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91.
We study theoretically the negative refraction of a surface plasmon polariton. The system we consider consists of a vacuum that is in a contact with two metals that each fill a quarter space with a periodic boundary between them. The interface of each of the metals with the vacuum supports a surface plasmon polariton. When a surface plasmon polariton passes through the periodic boundary between the metals it transforms partly into the Bragg beams of the refracted and reflected surface plasmon polaritons and partly into volume waves in the vacuum. A suitable choice of the period can ensure that the only propagating Bragg beams of the refracted surface plasmon polariton are the specular beam and the (?1)-order beam, which is negatively refracted. With a suitable choice for the form of the profile function and its amplitude the specular beam can be made to vanish. 相似文献
92.
The special interaction between 3-aminophenylboronic acid and monosaccharides, particularly glucose, fructose and galactose, has been investigated and used for the development of electrochemical and surface plasmon resonance (SPR) based saccharide sensors. The binding constants and thermodynamic parameters of interaction such as free energy of binding (ΔG), enthalpy (ΔH) and entropy (ΔS) were determined for the first time using isothermal titration calorimetry revealed the enthalpic and entropic contributions to the free energies of binding. Effects of pH and buffer on the binding constants (k) between 3-aminophenylboronic acid and monosaccharides were also examined. The binding constant of fructose was found to be six times higher than glucose and four times higher than galactose at pH 11, leading the specific detection of fructose. SPR and potentiometric calibration for fructose were linear in the concentration range of 10–120 mM and 8–84 mM, respectively. Limit of detection of the SPR and potentiometric method were found to be as 8.9 mM and 1.4 mM, respectively. 相似文献
93.
94.
Naveen Reddy Kadasala Lu Lin Christopher Gilpin 《Science and Technology of Advanced Materials》2013,14(1):210-218
AbstractAu–FexOy composite nanoparticles (NPs) are of great technological interest due to their combined optical and magnetic properties. However, typical syntheses are neither simple nor ecologically friendly, creating a challenging situation for process scale-up. Here we describe conditions for preparing Au–FexOy NPs in aqueous solutions and at ambient temperatures, without resorting to solvents or amphiphilic surfactants with poor sustainability profiles. These magnetic gold nanoclusters (MGNCs) are prepared in practical yields with average sizes slightly below 100 nm, and surface plasmon resonances that extend to near-infrared wavelengths, and sufficient magnetic moment (up to 6 emu g–1) to permit collection within minutes by handheld magnets. The MGNCs also produce significant photoluminescence when excited at 488 nm. Energy dispersive X-ray (EDX) analysis indicates a relatively even distribution of Fe within the MGNCs, as opposed to a central magnetic core. 相似文献
95.
Fangfang LiuAuthor Vitae Jingyu ZhangAuthor Vitae Yan DengAuthor VitaeDaqian WangAuthor Vitae Youyong LuAuthor VitaeXinglong YuAuthor Vitae 《Sensors and actuators. B, Chemical》2011,153(2):398-403
Label-free and real-time information acquisition of molecular phenotype and its function on living cells plays a significant role in disease diagnosis and drug development. In this paper, SPR phase sensing was applied to monitor the interactions between EGFR antibody, EGFR1, and membrane proteins EGFR on living human gastric cancer BGC823 cells. When 50 μg/mL EGFR1 was added onto the fixed cells chip and the living cells chip, a significant difference in the binding amount could be observed from the immunofluorescence images. Quantitative results were obtained by following SPR detection, which were 722 RU and 438 RU, respectively. On the same living cells chip, SPR detection also showed markedly different results of cellular responses when it was stimulated by EGFR1 at different concentrations, such as adhesion and/or morphology variation, revealing the EGFR1's cytotoxic effect on the BGC823 cells. The results demonstrate SPR phase sensing is capable of real-time detection of molecular interactions and cellular responses on living cells, and suggest that further studies on the mechanism and the technique may allow SPR sensing become a powerful tool not only for the basic research of cell biology, but also for medical diagnosis and drug development. 相似文献
96.
Dispersed nanosphere lithography can be employed to fabricate gold nanostructures for localized surface plasmon resonance,
in which the gold film evaporated on the nanospheres is anisotropically dry etched to obtain gold nanostructures. This paper
reports that by wet etching of the gold film, various kinds of gold nanostructures can be fabricated in a cost-effective way.
The shape of the nanostructures is predicted by profile simulation, and the localized surface plasmon resonance spectrum is
observed to be shifting its extinction peak with the etching time. 相似文献
97.
David Duche Ludovic Escoubas Jean-Jacques Simon Gérard Mathian 《Solar Energy Materials & Solar Cells》2009,93(8):1377-1382
Plasmonic phenomenon inside the materials composing an organic solar cell based on a photoactive poly(2-methoxy-5-(2′-ethyl-hexyloxy)-1,4-phenylenevinylene):(6,6)-phenyl-C61-butyric-acid-methyl ester (MEH-PPV:PCBM) bulk heterojunction is studied using Finite Difference Time Domain (FDTD) method calculations and the modeling results are compared with experimental results.Enhanced absorptance of light up to 50% is experimentally obtained in a 50-nm-thick blend layer including spin-coated silver nanospheres with a diameter of 40 nm. FDTD calculations based on the design of 2D-grating of nanoparticles confirm the high values of absorptance. Spatial distributions of electromagnetic field power density in the structures show confinement of the power at the interface or in the vicinity of the nanoparticles depending on the wavelength and on the preferential directions. 相似文献
98.
Y. Takeda O.A. Plaksin J. Lu K. Kono N. Kishimoto 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2006,250(1-2):372-376
Optical nonlinearity and dispersion were studied for Cu nanoparticle composite. Negative Cu− ions with 60 keV were applied for implanting into SrTiO3 at a flux of 10 μA/cm2 up to a total fluence of 1 × 1017 ions/cm2. The steady-state optical spectrum of Cu-implanted SrTiO3 showed a surface plasmon resonance resulting from the formation of nanoparticles. Transient transmission and reflection were measured by the pump–probe method with a femtosecond laser system. Optical nonlinearity originated from Cu:SrTiO3 nanoparticle composite and from SrTiO3 matrix overlap, in measured transient spectra. The nonlinear component of Cu:SrTiO3 composite was extracted from the transient spectra with the difference of time response. Nonlinear dielectric coefficient and dispersion around the surface plasmon resonance were derived from extracted transient spectra. The dispersion was compared with a local electric field factor. 相似文献
99.
Abstract— We theoretically modeled the optical plasmon absorption of anisotropic metallic nanoparticles in a liquid‐crystal host medium. Metallic nanorods and spheroids act as pleochroic dopants with virtually unlimited photostability. Calculations predict that full‐color displays based on nanorod orientation driven by the transition from homogeneous to homeotropic LC alignment are feasible. These displays are expected to have large viewing angles without the need for polarizers or LC anchoring surfaces. 相似文献
100.