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881.
Jingfei Luan Yue Shen Lingyan Zhang Ningbin Guo 《International journal of molecular sciences》2016,17(9)
BiGdO3 nanoparticles were prepared by a solid-state reaction method and applied in photocatalytic degradation of dyes in this study. BiGdO3 was characterized by X-ray powder diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, Brunauer-Emmett-Teller, UV-Vis diffuse reflectance spectroscopy and transmission electron microscopy. The results showed that BiGdO3 crystallized well with the fluorite-type structure, a face-centered cubic crystal system and a space group Fm3m 225. The lattice parameter of BiGdO3 was 5.465 angstrom. The band gap of BiGdO3 was estimated to be 2.25 eV. BiGdO3 showed a strong optical absorption during the visible light region. Moreover, the photocatalytic activity of BiGdO3 was evaluated by photocatalytic degradation of direct dyes in aqueous solution under visible light irradiation. BiGdO3 demonstrated excellent photocatalytic activity in degrading Direct Orange 26 (DO-26) or Direct Red 23 (DR-23) under visible light irradiation. The photocatalytic degradation of DO-26 or DR-23 followed the first-order reaction kinetics, and the first-order rate constant was 0.0046 or 0.0023 min−1 with BiGdO3 as catalyst. The degradation intermediates of DO-26 were observed and the possible photocatalytic degradation pathway of DO-26 under visible light irradiation was provided. The effect of various operational parameters on the photocatalytic activity and the stability of BiGdO3 particles were also discussed in detail. BiGdO3/(visible light) photocatalysis system was confirmed to be suitable for textile industry wastewater treatment. 相似文献
882.
90%以上高暴露单晶面TiO2(001),(101)和(010)以水热法合成,并通过光沉积方法负载贵金属Ag;在相同的负载条件下,由于不同晶面具有不同的原子排布和电子结构,其负载的Ag的粒径不同,TiO2(101)晶面上Ag的平均粒径最小,TiO2(001)晶面上Ag的平均粒径最大,Ag的粒径大小顺序:Ag/TiO2-101相似文献
883.
Jifeng Guo Simeng Li Liang Duan Ping Guo Xiaojie Li Qianqian Cui 《Integrated ferroelectrics》2016,168(1):170-182
TiO2, molecularly imprinted TiO2 (TiO2/OTC) and a novel Si doped molecularly imprinted TiO2 (TiO2/SiO2/OTC) nano photocatalytic materials were prepared by liquid phase deposition method. The products were characterized by XRD and SEM. The photocatalytic activities of the samples were evaluated by the photocatalytic degradation of oxytetracycline wastewater under a xenon lamp irradiation. The results showed that TiO2/SiO2/OTC and TiO2/OTC could improve both the photocatalytic activity and the molecular recognition ability, while the photocatalytic activities of TiO2/SiO2/OTC sample was more effective than TiO2/OTC sample with 5 times reuse. The photocatalytic activity of TiO2/SiO2/OTC photocatalyst sample had a greater improvement and its photocatalytic degradation of oxytetracycline wastewater reached 80.79% in 120 minute reaction. 相似文献
884.
885.
邓真丽 《精细石油化工进展》2012,13(3):32-34
采用溶胶-凝胶法制备了稀土La3+掺杂的TiO2催化剂,并用XRD对其进行表征,用催化剂对染料媒介漂兰B进行降解处理,考察影响降解率的因素.结果表明,La3+掺杂的TiO2降解效果较纯TiO2好,当La3+掺杂摩尔分数为0.5%,媒介漂兰B的质量浓度为20 mg/L,体系pH值为3,催化剂用量为1.5 g/L时,染料废水降解率可达97.7%. 相似文献
886.
Abdollahi Y Abdullah AH Zainal Z Yusof NA 《International journal of molecular sciences》2012,13(1):302-315
Photocatalytic degradation of p-cresol was carried out using ZnO under UV irradiation. The amount of photocatalyst, concentration of p-cresol and pH were studied as variables. The residual concentration and mineralization of p-cresol was monitored using a UV-visible spectrophotometer and total organic carbon (TOC) analyzer, respectively. The intermediates were detected by ultra high pressure liquid chromatography (UPLC). The highest photodegradation of p-cresol was observed at 2.5 g/L of ZnO and 100 ppm of p-cresol. P-cresol photocatalytic degradation was favorable in the pH range of 6-9. The detected intermediates were 4-hydroxy-benzaldehyde and 4-methyl-1,2-benzodiol. TOC studies show that 93% of total organic carbon was removed from solution during irradiation time. Reusability shows no significant reduction in photocatalytic performance in photodegrading p-cresol. 相似文献
887.
以钼酸铵、硝酸铋和硝酸铁为原料,采用水热/溶剂热法合成了铁掺杂的钼酸铋光催化剂,用X-射线粉末衍射、扫描电镜及紫外-可见吸收光谱等进行表征,并以罗丹明B为模型污染物,考察了纳米钼酸铋对罗丹明B溶液的光催化降解活性;以噻吩作为典型的含硫污染物,评价样品的光催化氧化脱硫活性。结果表明,Fe元素掺杂导致Bi2 MoO6的尺寸下降,比表面积增大;Fe掺杂,Bi2 MoO6吸收边发生红移;光催化活性与Fe元素的掺杂浓度有关,当掺杂量为0.5%时,活性最高;Fe掺杂Bi2MoO6对模拟汽油具有较好的脱硫活性,模拟可见光照射3 h,可使用模拟汽油的硫含量降低至70μg/g以下,脱硫率达到89%。 相似文献
888.
889.
AbstractThe use of nanoparticles in electrospun web has always been of great interest for a wider and easier application especially for microwave absorption and photocatalytic activity. In this work, nickel nanoparticles/recycled poly (ethylene terephthalate) nanofibers web (Ni NPs/RPET NFs web) were electrospun from a homogeneous sonicated RPET solution containing Ni NPs with an average diameter of 32.5?nm synthesizedthrough the chemical reduction method. To study morphologies, crystalline structure, magnetic, wettability, microwave absorption and photocatalytic activities of the web, field emission-scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM) and electromagnetic properties were used. The saturation magnetization of the Ni NPs/RPET NFs web at a nickel concentration of 3% was 0.5?emu/g. In addition, the wettability, the reflection coefficient, the absorption coefficient, the EMI shielding and the photocatalytic activities of the Ni NPs/RPET NFs web were improved compared to the RPET NFs web. 相似文献
890.