连续重整装置仿真系统的设计开发

为提高操作人员对连续重整装置开停工及事故处理的熟练程度，并对生产进行指导，采用半机理模型结合设计和现场数据介发的连续重整装置仿真系统已在现场成功投用。介绍了该仿真系统的软硬件结构、动态模型及仿真功能。     

Probing the early stages of polymerization of ethylene on a model chromium/silica catalyst by Fourier transform infrared spectroscopy

The nature of the interaction of monomer, and the early stages of growth of oligomers of ethylene on a rather more uniform surface of Cr/SiO₂ catalyst than hitherto studied has been investigated by differenceFTIR spectroscopy using C₂D₄ and C₂H₄ as reactants both with and without subsequent treatment of the catalyst with CO andTHF. The active catalyst was prepared by reaction of vapour phase CrO₂Cl₂ with the vicinal hydroxyls of the silica surface. Three distinct kinds of methylene groups were detected. Arguments are given for assigning the peaks at 2935 and 2860 cm^–1 to CH₂ groups directly bound to the active site and those at 2920 and 2850 to CH₂s in the growing chain well removed from the Cr. The peaks at 2160 and 2165 cm^–1 are attributed to CD₂ groups hydrogen bonded to surface hydroxyls.     

简并量子拍频三能级系统中的光场压缩效应

本文讨论了V-型简并量子拍频三能级原子与单模相干辐射场相互作用时的动力学行为，并研究了光场的压缩效应。     

异构数据的管理方法及异构数据源的集成研究

工程应用中软件工具的多样性和设计活动的分散性形成了大量异构数据。本文分析了传统的异构数据管理方法的不足，提出使用数据库系统的文件系统结合的管理方法。针对此方法下所形成的异构数据源问题，给出了基于J2EE规范的数据访问对象抽象工厂解决方案。     

中频反应溅射SiO2膜与直流溅射ITO膜的在线联镀

多数ITO透明导电玻璃生产线在实现SiO2膜与ITO膜在线联镀时，应用SiO2靶射频溅射沉积SiO2膜工艺和ITO靶直流溅射沉积ITO膜工艺，如果SiO2膜应用硅靶反应磁控溅射工艺，存在这种工艺是否可以与ITO靶直流溅射沉积ITO膜工艺在线联用以及如何实现联用的问题。作者对现有的生产线进行了改造设计、加工，做了大量实验、质谱分析和多项测试研究，成功地实现反应溅射SiO2膜与ITO膜在线联镀，做到SiO2镀膜室的工作状态的变化基本上不影响ITO镀膜室的工艺条件。     

测量输入光窗台阶指标的指示表的选择

阐述了对近贴聚焦型微通道板像增强管中输入光窗台阶高度和平整度指标进行测量时，所用指示仪表的选择依据，并详细分析了指示表在检定过程中的误差来源，进一步计算出其合成标准不确定度和扩展不确定度，从而选定可用于测试的指标表。     

Effect of dose rate and length of storage on the ESR signal strength in irradiated chicken bone

One hundred and twenty-five pairs of chicken drumsticks were randomly allocated to one of five dose rates: 5, 10, 15, 20 or 600 kGyh-. The highest dose rate was obtained using a linear accelerator whilst the remaining dose rates were provided using a ⁶⁰Co gamma source. Each batch of 25 pairs was further divided into groups five of which were stored at 4°C for 0, 7, 14, 21 or 28 days. ESR spectroscopy was used to measure the intensity of the radiation-induced signal. There was a quadratic relationship between ESR signal strength and dose rate, which although statistically significant is unlikely to be of practical importance. The magnitude of the ESR signal declined by about 20% over the first 14 days of storage at 4°C and thereafter the decrease was minimal.     

反应精馏法制备高纯度醋酸甲酯

在中试反应精馏塔中以浓硫酸为催化剂进行了醋酸与甲醇反应制备醋酸甲酯的试验。反应精馏塔的精馏段为填料,反应段为立体催化精馏塔板,采用连续操作,考察了回流比、甲醇进料位置、停留时间、催化剂用量对反应精馏的影响。试验结果表明,当回流比为1.2、甲醇进料位置为第11～15块塔板、停留时间为2.2～2.5h、催化剂与醋酸的质量比为1.07∶100时,塔顶醋酸甲酯的质量分数达到99.50%以上,醋酸的转化率达到99.85%以上。     

聚丙烯催化剂的研发进展

综述了用于丙烯聚合的Ziegler-Natta催化剂在给电子体技术及催化剂制备工艺等方面,茂金属催化剂在制备丙烯均聚物、丙烯共聚物及特殊聚丙烯等方面,非茂单活性中心催化剂在丙烯活性聚合、丙烯与极性单体共聚及水介质聚合等方面的研发进展;讨论了聚丙烯催化剂的前景。