A Thermo-Mechanical Study of Some Epoxy Adhesives Subjected to Combined Dynamic and Static Stresses

The object of the present study was to investigate the effect of superimposed dynamic and static stresses on mechanical and thermal properties of some epoxy adhesives. It was found that combinations of shear creep and torsional oscillations, applied simultaneously to adhesive joints at temperatures within the glassy range of the adhesive, led to strengthening of the joints in shear and to an increase in the glass transition temperature of the adhesive. Similar loading stresses applied at temperatures close to the T_g of the adhesive, led to opposite effects on the above mentioned properties of the joints. The width of the glassy-rubbery transition of the adhesives increased, in the whole range of temperatures used in this study and for all epoxy compositions, as a result of subjecting the joints to superimposed dynamic and static stresses. The broadening of the glass transition was interpreted as a result of the stiffening of polymer network during the combined stressing experiments. A linear relationship was found between the area of endothermal peaks in the first DSC scan of specimens subjected prior to test to superimposed dynamic and static stresses at temperatures below T_g, and the shear strength of the joints. In agreement with this observation and with literature data, a linear relationship was revealed also between the glass transition temperature of the resins (measured in the first DSC scan) and the shear strength of the joints. Based on experimental observations and on some literature information, it was suggested that the strengthening of the joint, as well as the changes in thermal properties of the adhesives, are mainly due to physical processes, such as short-range orientation of network chains and an increase in intermolecular interaction between highly polar sites of the network. The possibility that superimposed stressing led to changes in chemical crosslinking was discussed but it seems that no such reactions occurred.     

认知任务驱动的fMRI脑功能网络构建方法

针对脑功能网络的构建受到特定大脑图谱对兴趣点描述准确度及覆盖度的限制,提出了基于认知任务信息和神经影像数据的脑功能网络构建方法。首先计算fMRI体素对于认知任务的敏感度,然后在此基础上选取兼顾分布均衡和去中心化的大脑兴趣点,从而构建任务驱动的脑功能网络。实验通过在人脸情绪识别认知任务相关的梭状回构造任务驱动的脑功能网络,其度中心性、聚类系数、全局效率、局部效率这四个复杂网络指标均优于典型大脑图谱梭状回中兴趣点构成的网络。结果表明,计算得到的大脑兴趣点具有更强的整合性,更适合用于表征特定认知任务下的脑功能网络。     

无人机群目标搜索的主动感知方法

为提升蚁群搜索算法在规模大的栅格环境中对未知目标的搜索效率,提出基于蚁群算法的主动感知搜索框架。该框架通过应用历史环境信息来选择无人机的运动方式,并由无人机运动方式和感知域信息得到新的环境信息,从而实现无人机群的智能自动化搜索功能。新方法计算出一种具有探索偏好的未搜索概率,可使无人机搜索时偏向未搜索程度高的栅格,以此来提高算法的搜索能力。同时,以未搜索概率和信息素作为运动方式决策的依据来建立一种新的运动方式选择机制。该机制不仅考虑了目标可能出现的区域,又可兼顾未知区域,从而可实现无目标先验信息条件下的搜索过程。仿真结果表明,此算法在规模大的栅格环境中,与现有算法相比具有更高的搜索效率,并且得到的目标分布信息将更加全面。     

Identification methods for anomalous stress region in coal roadways based on microseismic information and numerical simulation

It is believed that the microseismicity induced by mining effect and gas gradient disturbance stress is a precursor to the essential characteristics of roadway unstability. In order to effectively identify and evaluate the stability of coal roadways in the process of mine development and extraction, a microseismic monitoring system was deployed for the study of the stress evolution process, damage degree and distribution characteristics in the tailgate and headgate. The mine under study is the 62113 outburst working face of Xin Zhuangzi coalmine in Huainan mining area. The whole process of microfractures initiation,extension, interaction and coalescence mechanisms during the progressive failure processes of the coal rock within the delineated and typical event clusters were investigated by means of a two dimensional realistic failure process analysis code(RFPA2D-Flow). The results show that the microseismic events gradually create different-sized event clusters. The microseismicity of the tailgate is significantly higher than that of the headgate. The study indicates that the greater anomalous stress region matches the area where microfractures continuously develop and finally connect to each other and form a fissure zone.Due to the mine layout and stress concentration, the ruptured area is mainly located on the left shoulder of the tailgate roof. The potential anomalous stress region of the coal roadway obtained by numerical simulation is relatively in good agreement with the trend of spatial macro evolution of coal rock microfractures captured by the microseismic monitoring system. The research results can provide important basis for understanding instability failure mechanism of deep roadway and microseismic activity law in complex geologic conditions, and it ultimately can be used to guide the selection and optimization of reinforcement and protection scheme.     

