DEDS-10双子表面活性剂的性能研究

合成了一种新型的DEDS-10双子表面活性剂,用红外光谱对所合成化合物的结构进行了初步表征。DEDS-10的临界胶束浓度cm c为0.47 mmol/L,γcm c为34.5 mN/m,A lC l3、CaC l2和NaC l可以使γcm c降低3.6~1.1 mN/m,其cm c值大约为纯水溶液cm c值的1/5~1/3;加入乙醇,可增加其表面活性,在乙醇的浓度为0.22 mol/L时,其表面张力为30 mN/m左右。与阳离子表面活性剂DTAB和非离子表面活性剂曲拉通X-100复配,可以大幅度地降低cm c和γcm c值,与阴离子表面活性剂TLS复配时,cm c降低,cγm c略有增加。     

合并隔膜碱和离子膜碱盐水生产系统的优势

论证了合并隔膜碱和离子膜碱盐水生产系统的可行性,指出两个盐水生产系统合并后降低了生产辅料 BaCl2消耗并有效地保护了环境。     

GRIP管混凝土组合结构压弯构件非线性全过程分析

本文应用细观力学、经典层板理论、平截面假定、FRP约束混凝土本构模型及数值积分对GFRP管混凝土组合结构压弯构件进行了非线性全过程分析。通过理论计算发现GFRP管混凝土组合结构能有效地提高构件的承载力，且构件具有良好的变形能力。FRP壳体参与承载且有效地约束混凝土的变形，显著提高核心混凝土强度和变形能力。文中讨论了轴压比、长细比、径厚比、混凝土强度等级、纵筋配筋率、铺层角变化对极限水平荷载和极限水平位移的影响，从而得到了一些有益的结论。     

全级配混凝土单轴疲劳特性细观数值模拟

为研究全级配混凝土在等幅、变幅及阶梯重复荷载作用下的疲劳特性,揭示材料特性与疲劳应力水平对其疲劳寿命的影响规律,通过自编程序建立二维随机骨料模型,运用有限元软件和耐久性疲劳分析软件进行联合仿真,对全级配混凝土细观结构进行应力分析和疲劳分析,探讨了不同骨料分布、骨料形状及疲劳应力水平对混凝土疲劳性能的影响,并估算了疲劳寿命。结果表明:在阶梯重复荷载作用下,骨料形状和分布对混凝土疲劳寿命影响较小,而疲劳应力水平对疲劳寿命影响较大;圆形和椭圆形骨料混凝土疲劳寿命较高,多边形骨料寿命较低;在疲劳加载破坏过程中,骨料界面先起裂,然后裂纹逐渐扩展贯通,最后导致整个试件完全破坏,可见骨料界面是混凝土中的薄弱部位,其寿命直接影响整个混凝土试件的寿命。研究成果为后续混凝土疲劳性能研究提供了参考。     

The properties of equimolar copolycarbonates of bisphenol A with bisphenol S and 1,4-bis(hydroxymethyl)cyclohexane

Ranges of both alternating and random 1:1 copolycarbonates of Bisphenol-A (2,2-bis(4-hydroxyphenyl)propane) and Bisphenol-S (4,4′-dihydroxydiphenyl sulphone) and of Bisphenol-A and 1,4-dimethanoylcyclohexane have been synthesized in order to test the hypothesis that, other things being equal, a more random structured polymer should exhibit superior thermal ageing characteristics. Studies on these materials' mechanical and thermal properties establish that within each pair they are extremely similar and hence the original hypothesis is disproved.     

Synthesis of tertiary poly(amido-amine)s with amido- and amino-groups randomly arranged along the macromolecular chain

A new synthesis of poly(amido-amine)s from bis (secondary amine)s and acryloyl chloride has been studied, leading to polymers in which the amido- and amino-groups are randomly arranged along the macromolecular chain. A poly(amido-amine) based on piperazine, chosen as the mother compound, has been fully characterized by ¹³C n.m.r. as well as by identification and quantitative evaluation of its hydrolysis products.     

带可变随机函数和变异算子的粒子群优化算法

标准粒子群优化算法的收敛分析表明,改变随机函数、个体历史最优,群体全局最优,有助于提高该算法的性能。为此,本文提出了一种带可变随机函数和变异算子的粒子群优化算法,即通过改变速度更新方程中的随机函数分布来调节粒子在迭代过程中飞向个体历史最优和群体全局最优的比重,通过对个体历史最优和群体全局最优进行变异来增强种群的搜索能力。实验结果证实了该算法的有效性。     

FREQUENCY DOMAIN TESTS OF MULTIVARIATE GAUSSIANITY AND LINEARITY

A stationary multivariate time series { X _t } is defined as linear if it can be written in the form X _t = ∑^∞ _{j =−∞} A _j e _{t − j} where A _j are square matrices and e _t are independent and identically distributed random vectors. If the e _t } are normally distributed, then { X _t is a multivariate Gaussian linear process. This paper is concerned with the testing of departures of a vector stationary process from multivariate Gaussianity and linearity using the bispectral approach. First the definition and properties of cumulants of random matrices are used to obtain the expressions for the higher-order cumulant and spectral vectors of a linear vector process as defined above. Then it is shown that linearity of a vector process implies constancy of the modulus square of its normalized higher-order spectra whereas the component of such a vector process does not necessarily have a linear representation. Finally, statistics for the testing of multivariate Gaussianity and linearity are proposed.     

15万t/a双甲氨合成联合装置设计

从工艺路线的比较、压力等级的选择、主要设备的选型等方面阐述了双甲氨合成联合装置的设计特点。结合生产运行实践,分析了双甲氨合成工艺路线的运行参数,与采用不同工艺的生产消耗和产品成本进行了对比。结果表明,该工艺吨氨节约成本80元,精醇成本为1112.6元/t,经济效益显著且生产运行稳定。     

适用于摩托车零件的多层镍电镀工艺

概括目前我国摩托车零件电镀所用镀层组合，对照有关金属覆盖层的国家标准，认为摩托车零件应用多层镍组合，并提供了工艺配方。