直径对单壁碳纳米管热力学性质影响的理论研究

采用MedeA软件包优化了一系列不同直径的碳纳米管的结构,并计算了相关声子谱和声子态密度,进一步计算了碳纳米管的热力学性质。结果表明碳纳米管的直径和温度对其热力学性质有影响。碳纳米管的直径越大,其生成能和总能量就越低,即稳定性越好。在低温时,直径对碳纳米管的热力学性质的影响较小;高温时,碳纳米管的热力学性质Cv(T)、S0(T)、–A(T)及Evib(T)随直径增大呈现升高趋势,而E(T)和G(T)则随碳纳米管的直径增大呈现降低趋势。     

孔隙水溶液浓度对膨胀土膨胀特性的影响

通过开展恒体积膨胀压力试验与有荷膨胀率试验,研究了孔隙水溶液浓度对膨胀土膨胀特性的影响.试验结果表明,随着溶液浓度的增大,膨胀压力降低;相同浓度溶液制作的试样,分别浸入不同浓度的溶液,一种浓度小于制样所用浓度,另一种与制样溶液浓度相等,最终所得的膨胀压力与膨胀应变均很接近.通过对孔隙水赋存状态的分析表明,试验结果均符合渗透压理论.     

Influence of subsequent curing on water sorptivity and pore structure of steam-cured concrete

Steam-cured condition is found to cause larger porosity and worse properties of concrete compared with normal curing condition. For the sake of seeking effective measurements to eliminate this bad effect of steam-cured condition on concrete, the water sorptivity and pore structure of steam-cured concretes exposed to different subsequent curing conditions were investigated after steam-curing treatment. The capillary absorption coefficient and porosity of the corresponding concretes were analyzed, and their mechanisms were also discussed. The results indicate that water sorptivity and pore structure of steam-cured concrete are greatly influenced by the curing condition used in subsequent ages. Exposure steam-cured concrete to air condition has an obviously bad effect on its properties and microstructures. Adopting subsequent curing of immersing steam-cured concrete into about 20 °C water after steam curing period can significantly decrease its capillary absorption coefficient and porosity. Steam-cured concrete with 7 d water curing has minimum capillary absorption coefficient and total porosity. Its water sorptivity is decreased by 23% compared with standard curing concrete and the porosity is 9.6% lower. Moreover, the corresponding gradient of water sorptivity and porosity of steam-cured concrete both decrease, thus microstructure of concrete becomes more homogeneous.     

某围垦工程原位监测施工和分析

通过某围垦工程原位监测施工实施,阐述了原位监测的目的和意义,并对原位监测成果进行分析,得到监测的有效数据,从而指导下一步的施工,确保地基稳定、沉降均匀。     

Oxidation behaviors of Ni-Cr-Al superalloy foams at 1 000 ℃ in air

The oxidation behaviors of Ni-16Cr-xAl （x=4.5%, 9.0%, mass fraction） superalloy foams in air at 1000℃ were investigated. The effects of AI content on the resistance to high temperature oxidation were examined. The oxidation mechanisms of the foams were discussed. The results show that the resistance to the oxidation of the Ni-16Cr-xA1 based alloy at 1 000 ℃ increases with the content of A1 increasing from 4.5% to 9.0%. Complex oxide products are formed on the surface of the superalloy foams after the oxidation. Cr203 and A1203 are the predominant oxides for the scales of the foams with 4.5% A1 and 9% A1, respectively. Excellent high temperature oxidation resistance and superior pore conformation stability for the Ni-16Cr-xA1 based superalloy foam with 9% A1 can be mainly attributed to the formation of relatively continuous and protective A1203 oxides on the surface of the foam.     

O2／CO2气氛下煤燃烧过程中孔隙结构演化特征

在固定床和热重分析仪上对云浮烟煤焦在不同温度下O2／CO2燃烧特性进行研究．研究结果表明热解终温和温度是影响煤焦燃烧特性的主要因素,反应速率随着温度的升高而增大,并且热解终温对焦结构的影响是不可忽略的．这主要是由于孔隙结构的变化主要受挥发分析出和焦受热变形的影响．云浮烟煤O2／CO2燃烧过程中起始阶段比表面积（SBET）有增加趋势,这种现象的产生主要是由于煤焦燃烧过程中微孔的扩容和新孔的产生,并且比表面积与微孔孔容积的变化规律非常相似,而这由于SHET主要是由微孔来提供,但当转换率大于80％时由于孔坍塌造成SBET有减小的趋势．     

基于图论模型的三环网络G（N；1，s，s＋1）直径分布算法

针对三环网络,提出一种基于图论模型的直径求解算法。从图论模型出发,以仿真方法得到对于任意给定的N,2≤s≤N-2这样一族三环网络的直径,并得出对于任意的N,有一些S使得G（N：1,s,s＋1）紧优。利用C＋＋编程计算出三环网络的直径分布图,并分析其直径分布特点。     

大孔Ni_2P/γ-A1_2O_3催化剂的制备及加氢脱硫性能研究

采用酸沉淀法制备大孔γ-Al2O3为载体,并用浸渍法制备Ni2P(25%)/γ-A12O3催化剂。BET、XRD、压汞法的分析结果显示:合成大孔γ-Al2O3载体晶型良好,且具有适宜比表面积和孔结构。催化剂经原位还原处理后,以柴油为原料在连续固定反应装置上,考察了催化剂的制备条件及反应条件对催化剂加氢脱硫活性的影响。结果表明:当载体合成温度为80℃,反应pH为8,反应条件为温度360℃、压力4.0MPa、空速1.0h-1、氢烃体积比500∶1时,催化剂的加氢脱硫活性最好,柴油的脱硫率可达98.2%。