Effects of COD to Phosphorus Ratios on the Metabolism of PAOs in Enhanced Biological Phosphorus Removal with Different Carbon Sources

To elucidate the phosphorus removal and metabolism under various COD / P ratio,a sludge highly enriched in PAOs was used to investigate the impacts of COD / P in batch tests under different carbon supply conditions. Acetate,propionate and a mixture of acetate and propionate at a ratio of 3 ∶ 1( COD basis) was used as carbon sources with the COD / P of 20,15,10 and 5. 0 g COD /gP,respectively. The minimum COD / P ratios for complete P removal were found to be 8. 24 g COD /gP for acetate,11. 40 g COD /gP for propionate and9. 10 g COD /gP for the 3 ∶ 1 mixture of acetate and propionate. Converted to a mass basis,all three cases had a very similar ratio of 7. 7 g VFA /gP,which represented a useful guide for operation of EBPR plants to identify possible shortages in VFAs. The trend in PHV accumulation during the anaerobic period along with the decrease of COD / P ratios suggested that,PAOs may use the TCA pathway for anaerobic VFA uptake to maintain the required NADH production with reduced glycogen degradation. During the aerobic phase,the glycogen pool was reduced but remained enough compared to the requirement for anaerobic VFA uptake,and the synthesis and degradation of glycogen was not the inhibition factor of PAOs.     

体积比对分段进水工艺处理低浓度废水性能的影响

采用改良A2/O四点分段进水工艺处理低浓度、低碳氮比城市生活污水.在HRT为8.7 h、SRT为15 d、污泥回流比为75%、进水流量分配比为20∶35∶35∶10、好氧段ρ(DO)为1~1.5 mg/L条件下,通过调整不同的厌氧/缺氧/好氧体积比,分析体积比对污染物去除性能的影响.结果表明:不同的体积比对COD、氨氮的去除基本无影响,但对TN、TP去除影响较大.当厌氧/缺氧/好氧体积比为4∶8∶10时,对污染物去除效果最佳,出水COD、氨氮、总氮、总磷质量浓度分别为28.12、0.58、9.26、0.43 mg/L,进水碳源有效利用率达72.4%.通过逐步减少好氧段体积以提高缺氧段体积的策略,可使进水碳源在各缺氧段或厌氧段被充分利用,同时有利于反硝化除磷菌的富集,DPAOs最高比例为20.9%.     

Ba—P复合变质对铝硅合金初晶硅的细化作用

研究了钡、磷及钡磷复台变质对过共晶铝硅合金初晶硅的细化作用，发现钡变质可细化初晶硅的尺寸，同时使硅晶体由板块状改变为树枝状；磷变质可明显细化初晶硅，但对其形状因子改变不大；但磷复合变质综合了二者的优势。硅晶体表面有钡或钡的化合物的吸附，认为吸附抑制机制是钡变质的实质。     

Recovery of gallium from phosphorus industry flue

The flue dust generated during electric furnace production of elemental phosphorus was investigated for the recovery of gallium. Then the flue dust was slurried with water and blended with concentrated sulfuric acid, followed by ageing. The gallium in the dust was thereby converted to soluble sulfate. The factors affecting the dust curing were investigated to understand the process chemistry of the pretreatment. The optimal curing conditions are determined as follows: the mass ratio of dust to water and acid is 1 : 1 : 1, ageing temperature and time are 200℃ and 2h, respectively. Almost all the gallium available to acid dissolution in the dust, about 90% gallium, can be extracted by leaching the cured dust at 80℃ for 1h.     

FRACTAL ANALYSES OF DIRECTIONAL SOLIDIFICATION BEHAVIOR OF A Ni-BASE SUPERALLOY

The morphology of solid/liquid interface of a directionally solidification process is describedby means of fractal analysis,and the relations among the fractal dimension of the solid/liq-uid interface,solidification rate,dendrite arm space and the phosphorus content of the test al-loys have been given.It was found that the increase of the solidification rate and the phos-phorus content of the test alloy will lead to a increase,following the regularity of exponentialfunction,in the fractal dimension of solid/liquid interface.Furthermore,by combining thefractal theory and the thermodynamic principle with the measured results,it has been provedthat the fractal dimension is not only a kind of simple geometrical parameter used in des-cribing irregular geometry,but also a state function depending the change of solidificationparameters and chemical compositions.     

