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111.
芘四硫酸四钠盐/甲基紫精复合物光物理性质的研究 总被引:1,自引:0,他引:1
本文通过吸收光谱滴定和时间分辨瞬态吸收光谱对芘四硫酸四钠盐(pyrenetetrasulfonicacidtetrasodiumsalt,PyTS)/甲基紫精(methylviologen,MV2+)复合物在水溶液中的光物理性质进行研究.用甲基紫精滴定芘四硫酸四钠盐时,得到该复合物的组成成份是1∶1,反之,用芘四硫酸四钠盐滴定甲基紫精时,同样得到1∶1组成成份的复合物.该复合物的形成常数是2.4×106mol-1·L,当用光激发该复合物时,发现其中存在芘四硫酸四钠盐到甲基紫精的电子转移过程,并得到该过程的动力学模型. 相似文献
112.
To explore ultralow dielectric constant polyimide, the crosslinked polyimide foams (PIFs) were prepared from 3,3′,4,4′‐benzophenonetetracarboxylic dianhydride (BTDA), 4,4′‐oxydianiline (ODA), and 2,4,6‐triaminopyrimidine (TAP) via a poly(ester–amine salt) (PEAS) process. FTIR measurements indicated that TAP did not yield a negative effect on imidization of PEAS precursors. SEM measurement revealed the homogeneous cell structure. Through using TAP as a crosslinking monomer, the mechanical properties of PIFs could be improved in comparison with uncrosslinked BTDA/ODA based PIF. The crosslinked PIFs still exhibited excellent thermal stability with 5% weight loss temperatures higher than 520°C. In the field with frequency higher than 100 Hz, the dielectric constants of the obtained PIFs ranged from 1.77 to 2.4, and the dielectric losses were smaller than 3 × 10?2 at 25–150°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 1734–1740, 2006 相似文献
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114.
A novel method for the preparation of a quaternary ammonium ionomer of styrene–butadiene–styrene triblock copolymer (SBS) was developed by a ring‐opening reaction of epoxidized SBS with triethylamine hydrochloride in the presence of a phase transfer catalyst. The optimum conditions were studied. The ionomer was characterized by quantitative analysis, IR spectroscopy, and 1H‐NMR spectroscopy. Its water absorbency, oil absorbency, dilute solution viscosity, and use as a compatibilizer for the blending of SBS and chlorosulfonated polyethylene (CSPE) were investigated. The results showed that, under optimum conditions, the epoxy groups can be completely converted to the quaternary ammonium groups. The IR spectrum did not exhibit the absorption peak for quaternary ammonium groups, whereas the 1H‐NMR spectrum and titration method demonstrated it. With increasing ionic group content, the water absorbency of the ionomer increased whereas its oil absorbency decreased. These indicated the amphiphilic character of the SBS ionomer. The dilute solution viscosity of the ionomer in toluene/methanol (9/1) solvent increased with increasing quaternary ammonium group content. The ionomer was used as a compatibilizer for the blends of SBS and CSPE. The addition of a small amount of the ionomer to the blend enhanced the mechanical properties of the blends: 2 wt % ionomer based on the blend increased the tensile strength and ultimate elongation of the blend nearly 2 times. The blends of equal parts SBS and CSPE behaved as oil‐resistant thermoplastic elastomers. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1975–1980, 2006 相似文献
115.
发酵液的组成对纳滤分离谷氨酰胺的影响 总被引:2,自引:0,他引:2
研究了谷氨酰胺发酵液中盐离子对纳滤分离提取谷氨酰铵的作用,系统地考察了操作温度和发酵液组成对纳滤分离透过特性的影响,确定了纳滤分离时发酵液最佳稀释倍数和操作温度. 结果表明,二价阳离子通过改变膜面电荷密度对谷氨酸的透过特性产生很大影响,使其截留率降低了8%. 发酵液中较高浓度的(NH4)2SO4使谷氨酸和谷氨酰胺的截留率和透过通量明显降低,但较高浓度的NH4Cl影响较小,这体现了纳滤膜对不同离子排斥力的差异. 当发酵液稀释至谷氨酰胺浓度为1%,pH调至7时,发酵液中的其它盐离子和残糖因浓度较低而对纳滤分离影响不显著. 相似文献
116.
十二烷基苯磺酸钠水溶液聚集性质的研究 总被引:8,自引:0,他引:8
用滴体积法测出十二烷基苯磺酸钠(SDBS)稀水溶液的表面张力;然后求出其临界胶束浓度(CMC)。同时通过溶液的电导率、吸收光谱以及荧光光谱测定求出其CMC。这样测出的CMC值为1.2~1.6×10-3mol/L,与文献值相符。也研究了部分水解的聚丙烯酰胺(PHPAM)对SDBS聚集性质的影响;发现SDBS的CMC值随PHPAM的加人而减少并且PHPAM水溶液的粘度随SDBS的存在而急剧降低(类似盐效应)。这些方法与性质对强化采油(EOR)是重要的。 相似文献
117.
118.
P. Madhusudhan Rao M.V. Landau A. Wolfson A.M. Shapira-Tchelet M. Herskowitz 《Microporous and mesoporous materials》2005,80(1-3):43-55
The Cs-salt of heteropolyacid with stoichiometry Cs2.5H0.5PW12O40 (CsHPW) was deposited selectively at the external surface of the SBA-15 silica microcrystals, inside its mesoporous channels and simultaneously at both location modes. The structure, texture and performance of these CsHPW/SBA-15 composites were compared with that of a reference bulk salt of the same composition. Location of CsHPW salt on the external surface of SBA-15 microcrystals leads to disintegration of its agglomerates increasing acidity of the catalytic phase. A novel preparation strategy consisting of grafting the basic Cs-species at the internal pores surface of SBA-15 stabilized the CsHPW phase inside the channels in form of 5–8 nm nanocrystals at 30–70 wt.% loadings. The catalytic tests demonstrated that insertion of the CsHPW catalytic phase inside the nanotubular channels of SBA-15 in combination with location of an additional amount of this phase at the external surface of SBA-15 microcrystals allows to increase the specific activity of this phase in MTBE synthesis, propionylation of anisole and alkylation of catechol with t-butanol by a factor of 1.5–3. This level of specific activity in combination with high total loading of catalytic phase >60 wt.% permit to get composite catalytic materials with catalytic activity higher by a factor of 1.2–1.5 with respect to the bulk CsHPW catalyst and stabilizing the catalytic phase against colloidization in polar media. 相似文献
119.
水性纳米复合铁钛防锈涂料的研制 总被引:5,自引:0,他引:5
以不同类型乳液作为基料,将纳米复合铁钛防锈颜料中WD—A型粉和WD—D型粉以一定的比例配合,发挥协同效果,提高防锈性能,制备出性价比合理、综合性能优良的水性防锈涂料。并重点分析了影响漆膜耐盐水和盐雾性能的各项因素。 相似文献
120.