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31.
Investigations on white spirit and acetone permeation resistance of modified polyamide and nylon 6 clay (MPANYC) blends and their corresponding polyethylene/MPANYC bottles were reported in this study. The white spirit and acetone permeation resistance of MPANYC sheets improve consistently with increasing NYC contents present in MPANYC resins after blending nylon 6 clay (NYC) in modified polyamide (MPA) resins. However, the order of barrier improvement of the PE/MPANYC and PE/NYC bottle specimens is not corresponding to the order of barrier improvement of the MPANYC and/or NYC barrier resins added in PE. The blow-molded PE/NYC bottle specimen exhibits similarly worse white spirit and acetone solvent permeation resistance as the PE bottle specimen, wherein no clearly formed NYC laminas but only dispersed NYC droplets or agglomerates were found on the fracture surfaces of the PE/NYC bottles. However, after blending optimum compositions of MPANYC in PE, the PE/MPANYC bottles with demarcated MPANYC laminas exhibit significantly better white spirit and acetone permeation resistance than the PE/MPA bottle, wherein the white spirit and acetone permeation rates of the PE/MPA8NYC1 bottle are about 1.3 and 1.4 times slower than those of the PE/MPA bottle, respectively. In order to understand these interesting barrier properties of PE/MPANYC and PE/NYC bottles, rheological, thermal, wide angle X-ray diffraction and morphological properties of the base MPANYC and NYC resins and their corresponding morphology present in the blow-molded bottles were investigated. 相似文献
32.
在总结国内外地下水中污染物运移规律研究的基础上,阐述了地下水多孔介质中胶体与污染物协同运移的研究进展。讨论了胶体运移的基本过程、相关机理,探究污染物-胶体-微生物(生物胶体)协同运移的作用方式、影响因素、实验分析、模型构造,并指出该领域目前研究存在的主要问题,以及对该领域研究趋势的展望。 相似文献
33.
Monoj Pramanik Suneel Kumar Srivastava Biswas Kumar Samantaray Anil Kumar Bhowmick 《应用聚合物科学杂志》2003,87(14):2216-2220
Ethylene vinyl acetate rubber (45% vinyl acetate content, EVA‐45) and organomodified clay (12Me‐MMT) composites were prepared by solution blending of the rubber and the clay. A combination of X‐ray diffraction, scanning electron microscopy, and transmission electron microscopy studies showed that the composites obtained are on the nanometer scale. The measurements of the dynamic mechanical properties for different compositions over a temperature range (?100 to +100°C) showed that the storage moduli of these rubber–clay nanocomposites are higher above the glass to rubber transition temperature compared to the neat rubber. The tensile strength of the nanocomposites is about 1.6 times higher than that of the EVA‐45. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 87: 2216–2220, 2003 相似文献
34.
Dipole-dipole and/or hydrogen-bonding interactions between the pendant functional groups within maleated high-density polyethylene (PE-g-MAn) establish a physical polymer network, whose formation kinetics and shear-sensitivity are revealed by dynamic oscillatory testing. The pronounced time and shear dependent viscoelastic properties of PE-g-MAn were not observed for a corresponding imide derivative, PE-g-imide, presumably due to weakened functional group associations in the latter material.The melt compounding of PE-g-MAn with onium-ion exchanged montmorillonite clay (NR4+-MM) resulted in a partially exfoliated hybrid nanocomposite structure, whose viscoelastic behaviour differed significantly from that of the unfilled polymer. The presence of dispersed clay platelets altered the extent of functional group associations, thereby changing the dynamics of network formation. 相似文献
35.
