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91.
92.
Ruey-Shin Juang 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1992,54(1):75-80
The extraction of zinc from chloride solutions with tri-n-octylphosphine oxide (TOPO) dissolved in benzene has been thermodynamically studied based on the law of mass action. A model employing the simplified Pitzer equations for stoichiometric activity coefficient estimations is found to be effective for the explanation and prediction of the distribution data, and the thermodynamic extraction constant is determined as log Ket = 5.16 ± 0.11 at 20°C. 相似文献
93.
本文运用“软科学”一即通过建立数学模型,进行系统分析和系统优化,阐述对蒸汽管网优化运行的方法及原理,达到提高供热效率及节能降耗的目的. 相似文献
94.
Sergei L. Shmakov 《Polymer》2002,43(4):1491-1495
The two-region Okada-Numasawa model for solutions of star-shaped polymers has been improved by means of a change in the integration order and introduction of a concentration-dependent and molar-mass-dependent Flory-Huggins interaction parameter (the second and third approximations of the Flory-Huggins theory). To overcome calculation difficulties, a special algorithm for computing coexistence curves of polymeric systems with an UCST has been used. The agreement between the experimental and calculated coexistence curves for the star-shaped polystyrene (PS)-cyclohexane system has been improved: the difference between Tcs is ∼0.33 K against ∼12 K as given by the original model. 相似文献
95.
Calcium addition in straw gasification 总被引:1,自引:0,他引:1
The present work focuses on the influence of calcium addition in gasification. The inorganic-organic element interaction as well as the detailed inorganic-inorganic elements interaction has been studied. The effect of calcium addition as calcium sugar/molasses solutions to straw significantly affected the ash chemistry and the ash sintering tendency but much less the char reactivity. Thermo balance test are made and high-temperature X-ray diffraction measurements are performed, the experimental results indicate that with calcium addition major inorganic-inorganic reactions take place very late in the char conversion process. Comprehensive global equilibrium calculations predicted important characteristics of the inorganic ash residue. Equilibrium calculations predict the formation of liquid salt if sufficient amounts of Ca are added and according to experiments as well as calculations calcium binds silicon primarily as calcium silicates and less as potassium calcium silicates. 相似文献
96.
王逸峰 《南通纺织职业技术学院学报》2003,3(2):73-76
律师的思想政治特征状态及发展趋势,关系到律师行业的健康发展,影响着改革开放和社会经济发展的大局,左右着建设社会主义法治国家的进程。对此进行认真分析是做好律师统战工作的基础和前提。通过从思想观念、政治态度、道德认识、价值取向等层面分析了律师的现状和特征,揭示了团结、帮助、教育、引导律师对做好律师的统战工作的重要意义。 相似文献
97.
Trace element evaporation during coal gasification based on a thermodynamic equilibrium calculation approach 总被引:1,自引:0,他引:1
《Fuel》2003,82(2):137-145
Thermodynamic equilibrium calculations using the HSC-Chemistry program were performed to determine the distribution and mode of occurrence of potentially toxic and corrosive trace elements in gases from coal gasification processes. The influence of temperature, pressure and gas atmospheres on equilibrium composition was evaluated. In these reducing conditions, the behaviour of the trace elements is complex, but some form of organization can be attempted. Elements were classified into three groups. Group A includes those elements that, according to thermodynamic data at equilibrium, could probably be condensed in coal gasification. Mn is classified in this group. Group B contains those elements that could be totally or partially in gas phase in gas cleaning conditions, and can be divided into two subgroups, depending on whether the cleaning conditions are hot or cold. Co, Be, Sb, As, Cd, Pb, Zn, Ni, V, Cr are elements in this group. Group C contains those elements that could be totally in gas phase in all the possible conditions, including flue gas emissions. Se, Hg and B are the elements that make up this group. 相似文献
98.
鄱阳湖水质状况分析与评价 总被引:4,自引:0,他引:4
鄱阳湖是我国最大的淡水湖,其水质现状为人们普遍关心的问题。通过对1980年1月至1988年12月水质资料的搜集整理,对鄱阳湖水质的时空分布规律进行分析。作出的结论是:鄱阳湖虽已受到污染,但其水质总体情况尚属良好,在全国淡水湖泊中属最好的湖泊之一,应予特别珍惜、保护。 相似文献
99.
The free energies of mixing of two networks in the interpenetrating polymer network based on crosslinked polyurethane and poly(ester acrylate) have been determined by the vapour sorption method. It was established that the constituent networks in the IPN are not miscible. The introduction of fillers of different chemical nature increases the compatibility. The thermodynamic affinity of the fillers to the individual networks and IPN was estimated. It was established that when the free energy of interaction of one or both components of the IPN with the filler is negative, reinforcement leads to the formation of a compatible and equilibrium system. For fillers having no affinity to the polymers, compatibilization is observed, which is connected with slowing down of phase separation in the system in the presence of filler. 相似文献
100.
介绍了钒分厂利用正交试验法进行试验方案的设计及试验结果的直观分析,确定出钒渣烙烧的最佳工艺条件是:钒渣粒径小于0.12mm,烙烧气中氧气体积分数大于10%,焙烧温度850℃,烙烧时间60min,碱比(碱与钒渣质量比)16%,盐比(盐与钒渣质量比)5%,从而改变了以往在生产和转渣时组织生产的被动局面,为公司创造了可观的经济与社会效益。 相似文献