A3钢表面有机膦合钼聚多酸盐转化膜的研究

由Ｎａ２ＭｏＯ４·２Ｈ２Ｏ和Ｎａ２ＨＥＤＰ·５Ｈ２Ｏ合成了有机膦合钼聚多酸盐Ｎａ８［（ＨＥＤＰ）２Ｍｏ５Ｏ２１］·５Ｈ２Ｏ。用Ｎａ８［（ＨＥＤＰ）２Ｍｏ５Ｏ２１］·５Ｈ２Ｏ的溶液处理Ａ３钢，获得了具有一定耐蚀性的黄色转化膜，适宜的工艺条件为：浓度１６ｇ·Ｌ－１，ｐＨ３．５，温度５０℃，时间８０ｓ。本文还报告了膜层的ＸＰＳ和ＡＥＳ分析结果。     

Coupling watershed modeling,public engagement,and soil analysis improves decision making for targeting P retention wetland locations

Constructed and restored wetlands can be effective sinks for particulate and dissolved phosphorus (P) if properly managed, but identifying suitable P retention wetland locations remains challenging. From a landscape perspective, Soil and Water Assessment Tool (SWAT) models identify locations within target watersheds with high nutrient loads that exhibit appropriate site characteristics and hydrodynamics. However, soil properties vary at the field scale, dictating the capacity of wetland systems to remove P and ultimately determining if a given wetland will operate as a sink or source of P over time. Land ownership and site access further complicate identification of P retention wetland locations. As a result, optimization and identification of P retention wetland locations requires analysis at both 1) watershed and 2) field scales, and 3) public engagement. In response, a survey effort linked SWAT model results that identified locations with target watersheds with field soil P storage capacity data and interested landowners. Results suggest that several locations recommended for their high SWAT-predicted P loading and landowner interest were in fact not well suited for project implementation due to soil P saturation and legacy P constraints. These findings highlight the need to couple watershed models with field scale soils analysis to identify locations for P retention wetlands in order to avoid unintended P release. Additionally, increased collaboration with social scientists and others familiar with public engagement strategies is needed to improve outreach activities targeting regional water quality improvements. Practical applications for nutrient retention wetland site selection are also discussed.     

面源污染中磷流失多重影响因素主成分分析

为全面了解对美国中部Illinois州具有浅层排水系统的轮作农业地区的面源污染问题,利用主成分分析方法及多元线性回归,对Little Vermillion River流域磷流失影响因素主成分进行分析.结果表明,磷流失的影响因素基本分为3大主成分:一是生物主成分,包括温度、植被类型、覆盖因子、生物量、散蒸量;二是水力主成分,降雨及流量;三是人为干扰主成分,施肥量及耕作内容.其中水力主成分对流失的影响最大,尤其是对浅层排水中磷流失的影响.     

Effects of COD to Phosphorus Ratios on the Metabolism of PAOs in Enhanced Biological Phosphorus Removal with Different Carbon Sources

To elucidate the phosphorus removal and metabolism under various COD / P ratio,a sludge highly enriched in PAOs was used to investigate the impacts of COD / P in batch tests under different carbon supply conditions. Acetate,propionate and a mixture of acetate and propionate at a ratio of 3 ∶ 1( COD basis) was used as carbon sources with the COD / P of 20,15,10 and 5. 0 g COD /gP,respectively. The minimum COD / P ratios for complete P removal were found to be 8. 24 g COD /gP for acetate,11. 40 g COD /gP for propionate and9. 10 g COD /gP for the 3 ∶ 1 mixture of acetate and propionate. Converted to a mass basis,all three cases had a very similar ratio of 7. 7 g VFA /gP,which represented a useful guide for operation of EBPR plants to identify possible shortages in VFAs. The trend in PHV accumulation during the anaerobic period along with the decrease of COD / P ratios suggested that,PAOs may use the TCA pathway for anaerobic VFA uptake to maintain the required NADH production with reduced glycogen degradation. During the aerobic phase,the glycogen pool was reduced but remained enough compared to the requirement for anaerobic VFA uptake,and the synthesis and degradation of glycogen was not the inhibition factor of PAOs.     

