the phosphide and the collected moisture. By introducing an idea of common use of standard vials as the collector cells disposable and the scintillation cocktail containers, the treatment process has been simplified and the chances of error arising in process for subsequent tritium analysis have been decreased. From results of a typical experiment, a relationship between the collection efficiencies and the moisture contents of P2O5 has been obtained and the isotope effect on the moisture collection has been elucidated. The collecting performance and the isotope effect are discussed here considering the mass transport phenomena in collector cell. 相似文献
127.
Yan Huang Honggang Lu Bingnan Wang Wenbo He Hongzhou Dong Lina Sui Zhixing Gan Shuai Ma Beili Pang Lifeng Dong Liyan Yu 《International Journal of Hydrogen Energy》2021,46(5):3530-3538
As a promising catalyst for solar hydrogen production, black phosphorus (BP) has received widespread attention due to variable band gaps, high carrier mobility, and strong light absorption performance. Herein, we use MoS2 as a cocatalyst to synthesize BP/MoS2 catalyst with polycrystalline BP to improve photocatalytic performance under visible light irradiation. A small amount of MoS2 can reduce the recombination of electron-hole pairs in the composite, increase carrier transport efficiency, and then improve photocatalytic performance. As expected, the 10/0.5 ratio of BP/MoS2 catalyst exhibits the highest photocatalytic hydrogen evolution performance with a hydrogen evolution rate of 575.4 μmol h?1 g?1, which is 2.5 times of pure BP. Based on the results above, a simple method is provided to synthesize low-cost black phosphorus-based photocatalysts. 相似文献
128.
高磷铁水预处理脱磷的难题是脱磷剂用量太大、温降太多,急需研究脱磷能力强的脱磷剂。含有固体颗粒和液渣的非均相脱磷剂比仅含液渣的均相脱磷剂的脱磷能力强很多。为此,针对磷的质量分数为0. 5%的高磷铁水,应用FactSageTM热力学软件优选出脱磷能力强的3种液渣,添加不同数量的硅酸二钙颗粒配制非均相脱磷剂试样,脱磷剂和熔铁在1560℃下反应6h,测定熔铁中的平衡磷含量,用以评价其脱磷能力,然后在1400℃下进行了铁水脱磷预处理试验。研究结果表明,随着硅酸二钙颗粒含量的增加,非均相脱磷剂的脱磷能力明显改善;采用非均相脱磷剂有助于减少渣量和控制反应器内衬的侵蚀;采用非均相脱磷剂对铁水脱磷,仍然需要控制较高的渣铁界面FetO浓度。 相似文献
129.
Several new phosphorus‐containing potential flame retardants (FRs) were prepared and evaluated for heat release reduction potential, by incorporation of the molecules into polyurethane samples, generated from methylene diphenyl diisocyanate and 1,3‐propane diol. The potential FRs were all prepared from commercial diisocyanates, with the phosphorus‐containing substructure introduced as a semicarbazone. All of the target structures were diols, to facilitate their incorporation into a polyurethane main chain. The polyurethane samples were prepared via copolymerization, and analysis clearly demonstrated that the potential FRs were chemically incorporated, prior to heat release testing. The heat‐release reduction potential of these substances was evaluated using the microcombustion calorimeter. Results demonstrated that both heat release reduction potential and char formation were structure dependent. Some of the compounds containing an aromatic core had more effect on char formation (higher char yields) and peak heat‐release rate (lowered heat release) than just phosphorus content alone. 相似文献
130.
Influence of thermal behavior of phosphorus compounds on their flame retardant effect in PU rigid foam
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Phosphorus‐containing compounds have been widely used as flame retardants for polyurethane rigid foam (PURF). In this work, a number of phosphorus compounds were utilized and studied as flame retardants for PURF, including ammonium polyphosphate, pentaerythritol phosphate, triethyl phosphate, and dimethyl methyl phosphonate. The thermal behavior of flame retardants was thoroughly investigated, such as degradation, vaporization, and the properties of degraded products. The influence of thermal behavior of phosphorus flame retardants on PURF was examined and analyzed. The results indicated that the effect of flame retardant was highly related to their thermal behavior. Phosphorus compounds for gas phase flame retardants were very effective in decreasing the heat release rate and increase limited oxygen index of PURF, while condensed phase flame retardants showed better comprehensive flame retardant effect, such as reducing the toxicity of combustion product. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献