齐齐哈尔工业区春季大气中PBDEs的污染及气粒分配

齐齐哈尔富拉尔基区为典型的国家重工业集中区域,为研究其大气中多溴联苯醚(PBDEs)的质量浓度水平、污染特征和气/粒分配规律,分别在其下风向和上风向采集大气颗粒相和气相样品,对PBDEs的质量浓度进行测定.结果表明,大气中PBDEs总质量浓度为13.9~102 pg·m-3,平均值为53.6 pg·m-3,BDE-209是质量浓度最高的同系物.来源分析表明,PBDEs主要来源于商用五溴联苯醚和十溴联苯醚的使用.由log KP和log poL线性回归得到的斜率均高于平衡状态理论值-1,说明大气中的PBDEs气粒分配未达到平衡状态.采用Junge-Pankow吸附模型和Harner-Bidleman吸收模型对PBDEs颗粒态百分比(φ)进行了模拟,结果均高于实际值.     

裂纹起裂角预测方法研究

本文提出一个新的屈服准则,该屈服准则适用于岩石类材料的小范围屈服,旨在预测弹塑性材料的破坏行为,基于该屈服准则,推导出了I型,II型以及I-II混合型裂纹尖端塑性区半径并对在单轴拉伸和纯剪切等荷载作用下的裂纹尖端塑性区进行了分析。结果显示,荷载加载方式、裂纹倾斜角和材料内摩擦角对塑性区的形状与大小有显著影响。根据对裂纹尖端塑性区的分析,基于如下假设：裂纹沿塑性区最短路径扩展,本文在提出的屈服准则的基础上导出了新的断裂准则,该准则可预测裂纹开裂初始角。相较于其他断裂准则,文献实验结果与本文提出的准则吻合地更好,能更加精确的预测裂纹的起裂角。     

明亮区域的暗原色先验算法

针对暗原色先验算法在处理含有大面积明亮区域的有雾图像时,复原图像会产生严重色彩偏移的不足,提出了一种基于像素点的透射率修正方案.在分析暗原色先验去雾原理以及复原图像色彩偏移成因的基础上,对去雾模型进行推导,使用暗通道亮度与大气光数值接近度及像素通道间数值接近度作为明亮区域判定机制,得出更具普适性的透射率求取方法.明亮区域采用容差机制纠正错误估计的透射率,非明亮区域仍采用原透射率求取方式,并首次将改进算法应用到雪天模糊图像清晰化中.实验结果表明,改进算法使去雾图像清晰自然,可有效修正色彩失真.     

向列相液晶聚合物接枝碳纳米管制备及其性能

为了制备碳纳米管/液晶复合材料,合成了液晶单体1,4-苯二甲酸二-(4-羧基苯)酯,采用原位聚合法将其与1,6-己二酸、1,4-联苯酚、碳纳米管进行共聚,制备了不同配比的碳纳米管/液晶复合材料.利用红外光谱(FT-IR),差式扫描量热仪(DSC)、偏光显微镜(POM)、扫描电子显微镜(SEM)等研究了碳纳米管在液晶基体中的分散以及复合材料的液晶性.结果表明,少量的碳纳米管可以在液晶中分散良好;液晶复合材料的液晶区间变窄,但没有改变液晶复合材料的液晶类型.     

某机载雷达发射校正系统的EMC设计

因受载机平台内电子设备电磁干扰的影响,某机载雷达发射校正时存在通道相位漂移的现象,表现为同一通道相位多次测量偏差超过正常幅度值.在阐述发射校正系统工作原理的基础上,深入分析干扰的来源和机理,提出了综合运用屏蔽、接地、滤波等措施解决电磁兼容问题的具体方法,实现了雷达发射校正系统的可靠工作,为该类工程设计提供了参考.     

间歇式用能模式下墙体热分析

针对夏热冬冷地区间歇式用能特点,采用ANSYS软件对外墙内外保温墙体进行热分析。通过间断式施加温度荷载模拟空调运行,分析两种保温形式的墙体内温度变化情况。研究结果表明,受墙体内侧温度荷载的影响,内保温墙体内表面温度变化明显,且热量集中分布在内侧保温层部分,不易散失;外保温墙体受内侧温度荷载的影响较小,热量在墙体内分布均匀。在相同时间内,内保温需要施加荷载的时间明显比外保温的少。