Ba—P复合变质对铝硅合金初晶硅的细化作用

研究了钡、磷及钡磷复台变质对过共晶铝硅合金初晶硅的细化作用，发现钡变质可细化初晶硅的尺寸，同时使硅晶体由板块状改变为树枝状；磷变质可明显细化初晶硅，但对其形状因子改变不大；但磷复合变质综合了二者的优势。硅晶体表面有钡或钡的化合物的吸附，认为吸附抑制机制是钡变质的实质。     

Recovery of gallium from phosphorus industry flue

The flue dust generated during electric furnace production of elemental phosphorus was investigated for the recovery of gallium. Then the flue dust was slurried with water and blended with concentrated sulfuric acid, followed by ageing. The gallium in the dust was thereby converted to soluble sulfate. The factors affecting the dust curing were investigated to understand the process chemistry of the pretreatment. The optimal curing conditions are determined as follows: the mass ratio of dust to water and acid is 1 : 1 : 1, ageing temperature and time are 200℃ and 2h, respectively. Almost all the gallium available to acid dissolution in the dust, about 90% gallium, can be extracted by leaching the cured dust at 80℃ for 1h.     

FRACTAL ANALYSES OF DIRECTIONAL SOLIDIFICATION BEHAVIOR OF A Ni-BASE SUPERALLOY

The morphology of solid/liquid interface of a directionally solidification process is describedby means of fractal analysis,and the relations among the fractal dimension of the solid/liq-uid interface,solidification rate,dendrite arm space and the phosphorus content of the test al-loys have been given.It was found that the increase of the solidification rate and the phos-phorus content of the test alloy will lead to a increase,following the regularity of exponentialfunction,in the fractal dimension of solid/liquid interface.Furthermore,by combining thefractal theory and the thermodynamic principle with the measured results,it has been provedthat the fractal dimension is not only a kind of simple geometrical parameter used in des-cribing irregular geometry,but also a state function depending the change of solidificationparameters and chemical compositions.     

温度和气氛对CaO-SiO2-Al2O3-MgO-FetO渣系磷容量的影响

采用气-渣-金平衡法测定CaO-SiO2-Al2O3-MgO-FetO渣系的磷容量,用钼坩埚作为反应容器,Ag-0.2%P合金作为气-渣-金平衡的熔剂,CO-CO2-Ar混合气体提供体系的氧分压,分析了温度和气氛对该渣系磷容量的影响.结果表明,对于一定成分的炉渣,当体系CO、CO2、Ar组成一定时,随着温度由1 723 K增加到1 823 K,CaO-SiO2-Al2O3-MgO-FetO渣系的磷容量降低;在1 773 K,气氛中氧分压由3.6×10-5 Pa增大到7.2×10-4 Pa时,磷容量随着氧分压的增大而增大.     

Influence of Electrolyte Composition on the Calcium-Phosphorus compound Coating on Titanium Substrate by Micro-arc Oxidation

In recent years the biomedical material has been widelydeveloped,and application that the implant materialssubstitute for hard organ has attracted much attention.Titanium alloys are frequently utilized as skeletonimplant and modification materials because of theirlight density,high strength and proper biocompatibility.However,titanium alloys are bioinertial materials,which are not beneficial to the performance of organiccoalescence,so they are not yet the ideal implantmaterials.Therefore,impro…     

合肥市区周边地表水体形态磷的研究

选取合肥市周边代表性的地表水体董铺水库、天鹅湖、翡翠湖为研究对象,运用地表水和污水监测技术规范中的标准方法,对3个水体的TP、DTP、PP、DIP、DOP进行监测,并做了初步研究和分析。结果表明,天鹅湖水体中总磷的平均浓度为O,102mg／L,符合V类标准要求,水体中磷主要以DTP和DOP的形式存在,TP—DIP显著正相关;董铺水库总磷的平均浓度为0．031mg／L,达到Ⅲ类标准,磷主要以DTP和DIP的形式存在,其中TP与DTP之间高度显著正相关;翡翠湖水体中总磷的平均浓度为0．060meCL,达到IV类标准,水体中磷主要以ADTP的形式存在,其@TP与PP之间显著正相关,PP在该湖泊中占有重要的地位。