温度和气氛对CaO-SiO2-Al2O3-MgO-FetO渣系磷容量的影响

采用气-渣-金平衡法测定CaO-SiO2-Al2O3-MgO-FetO渣系的磷容量,用钼坩埚作为反应容器,Ag-0.2%P合金作为气-渣-金平衡的熔剂,CO-CO2-Ar混合气体提供体系的氧分压,分析了温度和气氛对该渣系磷容量的影响.结果表明,对于一定成分的炉渣,当体系CO、CO2、Ar组成一定时,随着温度由1 723 K增加到1 823 K,CaO-SiO2-Al2O3-MgO-FetO渣系的磷容量降低;在1 773 K,气氛中氧分压由3.6×10-5 Pa增大到7.2×10-4 Pa时,磷容量随着氧分压的增大而增大.     

Influence of Electrolyte Composition on the Calcium-Phosphorus compound Coating on Titanium Substrate by Micro-arc Oxidation

In recent years the biomedical material has been widelydeveloped,and application that the implant materialssubstitute for hard organ has attracted much attention.Titanium alloys are frequently utilized as skeletonimplant and modification materials because of theirlight density,high strength and proper biocompatibility.However,titanium alloys are bioinertial materials,which are not beneficial to the performance of organiccoalescence,so they are not yet the ideal implantmaterials.Therefore,impro…     

合肥市区周边地表水体形态磷的研究

选取合肥市周边代表性的地表水体董铺水库、天鹅湖、翡翠湖为研究对象,运用地表水和污水监测技术规范中的标准方法,对3个水体的TP、DTP、PP、DIP、DOP进行监测,并做了初步研究和分析。结果表明,天鹅湖水体中总磷的平均浓度为O,102mg／L,符合V类标准要求,水体中磷主要以DTP和DOP的形式存在,TP—DIP显著正相关;董铺水库总磷的平均浓度为0．031mg／L,达到Ⅲ类标准,磷主要以DTP和DIP的形式存在,其中TP与DTP之间高度显著正相关;翡翠湖水体中总磷的平均浓度为0．060meCL,达到IV类标准,水体中磷主要以ADTP的形式存在,其@TP与PP之间显著正相关,PP在该湖泊中占有重要的地位。     

环境因子对鱼饵中磷释放影响的实验研究

通过室内模拟实验,分析了环境因子(上覆水、微生物活动、温度、pH、水动力条件)对鱼饵磷释放特征的影响及原因。结果表明:鱼饵在去离子水中总磷和正磷酸盐的平衡释放量约是潘家口水库水中的1.58倍和1.76倍;微生物作用有利于鱼饵中磷向水体释放,前者总磷和正磷酸盐的释放量约为后者的1.55倍和1.28倍;温度升高和水体扰动促进了鱼饵中磷的释放;酸性和碱性条件下鱼饵中磷的释放量高于中性条件下鱼饵中磷的释放量。各环境因子作用下,鱼饵中磷在前3h内的释放速率最大。     

Electrocatalysis of Fe-N-C Bonds Driving Reliable Interphase and Fast Kinetics for Phosphorus Anode in Sodium-Ion Batteries

Phosphorus exhibits high capacity and low redox potential, making it a promising anode material for future sodium-ion batteries. However, its practical applications are confined by poor durability and sluggish kinetics. Herein, an innovative in-situ electrochemically self-driven strategy is presented to embed phosphorus nanocrystal (≈10 nm) into a Fe-N-C-rich 3D carbon framework (P/Fe-N-C). This strategy enables rapid and high-capacity sodium ion storage. Through a combination of experimental assistance and theoretical calculations, a novel synergistic catalytic mechanism of Fe-N-C is reasonably proposed. In detail, the electrochemical formation of Fe-N-C catalytic sites facilitates the release of fluorine in ester-based electrolyte, inducing Na⁺-conducting-enhanced solid-electrolyte interphase. Furthermore, it also effectively induces the dissociation energy of the P-P bond and promotes the reaction kinetics of P anode. As a result, the unconventional P/Fe-N-C anode demonstrates outstanding rate-capability (267 mAh g⁻¹ at 100 A g⁻¹) and cycling stability (72%, 10 000 cycles). Notably, the assembled pouch cell achieves high-energy density of 220 Wh kg⁻¹.