PTA生产中浆料浓度的先进控制

在PTA生产过程中,TA浆料浓度是一个极其重要的工艺变量,该变量控制的好坏直接影响最终产品的产量和质量。首先分析了浆料浓度的特性,然后根据其特性提出了非线性补偿+预测控制的先进控制策略。实际应用表明,这一控制策略可以显著减少浆料浓度波动、提高装置处理能力。     

Mechanical properties and crosslink density of rare earth‐modified high‐abrasion furnace‐filled powdered natural rubber

High‐abrasion furnace‐filled powdered natural rubber [P(NR/HAF)] has more advantages than traditional HAF‐filled bale NR (NR/HAF) because of its better environmental performance and easier processing quality, but its lower mechanical properties are disadvantageous. To improve the mechanical properties, rare earth‐modified HAF‐filled powdered NR [P(NR/HAF‐Ln)] (Ln = Sm,La,Pr) was prepared by means of coacervation–coprecipitation, using rare earth‐modified HAF as separant and filler. The effect on mechanical properties of P(NR/HAF‐Ln) vulcanizate exerted by the emulsifier/HAF ratio, powdering temperature, Ln/HAF ratio and type of Ln, and HAF content were studied. The results indicated that when optimum formulation, the mechanical properties of P(NR/HAF‐Ln) vulcanizate were better than P(NR/HAF) vulcanizate. In addition, the relationship of the apparent crosslink density and HAF content of P(NR/HAF‐Ln), P(NR/HAF), NR/HAF vulcanizates was also investigated, along with their SEM microphotographs of tensile fracture surface, which indicated that the excellent mechanical properties of P(NR/HAF‐Ln) vulcanizate was attributed to correct amount of Ln that could increase crosslink density and reinforce the interface structure of NR matrix/HAF‐Ln particle. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 1755–1762, 2006     

一种基于混合高斯模型的多目标进化算法

目前,大多数多目标进化算法采用为单目标优化所设计的重组算子.通过证明或实验分析了几个典型的单目标优化重组算子并不适合某些多目标优化问题.提出了基于分解技术和混合高斯模型的多目标优化算法（multiobjective evolutionary algorithm based on decomposition and mixture Gaussian models,简称MOEA/D-MG）.该算法首先采用一个改进的混合高斯模型对群体建模并采样产生新个体,然后利用一个贪婪策略来更新群体.针对具有复杂Pareto前沿的多目标优化问题的测试结果表明,对给定的大多数测试题,该算法具有良好的效果.     

基于密度调整的改进自适应谱聚类算法

针对谱聚类存在构造相似度矩阵时对尺度参数敏感以及处理多重尺度数据集效果不理想的缺陷, 提出一种基于密度调整的改进自适应谱聚类算法. 该算法将样本点所处领域的密度引入谱聚类, 利用密度差来调整样本点之间的相似度, 使其更符合实际簇类中样本点间的内在关系, 在一定程度上解决了多尺度聚类问题; 同时, 通过样本点的近邻距离自适应得到尺度参数, 使算法对尺度参数相对不敏感. 仿真实验验证了所提出算法的有效性和优越性.

     

Physicochemical properties of irradiated and loaded LDPE films with polyfunctional monomers

Polyfunctional monomers (PFMs), namely, trimethylol propane trimethacrylate (TMPTMA), trimethylol propane triacrylate, ethylene glycol dimethacrylate, and diethylene glycol diacrylate were blended with low‐density polyethylene (LDPE) and exposed to different doses of EB irradiation. Fourier transform infrared and ultraviolet and UV–vis spectroscopy of the unirradiated, irradiated, unloaded, and PFMs‐loaded LDPE films were studied under various irradiation doses up to 300 kGy. The degree of crosslinking and oxidative degradation, as measured by the spectroscopic parameters, were dependent on both the irradiation dose and the type of loaded PFMs. For all of the loaded monomers, the extent of crosslinking increased at different rates as a function of irradiation dose. TMPTMA monomer was the most efficient in enhancing the crosslinking of LDPE films compared to the other loaded monomers. However, the unloaded LDPE film showed the least extent of crosslinking. In addition, the EB‐radiation‐induced changes, such as trans‐vinylene formation, a decrease in vinyl and vinylidene unsaturation; and carbonyl double‐bond formation and change in crystallinity were correlated. The importance of these results on the prediction of the role of polyfunctional monomers in the production of crosslinked polymers is discussed. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2025–2035, 2003     

Anodic dissolution of spongy titanium in ethanol solution for preparation of nano-sized TiO2 powder

Nano-sized TiO₂ powder was prepared by electrochemical dissolution of spongy titanium in an ethanol solution following direct hydrolysis of the electrolyte solution. Characterization of the electrochemical product revealed that Ti(OEt)₄ was formed by anodic dissolution of spongy titanium in ethanol solution. X-ray diffraction and transmission electron microscope were, respectively, used to investigate the structure of TiO₂. This study showed that nano-sized TiO₂ prepared by this method has a structural and thermal stability with a narrow size distribution of 5-10 nm. The optimum electrochemical operating conditions established were a temperature of 333-343 K, current density of 400 A m⁻² and faradaic efficiency of 86%. Experiments showed that this process might be recommended as a promising technique for synthesis of nano-sized powder.     

双峰PE80级管材专用树脂的开发

介绍了高密度聚乙烯管材专用树脂6366M的结构特性、物理性能及其加工应用试验的情况。结果表明，6366M具有相对高的相对分子质量，其相对分子质量分布结构特性呈双峰分布。该材料具有优异的力学性能和耐环境应力开裂性能，而且加工性能较好，实现了刚性和韧性的平衡。成品管材的性能指标可以满足用户的需求。     

改性蛋白土填充线型低密度聚乙烯的研究

对超细加工并经硅烷偶联剂处理的蛋白土填充线型低密度聚乙烯进行了研究,结果表明:采用适当的偶联剂及恰当的添加量,改性蛋白土可以降低塑料的成本。     

球磨效率探讨

主要讨论了球石的装载量、球石空隙率、球石级配、泥浆密度等因素对球磨效率的影响。运用正交试验优选了各因素。     

802.11 DCF协议引入信道预约机制的必要性分析

论文对802.11 DCF协议引入信道预约机制的必要性问题进行了探讨.通过分析信道预约机制与隐藏/暴露终端问题之间的关系,提出一种比较隐藏终端和暴露终端出现概率大小的等效方法,并给出了相应的数值估算结果.理论分析结果验证了802.11 DCF协议引入信道预约机制的有效性.