高镁边缘磷矿制取阻燃剂氢氧化镁的工艺

为解决大量的高镁低磷边缘磷矿废渣堆存对环境的影响,开发了以其为原料制取阻燃剂氢氧化镁工艺.该工艺主要包括酸解磷矿和镁沉淀过程,重点讨论了沉淀氢氧化镁过程中时间、温度、氨镁摩尔比n(NH3/MgO)等多种因素的影响,得到的最佳工艺条件是:反应温度65℃,反应时间80min,n(NH3/MgO)为5∶ 1,镁的沉淀效率为80%.     

高温和低张应力引起的非平衡晶界偏聚动力学(Ⅱ)--实验结果的动力学模拟

以文献[1]建立的张应力引起的非平衡晶界偏聚动力学方程模拟了Shinoda T等的磷在钢中的应力时效实验结果和Misra R D K的硫在钢中的应力时效实验结果，模拟结果与实验结果互相吻合。通过模拟发现，张应力使磷-空位复合体以及硫-空位复合体在钢中的扩散系数均增加3个数量级，且磷原子和硫原子的扩散系数分别降低3个和5个数量级。     

Research on charge ordering and magnetic properties in La0.3Ca0.7Mn1-xWxO3 system

The perovskite manganite sample La0.3Ca0.7Mn1-xWxO3 （x = 0.08, 0.12） was prepared by the solid-state reaction method. The effect of W doping on the Mn site to La0.3Ca0.7MnO3 charge ordering phase and the changing process of magnetic properties were studied through the measurement of the M-T curve, M-H curves, and ESR curves of the sample. The results showed that when x = 0.08, the charge ordering （CO） phase exists in the system, the transition temperature Tco= 275 K, and the system exhibits PM when T 〉 275 K. The system transforms from spin-disordering paramagnetism to spin-ordering antiferromagnetism in the charge ordering state with the temperature decreasing from 275 K to 230 K. The long-range antiferromagnetism forms and AFM/CO states coexist between 230 K and 5 K. There is a little ferromagnetic component in the AFM/CO background in a low temperature range. When x = 0.12, the CO phase in the system has almost melted completely. There is a little remnant of the CO phase below 150 K. The system exhibits paramagnetism when T 〉 150 K and transforms from paramagnetism to ferromagnetism when T〈 150 K.     

甘油三乙酸酯超临界酯交换反应及其动力学研究

研究了在超临界条件下甘油三乙酸酯与甲醇或乙醇的酯交换反应,分别考察了超临界状态下醇油摩尔比和温度对反应的影响。实验结果表明,甲醇或乙醇与甘油三乙酸酯的摩尔比为14、反应温度为350℃、反应时间为20m in时,乙酸甲酯或乙酸乙酯的收率分别达100%和60%。对超临界状态下动力学的研究结果表明,甘油三乙酸酯与甲醇或乙醇的酯交换反应为拟一级反应,在相同的反应条件下,采用甲醇时酯交换反应速率比用乙醇时快,相应的甘油三乙酸酯的转化率也高;甘油三乙酸酯在超临界甲醇或乙醇中酯交换反应的表观活化能分别为58.7 kJ/mol和75.1 kJ/mol,甘油三乙酸酯与甲醇酯交换反应的活化能低于与乙醇酯交换反应的活化能,表明碳链短的醇更易进行酯交换反应。     

靶向抗癌药格列卫与其治疗白血病疗效监测

Gleevec是抑制致癌的融合蛋白BCR-ABL的一种分子靶向治疗药物,BCR-ABL是一种与慢性髓细胞性白血病(CML)有关的酪氨酸激酶抑制剂。用Gleevec选择性地抑制BCR-ABL活性在治疗CML中显示出很好的效果,特别是在CML慢性期,因此,监测疗效非常重要。现就Gleevec的研究进展及如何监测其在CML中的疗效作一简单综述。     

沸石孔结构对1-己烯异构化性能的影响

采用1-己烯为原料,对硅铝比相近、不同孔结构的沸石在脉冲微反装置上进行了评价试验,考察了FCC条件下沸石孔结构对烯烃异构化性能的影响。结果表明,大孔径的Y型沸石具有良好的异构化性能,异构化能力由强到弱的排列顺序为Y>β>ZRP>丝光沸石>镁碱沸石。     

Motor fluency deficits in the sequencing of actions in schizophrenia.

Many everyday activities depend on the capacity to organize and smoothly execute motor sequences. The authors tested the hypothesis that a sequencing deficit is associated with schizophrenia. They used a new method to distinguish between lower and higher order mechanisms for the impairment. The 1st task involved triggered sequences in which sensory information from 1 movement was the cue for initiation of the following movement. Results showed that the motor sequences were performed as fluently in patients as in controls. The 2nd and 3rd tasks involved sequences in which the entire movement sequence could be preplanned. Patients executed the sequences less fluently than controls but only under the condition where action sequences were required. Furthermore, the patients' fluency deficit increased with sequence complexity. The high discrimination power of Task 3 gave the authors a means to control for a potential psychometric confound involving differential discriminating power and to argue in favor of a specific higher order motor fluency deficit in patients with schizophrenia. It is suggested that basic lower order mechanisms that integrate sensory information with outgoing motor commands are preserved in schizophrenia, whereas higher order integrative mechanisms that are required for the smooth coordination of motor sequences are impaired. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

在酸性介质中N-H伪酸Mannich反应机理的量子化学研究

用量子化学中的ＳＣＦ－ＭＯＡＭ１方法，全优化计算了以苯并唑酮为伪酸组分的（Ｎ－Ｈ酸）Ｍａｎｎｉｃｈ反应的反应物、过渡态和产物络合物的分子几何构型、电子结构和生成热。根据计算所得各反应的活化能，提出了该反应在酸性介质中的机理，即甲醛首先与苯并唑酮作用，其产物再与二甲胺作用生成Ｍａｎｎｉｃｈ碱，并就其缘由进行了讨论。     

关于彩色火焰蜡烛的研制

本文阐述了利用焰色反应的原理研制彩色火焰蜡烛，着重分析并解决了在研制工作中出现的几个技术关键，如主燃剂的选取、蜡烛成型和强度、发色剂的选择与用量等．