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71.
The electrochemical oxidation of 2-naphthol has been studied by galvanostatic electrolysis, using a range of electrode materials such as lead dioxide, boron-doped diamond (BDD) and Ti-Ru-Sn ternary oxide anodes. The influence of some operating parameters, such as current density, flow-rate and chloride concentration on naphthol oxidation has been investigated in order to find the optimum experimental conditions. Measurements of chemical oxygen demand, HPLC and total organic carbon have been used to follow the oxidation. The experimental data indicate that on PbO2 and BDD, naphthol oxidation takes place by reaction with electrogenerated hydroxyl radicals and is favoured by low current density and high flow-rate. On the contrary, on a Ti-Ru-Sn ternary oxide the mineralisation of naphthol occurs only in the presence of chloride ions that act as redox mediators and COD removal is affected by chloride concentration and is not significantly influenced by the current density and mass-transfer coefficient. From a comparison of the results of the three electrodes it has been found that boron-doped diamond gives a faster oxidation rate and better current efficiency. 相似文献
72.
通过正交实验,研究了γ-Al2O3载体制备中拟薄水铝石水洗的连续化。方差分析表明,第一阶段洗水的pH是影响脱氯效果的关键因素,初步得出水洗连续化的优化条件。与国内外传统的间歇式水洗相比,收率从80%提高到99.7%,所需洗水量仅为原来的1/3,而处理500 kg物料的生产周期也从10 h缩短到2~3 h。 相似文献
73.
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75.
Carbon materials and catalytic wet air oxidation of organic pollutants in wastewater 总被引:1,自引:0,他引:1
F. Stüber J. Font A. Fortuny C. Bengoa A. Eftaxias A. Fabregat 《Topics in Catalysis》2005,33(1-4):3-50
The use of carbon materials as catalytic support or direct catalyst in catalytic wet air oxidation (WAO) of organic pollutants is reviewed. The discussion covers important engineering aspects including the characterisation, activity and stability of carbon catalysts, process performance, reaction kinetics and reactor modelling. Recommendations for further research in catalytic WAO are outlined. 相似文献
76.
The possibility of multiplicity in an isothermal continuous mixed suspension-mixed product removal crystallizer is explored using the bifurcation theory.A process involving agglomeration controlled precipitation is considered in which secondary nucleation occurs simultaneously with primary nucleation.The determinant equations for the existence of multiple steady states are developed and the multiplicity boundaries dependent on the physical and kinetic properties and operational parameters of the process are obtained by resolving these determinant equations.The number of steady states in the precipitator for various multiplicity regions is determined and the linear stability of these steady states is analyzed by using the Routh criterion. 相似文献
77.
《Fuel》2003,82(2):147-151
The aim of this paper is to show how a cheap carbonaceous material such as low rank coal-based carbon (or char) can be used in the combined SO2/NO removal from exhaust gas at the linear gas velocity used in commercial systems (0.12 m s−1). Char is produced from carbonization and optionally activated with steam. This char is used in a first step to abate the SO2 concentration at the following conditions: 100 °C, space velocity of 3600 h−1, 6% O2, 10% H2O, 1000 ppmv SO2, 1000 ppmv NO and N2 as remainder. In a second step, when the SO2 concentration in the flue gas is low, NO is reduced to N2 and steam at the following experimental conditions: 150 °C, space velocity of 900 h−1, 6% O2, 10% H2O, 0-500 ppmv SO2, 1000 ppmv NO, 1000 ppmv NH3 and N2 as remainder.It has been shown that the presence of NO has no effect on SO2 abatement during the first step of combined SO2/NO removal system and that low SO2 inlet concentration has a negligible effect on NO reduction in the second step. Moreover, this char can be thermally regenerated after use for various cycles without loss of activity. On the other hand, this regenerated char shows the highest NO removal activity (compared to parent chars, either carbonized or steam activated) which can be attributed to the activating effect of the sulfuric acid formed during the first step of the combined SO2/NO removal system. 相似文献
78.
电解法处理利福霉素SV钠废渣分离液的研究 总被引:2,自引:0,他引:2
根据电化学原理,采用电解法,利用铁屑与炭粒作电极,处理利福霉素SV钠药渣分离液,讨论各种因素对分离液污染物作效果的影响,COD去除率可达91.8%左右,脱色率可达95%左右。 相似文献
79.
Effect of operating conditions in removal of arsenic from water by nanofiltration membrane 总被引:2,自引:0,他引:2
The removal of arsenic from synthetic waters and surface water by nanofiltration (NF) membrane was investigated. In synthetic solutions, arsenic rejection experiments included variation of arsenic retentate concentration, transmembrane pressure, crossflow velocity and temperature. Arsenic rejection increased with arsenic retentate concentration. Arsenic was removed 93-99% from synthetic feed waters containing between 100 and 382 μg/L as V, resulting in permeate arsenic concentrations of about 5 μg/L. Under studied conditions, arsenic rejection was independent of transmembrane pressure, crossflow velocity and temperature. In surface water, the mean rejection of As V was 95% while the rejection of sulfate was 97%. The co-occurrence of dissolved inorganics does not significantly influence arsenic rejection. The mean concentration of As in collected permeated was 8 μg/L. The mean rejection of TDS, total hardness and conductivity were 75, 88 and 75% respectively. 相似文献
80.
塑料旋转成型的特点与研究 总被引:3,自引:0,他引:3
介绍了塑料旋转成型的原理和主要特点,对旋转成型制品中易出现的气泡和弯曲,收缩现象,以及冲击强度低的原因进行了分析研究,相应地提出了减少或消除旋转成型制品中的气泡,减少或消除制品收缩和弯曲,以及提高制品冲击强度的主要途径。 相似文献