Jui‐Ming Yeh Chi‐Lun Chen Tai‐Hung Kuo Wen‐Fen Su Hsi‐Ya Huang Der‐Jang Liaw Hsin‐Yi Lu Chi‐Fong Liu Yuan‐Hsiang Yu 《应用聚合物科学杂志》2004,92(2):1072-1079
A series of polymer–clay nanocomposite (PCN) materials consisting of 1,4‐bis(4‐aminophenoxy)‐2‐tert‐butylbenzene–4,4′‐oxydiphthalic anhydride (BATB–ODPA) polyimide (PI) and layered montmorillonite (MMT) clay were successfully prepared by an in situ polymerization reaction through thermal imidization up to 300°C. The synthesized PCN materials were subsequently characterized by Fourier‐Transform infrared (FTIR) spectroscopy, wide‐angle powder X‐ray diffraction (XRD) and transmission electron microscopy (TEM). The effects of material composition on thermal stability, mechanical strength, molecular permeability and optical clarity of bulk PI and PCN materials in the form of membranes were studied by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA), molecular permeability analysis (GPA) and ultraviolet‐visible (UV/VIS) transmission spectra, respectively. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 1072–1079, 2004 相似文献
36.
37.
A poly(ethylene terephthalate) (PET)/montmorillonite clay nanocomposite was synthesized via in situ polymerization. Microscopic studies revealed that in an isothermal crystallization process, some crystallites in the nanocomposite initially were rod‐shaped and later exhibited three‐dimensional growth. The crystallites in the nanocomposite were irregularly shaped, rather than spherulitic, being interlocked together without clear boundaries, and they were much smaller than those of neat PET. With Avrami analysis, the isothermal crystallization kinetic parameters (the Avrami exponent and constant) were obtained. The rate constants for the nanocomposite demonstrated that clay could greatly increase the crystallization rate of PET. The results for the Avrami exponent were consistent with the observation of the rodlike crystallites in the PET/clay nanocomposite during the initial stage. Wide‐angle X‐ray scattering and Fourier transform infrared studies showed that, in comparison with neat PET, the crystal lattice parameters and crystallinity of the nanocomposite did not change significantly, whereas more defects may have been present in the crystalline regions of the nanocomposite because of the presence of the clay. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 1381–1388, 2004 相似文献
38.
在石油、化工生产中 ,蒸汽夹套管作为保温管道类型之一常常在实际生产广泛运用。针对蒸汽夹套管在设计、安装中经常忽视的一些问题 ,分别从不同侧面加以比较分析 ,概括出它们在不同工况下的共同特点。在实际生产中 ,可有效提高管道运行的可靠性 ,降低投资 相似文献
39.
在对广西气刀土原料性能研究的基础上,进行了在卫生陶瓷坯料、釉料中的应用研究。坯料中加入4%~7%的广西气刀土原料替代等量的2#苏州土,在釉料中引入4~6%的气刀土原料替代1#苏州土,可以生产出理化性能和外观质量达到了美国ASMEA112.19.2M-1998标准要求的高档卫生陶瓷产品。引入广西气刀土原料使泥浆性能增强、厚化系数降低、湿坯硬度特别是内硬度明显提高、干坯抗折强度增大;制品体积密度增加、气孔率和吸水率降低;增强釉面乳浊效果、提高釉面白度,保证和提高产品的热稳定性能。 相似文献
40.
V. A. Sadykov T. G. Kuznetsova V. P. Doronin E. M. Moroz D. A. Ziuzin D. I. Kochubei B. N. Novgorodov V. N. Kolomiichuk G. M. Alikina R. V. Bunina E. A. Paukshtis V. B. Fenelonov O. B. Lapina I. V. Yudaev N. V. Mezentseva A. M. Volodin V. A. Matyshak V. V. Lunin A. Ya. Rozovskii V. F. Tretyakov T. N. Burdeynaya J. R. H. Ross 《Topics in Catalysis》2005,32(1-2):29-38
Approaches to design of zirconia pillared clays via control of the properties of pillaring species in solutions were elaborated. Structural features of pillars and Pt + Cu active components fixed at these nanoparticles were shown to determine catalytic properties of pillared clays in NOx selective reduction by hydrocarbons in the oxygen excess. 相似文献